Selective Separation of Organic Electrolytes by Neutralization Dialysis with Grafted Polyethylene Films

Yuji Kimura; Kazunori Yamada

doi:doi:10.11648/j.ijmsa.20180703.14

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Selective Separation of Organic Electrolytes by Neutralization Dialysis with Grafted Polyethylene Films

Yuji Kimura, Kazunori Yamada

Published in International Journal of Materials Science and Applications (Volume 7, Issue 3)

Received: 14 November 2017 Accepted: 30 November 2017 Published: 26 April 2018

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Abstract

The selective separation of organic electrolytes by neutralization dialysis was investigated with two kinds of grafted polyethylene (PE) films prepared through the photografting of 2-(dimethylamino) ethyl methacrylate (DMAEMA) onto the PE films and the subsequent quaternization and through the photografting of glycidyl methacrylate (GMA) and the subsequent sulfonation. The permeation flux of benzoic acid (BA) for the quarternized DMAEMA-grafted PE (PE-g-QPDMAEMA) films increased with an increase in the degree of quaternization, and the BA permeability had the maximum at the initial pH value of the permeate solution of 12.0. On the other hand, the sulfonation offered the phenylalaninol (Phl) permeability of the GMA-grafted PE (PE-g-PGMA) films. The selective separation for the binary BA/Phl or 2,5-dichlorobenzoic acid/Phl systems was successfully achieved by use of a pH difference between the feed and permeate solutions through the PE-g-QPDMAEMA and sulfonated PE-g-PGMA (PE-g-SPGMA) films. The maximum selective separation was obtained under the conditions that the initial pH values of the permeate solutions through the PE-g-QPDMAEMA and PE-g-SPGMA films were adjusted to 12.0 and 2.0, respectively. This procedure will be applied to separation and concentration of organic electrolytes and water purification.

Published in	International Journal of Materials Science and Applications (Volume 7, Issue 3)
DOI	10.11648/j.ijmsa.20180703.14
Page(s)	95-105
Creative Commons	This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.
Copyright	Copyright © The Author(s), 2024. Published by Science Publishing Group

Keywords

Polyethylene, Photografting, 2-(dimethylamino) ethyl Methacrylate, Glycidyl Methacrylate, Neutralization Dialysis, Selective Separation

References

[1]	G. A. Denisov, G. A. Tishchenko, M. Bleha, L. K. Shataeva, “Theoretical analysis of neutralization dialysis in the three-component membrane cell,” J. Memb. Sci., Vol. 98, No. 1-2, pp. 13-25, 1995.
[2]	A. Elmidaoui, S. Belcadi, Y. Houdus, T. Cohen, C. Gavach, “Perfluorinated anion-exchange membranes- preparation and preliminary tests dialysis,” J. Polym. Sci., A: Polym. Chem., Vol. 30. No. 7, pp. 1407-1412, 1992.
[3]	T. Sata, T. Yamaguchi, K. Matsusaki, “Effect of hydrophobicity of ion-exchange groups of amion-exchange membranes of permselectivity between 2 anions,” J. Phys. Chem., Vol. 99, No. 34, pp. 12875-12882, 1995.
[4]	T. Sata, K. Teshima, K. Yamaguchi, “Permselectivity between two anions in anion exchange membranes crosslinked with various diamines in electrodialysis” J. Polym. Sci., A: Polym. Chem., Vol. 34, No. 8, pp. 1475-1482, 1996.
[5]	Y. Zhang, L. Pinoy, B. Meesschaert, B. Van der Bruggen, “Separation of small organic ions from salts by ion-exchange membrane in electrodialysis,” AIChE J. Vol. 57, No. 8, pp. 2070-2078, 2011.
[6]	S. Zeidler, U. Kätzel, P. Kreis, “Systematic investigation on the influence of solutes on the separation behavior of a PDMS membrane in organic solvent nanofiltration,” J. Memb. Sci., Vol. 429, No. 15, pp. 295-303, 2013.
[7]	E. Fontananova, G. Di Profio, F. Artusa, E. Drioli, “Polymeric homogeneous composite membranes for separations in organic solvents,” J. Appl. Polym. Sci., Vol. 129, No. 4, pp. 1653-1659, 2013.
[8]	G. Wang, H. Tababe, M. Igawa, “Transport of glycine by neutralization dialysis,” J. Memb. Sci., Vol. 106, No. 3, pp. 207-211, 1995.
[9]	M. Igawa, K. Mikawa, H. Okachi, “Transport characteristics of neutralization dialysis and desalination of tap water,” Bull. Chem. Soc. Jpn., Vol. 76, No. 2, pp. 437-441, 2003.
[10]	M. Chérif, I. Mkacher, R. Ghalloussi, L. Chaabane, A. Ben Salah, K. Walha, “Experimental investigation of neutralization dialysis in three-compartment membrane stack,” Desalin. Water Treat., Vol. 56, No. 10, pp. 9363-9370, 2015.
[11]	M. Chérif, I. Mkacher, L. Dammak, A. Ben Salah, K. Walha, D. Grande, V. Nikonenko, “Water desalination by neutralization dialysis with ion-exchange membranes: Flow rate and acid/alkali concentration effects,” Desalination, Vol. 361, No. 1, pp. 13-24, 2015.
[12]	M. Chérif, I. Mkacher, L. Dammak, A. Ben Salah, K. Walha, V. Nikonenko, “Fractional factorial design of water desalination by neutralization dialysis process: concentration, flow rate, and volume effects,” Desalin. Water Treat., Vol. 57, No. 31, pp. 14403-14413, 2016.
[13]	K. Yamada, T. Taki, K. Sato, M. Hirata, “Electrotransport of organic electrolytes through 2-(dimethylamino) ethyl methacrylate-grafted polyethylene films and their separation and concentration,” J. Appl. Polym. Sci., Vol. 89, No. 9, pp. 2535-2344, 2003.
[14]	K. Yamada, K. Sato. S. Tatekawa, M. Hirata, “Membrane properties of polyethylene films photografted with hydrophilic monomers,” Polym. Gels Networks, Vol. 2, No. 3-4, pp. 323-331, 1994.
[15]	K. Yamada, K. Sasaki, M. Hirata, “Separation and concentration of anionic organic electrolytes by electrotransport through polyethylene films grafted cationic polymers,” in Field Responsive Polymers. Electroresponsive, Photoresponsive, and Responsive Polymers in Chemistry and Biology, ACS Symposium Series 726; American Chemical Society: Washington, DC, Chapter 21, pp. 16-24, 1999.
[16]	T. Taki, K. Yamada, M. Hirata, “Concentration of organic electrolytes by electrotransport using polyethylene films photografted with ionic monomers,” Trans. Mater. Res. Soc. Jpn., Vol. 24, No. 4, pp. 553-548, 1999.
[17]	K. Yamada, S. Tatekawa, M. Hirata, “Polyethylene film gels prepared by photografting of hydrophilic monomers,” J. Colloid Interface Sci., Vol. 162, No. 1, pp. 144-150, 1994.
[18]	K. Yamada, K. Sato, M. Hirata, “Uphill transport of organic electrolytes using polyethylene films photografted with 2-(dimethylamino) ethyl methacrylate,” J. Mater. Sci., Vol. 34, No. 5, pp. 1081-1091, 1999.
[19]	K. Yamada, M. Shibuya, C. Takagi, M. Hirata, “Adsorption and desorption properties of cationic polyethylene film gels to organic anions and their regeneration,” J. Appl. Polym. Sci., Vol. 99, No. 1, pp. 381-391, 2006.
[20]	K. Yamada, R. Nagano, M. Hirata, “Adsorption and desorption properties of the chelating membranes prepared from the PE films,” J. Appl. Polym. Sci., Vol. 99, No. 4, pp. 1895-1902, 2006.
[21]	H. Tanabe, H. Okachi, M. Igawa, “Separation of weak acids and bases by neutralization dialysis,” Ind. Eng. Chem. Res., Vol. 34, No. 7, pp. 2450-2454, 1995.
[22]	M. Bleha, G. A. Tishchenko, “Neutralization Dialysis for Desalination,” J. Memb. Sci., Vol. 73, No. 2-3, pp. 305-311, 1992.
[23]	M. Igawa, H. Tanabe, T. Ida, F. Yamamoto, H. Okachi, “Separation of weak acids and bases by neutralization dialysis,” Chem. Lett., No. 9, pp. 1591-1594, 1993.
[24]	Y. Takeuchi, K. Fujita, N. Tsubokawa, “Preparation of amphiphilic carbon black by postgrafting of polyethyleneimine to grafted polymer chains on the surface,” Polym. Bull., Vol. 41, No. 1, pp. 85-90, 1998.
[25]	R. R. Navarro, K. Sumi, M. Matsumura, “Improved metal affinity of chelating adsorbents through graft polymerization,” Water Res., Vol. 33, No. 9, pp. 2037-2044, 1999.
[26]	R. R. Navarro, K. Tatsumi, K. Sumi, M. Matsumura, “Role of anions on heavy metal sorption of a cellulose modified with poly (glycidyl methacrylate) and polyethyleneimine,” Water Res., Vol. 35, No. 11, pp. 2724-2730, 2001.
[27]	R. Molinari, P. Argurio, T. Poerio, “Comparison of polyethylenimine, polyacrylic acid and poly (dimethylamine-co-epichlorohydrin-co-ethylenediamine) in Cu2+ removal from wastewaters by polymer-assisted ultrafiltration,” Desalination, Vol. 162, No. 1-3, pp. 217-228, 2004.
[28]	S. M. Gawish, A. Kantouch, A. M. El Naggar, S. Mosleh, “Grafting of 2-(dimethylamino) ethyl-methacrylate onto gamma-irradiated polypropylene fablic,” J. Appl. Poylm. Sci., Vol. 44, No. 9, pp. 1671-1677, 1992.
[29]	K. Yamada, Y. Saitoh, Y. Haga, K. Matsuda, M. Hirata, “Adsorption and desorption properties of grafted polyethylene films modified with polyethylenimine chains,” J. Appl. Poylm. Sci., Vol. 102, No. 6, pp. 5965-5976, 2006.
[30]	D. Okamura, K. Saito, K. Sugita, M. Tamada, T. Sugo, “Effect of alcohol solvents for glycidyl methacrylate in radiation-induced graft polymerization on performance of cation-exchange porous membranes, Membrane, Vol. 27, No. 4, pp. 196-201, 2002 (in Japanese).
[31]	K. Yamada, J. Kimura, M. Hirata, “Surface Modification and Autohesive Properties of Poly (tetrafluoroethylene) and Polyethylene by the Photografting Technique,” J. Photopolym. Sci. Technol., Vol. 11, No. 2, pp. 263-270, 1998.
[32]	S. S. Mikhailova, O. M. Mykhaylyk, A. M. Dorfman, V. I. Povstugar, “XPS study of finely dispersed iron powders modified by radiation-grafted acrylamide,” Sur. Interface Anal., Vol. 29, No. 8, pp. 519-523, 2000.
[33]	A. Khot, A. Bailey, T. Debies, G. A. Takacs, “XPS studies of poly (acrylic acid) grafted onto UV photo-oxidized polystyrene surfaces,” J. Adhes. Sci. Technol., Vol. 26, No. 23, pp. 2627-2639, 2012.
[34]	K. Yamada, T. Gondo, M. Hirata, “Application of DMAEMA-grafted expanded PTFE films to positively charged ultrafiltration membranes and their electrostatic sieve separation properties,” J. Appl. Poylm. Sci., Vol. 81, No. 7, pp. 1595.-1604, 2001.
[35]	V. I. Vasil’eva, E. A. Goleva, “Selective separation of sodium ions from a mixture with phenylalanine by Donnan dialysis with a profiled sulfogroup cation exchange membrane,” Russ. J. Phys. Chem., Vol. 90, No. 10, pp. 2035-2043, 2016.
[36]	M. German, A. K. DenGupta, J. Greenleaf, “Hydrogen Ion (H+) in waste acid as a driver for environmentally sustainable processes: Opportunities and challenges,” Environ. Sci. Technol., Vol. 47, No. 5, pp. 2145-2150, 2013.
[37]	S. Tsukahara, B. Nanzai, M. Igawa, “Selective transport of amino acids across a double membrane system composed of a cation- and an anion-exchange membrane,” J. Memb. Sci., Vol. 448, pp. 300-307, 2013.
[38]	Y. Osada, Y. Takeuchi, “Water and protein permeation through polymeric membrane having mechanochemically expanding and contracting pores. Function of chemical valve. I,” J. Polym. Sci., Polym. Lett., Vol. 19, No. 6, pp. 303-308, 1981.

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Yuji Kimura, Kazunori Yamada. (2018). Selective Separation of Organic Electrolytes by Neutralization Dialysis with Grafted Polyethylene Films. International Journal of Materials Science and Applications, 7(3), 95-105. https://doi.org/10.11648/j.ijmsa.20180703.14

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ACS Style

Yuji Kimura; Kazunori Yamada. Selective Separation of Organic Electrolytes by Neutralization Dialysis with Grafted Polyethylene Films. Int. J. Mater. Sci. Appl. 2018, 7(3), 95-105. doi: 10.11648/j.ijmsa.20180703.14

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AMA Style

Yuji Kimura, Kazunori Yamada. Selective Separation of Organic Electrolytes by Neutralization Dialysis with Grafted Polyethylene Films. Int J Mater Sci Appl. 2018;7(3):95-105. doi: 10.11648/j.ijmsa.20180703.14

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@article{10.11648/j.ijmsa.20180703.14,
  author = {Yuji Kimura and Kazunori Yamada},
  title = {Selective Separation of Organic Electrolytes by Neutralization Dialysis with Grafted Polyethylene Films},
  journal = {International Journal of Materials Science and Applications},
  volume = {7},
  number = {3},
  pages = {95-105},
  doi = {10.11648/j.ijmsa.20180703.14},
  url = {https://doi.org/10.11648/j.ijmsa.20180703.14},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ijmsa.20180703.14},
  abstract = {The selective separation of organic electrolytes by neutralization dialysis was investigated with two kinds of grafted polyethylene (PE) films prepared through the photografting of 2-(dimethylamino) ethyl methacrylate (DMAEMA) onto the PE films and the subsequent quaternization and through the photografting of glycidyl methacrylate (GMA) and the subsequent sulfonation. The permeation flux of benzoic acid (BA) for the quarternized DMAEMA-grafted PE (PE-g-QPDMAEMA) films increased with an increase in the degree of quaternization, and the BA permeability had the maximum at the initial pH value of the permeate solution of 12.0. On the other hand, the sulfonation offered the phenylalaninol (Phl) permeability of the GMA-grafted PE (PE-g-PGMA) films. The selective separation for the binary BA/Phl or 2,5-dichlorobenzoic acid/Phl systems was successfully achieved by use of a pH difference between the feed and permeate solutions through the PE-g-QPDMAEMA and sulfonated PE-g-PGMA (PE-g-SPGMA) films. The maximum selective separation was obtained under the conditions that the initial pH values of the permeate solutions through the PE-g-QPDMAEMA and PE-g-SPGMA films were adjusted to 12.0 and 2.0, respectively. This procedure will be applied to separation and concentration of organic electrolytes and water purification.},
 year = {2018}
}

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TY  - JOUR
T1  - Selective Separation of Organic Electrolytes by Neutralization Dialysis with Grafted Polyethylene Films
AU  - Yuji Kimura
AU  - Kazunori Yamada
Y1  - 2018/04/26
PY  - 2018
N1  - https://doi.org/10.11648/j.ijmsa.20180703.14
DO  - 10.11648/j.ijmsa.20180703.14
T2  - International Journal of Materials Science and Applications
JF  - International Journal of Materials Science and Applications
JO  - International Journal of Materials Science and Applications
SP  - 95
EP  - 105
PB  - Science Publishing Group
SN  - 2327-2643
UR  - https://doi.org/10.11648/j.ijmsa.20180703.14
AB  - The selective separation of organic electrolytes by neutralization dialysis was investigated with two kinds of grafted polyethylene (PE) films prepared through the photografting of 2-(dimethylamino) ethyl methacrylate (DMAEMA) onto the PE films and the subsequent quaternization and through the photografting of glycidyl methacrylate (GMA) and the subsequent sulfonation. The permeation flux of benzoic acid (BA) for the quarternized DMAEMA-grafted PE (PE-g-QPDMAEMA) films increased with an increase in the degree of quaternization, and the BA permeability had the maximum at the initial pH value of the permeate solution of 12.0. On the other hand, the sulfonation offered the phenylalaninol (Phl) permeability of the GMA-grafted PE (PE-g-PGMA) films. The selective separation for the binary BA/Phl or 2,5-dichlorobenzoic acid/Phl systems was successfully achieved by use of a pH difference between the feed and permeate solutions through the PE-g-QPDMAEMA and sulfonated PE-g-PGMA (PE-g-SPGMA) films. The maximum selective separation was obtained under the conditions that the initial pH values of the permeate solutions through the PE-g-QPDMAEMA and PE-g-SPGMA films were adjusted to 12.0 and 2.0, respectively. This procedure will be applied to separation and concentration of organic electrolytes and water purification.
VL  - 7
IS  - 3
ER  -

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Author Information

Yuji Kimura

Department of Applied Molecular Chemistry, Nihon University, Narashino, Japan
Kazunori Yamada

Department of Applied Molecular Chemistry, Nihon University, Narashino, Japan

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Yuji Kimura, Kazunori Yamada. (2018). Selective Separation of Organic Electrolytes by Neutralization Dialysis with Grafted Polyethylene Films. International Journal of Materials Science and Applications, 7(3), 95-105. https://doi.org/10.11648/j.ijmsa.20180703.14

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ACS Style

Yuji Kimura; Kazunori Yamada. Selective Separation of Organic Electrolytes by Neutralization Dialysis with Grafted Polyethylene Films. Int. J. Mater. Sci. Appl. 2018, 7(3), 95-105. doi: 10.11648/j.ijmsa.20180703.14

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AMA Style

Yuji Kimura, Kazunori Yamada. Selective Separation of Organic Electrolytes by Neutralization Dialysis with Grafted Polyethylene Films. Int J Mater Sci Appl. 2018;7(3):95-105. doi: 10.11648/j.ijmsa.20180703.14

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@article{10.11648/j.ijmsa.20180703.14,
  author = {Yuji Kimura and Kazunori Yamada},
  title = {Selective Separation of Organic Electrolytes by Neutralization Dialysis with Grafted Polyethylene Films},
  journal = {International Journal of Materials Science and Applications},
  volume = {7},
  number = {3},
  pages = {95-105},
  doi = {10.11648/j.ijmsa.20180703.14},
  url = {https://doi.org/10.11648/j.ijmsa.20180703.14},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ijmsa.20180703.14},
  abstract = {The selective separation of organic electrolytes by neutralization dialysis was investigated with two kinds of grafted polyethylene (PE) films prepared through the photografting of 2-(dimethylamino) ethyl methacrylate (DMAEMA) onto the PE films and the subsequent quaternization and through the photografting of glycidyl methacrylate (GMA) and the subsequent sulfonation. The permeation flux of benzoic acid (BA) for the quarternized DMAEMA-grafted PE (PE-g-QPDMAEMA) films increased with an increase in the degree of quaternization, and the BA permeability had the maximum at the initial pH value of the permeate solution of 12.0. On the other hand, the sulfonation offered the phenylalaninol (Phl) permeability of the GMA-grafted PE (PE-g-PGMA) films. The selective separation for the binary BA/Phl or 2,5-dichlorobenzoic acid/Phl systems was successfully achieved by use of a pH difference between the feed and permeate solutions through the PE-g-QPDMAEMA and sulfonated PE-g-PGMA (PE-g-SPGMA) films. The maximum selective separation was obtained under the conditions that the initial pH values of the permeate solutions through the PE-g-QPDMAEMA and PE-g-SPGMA films were adjusted to 12.0 and 2.0, respectively. This procedure will be applied to separation and concentration of organic electrolytes and water purification.},
 year = {2018}
}

Copy | Download

TY  - JOUR
T1  - Selective Separation of Organic Electrolytes by Neutralization Dialysis with Grafted Polyethylene Films
AU  - Yuji Kimura
AU  - Kazunori Yamada
Y1  - 2018/04/26
PY  - 2018
N1  - https://doi.org/10.11648/j.ijmsa.20180703.14
DO  - 10.11648/j.ijmsa.20180703.14
T2  - International Journal of Materials Science and Applications
JF  - International Journal of Materials Science and Applications
JO  - International Journal of Materials Science and Applications
SP  - 95
EP  - 105
PB  - Science Publishing Group
SN  - 2327-2643
UR  - https://doi.org/10.11648/j.ijmsa.20180703.14
AB  - The selective separation of organic electrolytes by neutralization dialysis was investigated with two kinds of grafted polyethylene (PE) films prepared through the photografting of 2-(dimethylamino) ethyl methacrylate (DMAEMA) onto the PE films and the subsequent quaternization and through the photografting of glycidyl methacrylate (GMA) and the subsequent sulfonation. The permeation flux of benzoic acid (BA) for the quarternized DMAEMA-grafted PE (PE-g-QPDMAEMA) films increased with an increase in the degree of quaternization, and the BA permeability had the maximum at the initial pH value of the permeate solution of 12.0. On the other hand, the sulfonation offered the phenylalaninol (Phl) permeability of the GMA-grafted PE (PE-g-PGMA) films. The selective separation for the binary BA/Phl or 2,5-dichlorobenzoic acid/Phl systems was successfully achieved by use of a pH difference between the feed and permeate solutions through the PE-g-QPDMAEMA and sulfonated PE-g-PGMA (PE-g-SPGMA) films. The maximum selective separation was obtained under the conditions that the initial pH values of the permeate solutions through the PE-g-QPDMAEMA and PE-g-SPGMA films were adjusted to 12.0 and 2.0, respectively. This procedure will be applied to separation and concentration of organic electrolytes and water purification.
VL  - 7
IS  - 3
ER  -

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