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A Comparative Study of Metachromasy Induced in Azure B by Anionic Polyelctrolytes

Received: Sep. 06, 2014    Accepted: Sep. 23, 2014    Published: Sep. 23, 2014
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Abstract

The interaction of two cationic dyes, namely, Azure B (AB) with an anionic polyelectrolyte, namely, sodium heparinate (NaHep) has been investigated by Spectrophotometric method. The polymer induced metachromasy in the dyes resulting in the shift of the absorption maxima of the dyes towards shorter wavelengths. The stability of the complexes formed between Azure B and sodium alginate was found to be greater than that formed between Azure B and sodium carboxymethylcellulose.This fact was further confirmed by reversal studies using alcohols, urea surfactants and electrolytes.The interaction parametersrevealed that binding between Azure B and anionic poloyelectrolytes was mainly due to electrostaticinteraction.

DOI 10.11648/j.sjc.s.2014020602.12
Published in Science Journal of Chemistry ( Volume 2, Issue 6-2, December 2014 )

This article belongs to the Special Issue Polyelectrolytes & Dyes

Page(s) 8-13
Creative Commons

This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.

Copyright

Copyright © The Author(s), 2024. Published by Science Publishing Group

Keywords

Cationic Dye, Metachromasy, Anionicpolyelectrolytes, Electrostatic Interaction, Aggregation

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    Nandini Ratnakar. (2014). A Comparative Study of Metachromasy Induced in Azure B by Anionic Polyelctrolytes. Science Journal of Chemistry, 2(6-2), 8-13. https://doi.org/10.11648/j.sjc.s.2014020602.12

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    ACS Style

    Nandini Ratnakar. A Comparative Study of Metachromasy Induced in Azure B by Anionic Polyelctrolytes. Sci. J. Chem. 2014, 2(6-2), 8-13. doi: 10.11648/j.sjc.s.2014020602.12

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    AMA Style

    Nandini Ratnakar. A Comparative Study of Metachromasy Induced in Azure B by Anionic Polyelctrolytes. Sci J Chem. 2014;2(6-2):8-13. doi: 10.11648/j.sjc.s.2014020602.12

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  • @article{10.11648/j.sjc.s.2014020602.12,
      author = {Nandini Ratnakar},
      title = {A Comparative Study of Metachromasy Induced in Azure B by Anionic Polyelctrolytes},
      journal = {Science Journal of Chemistry},
      volume = {2},
      number = {6-2},
      pages = {8-13},
      doi = {10.11648/j.sjc.s.2014020602.12},
      url = {https://doi.org/10.11648/j.sjc.s.2014020602.12},
      eprint = {https://download.sciencepg.com/pdf/10.11648.j.sjc.s.2014020602.12},
      abstract = {The interaction of two cationic dyes, namely, Azure B (AB) with an anionic polyelectrolyte, namely, sodium heparinate (NaHep) has been investigated by Spectrophotometric method. The polymer induced metachromasy in the dyes resulting in the shift of the absorption maxima of the dyes towards shorter wavelengths. The stability of the complexes formed between Azure B and sodium alginate was found to be greater than that formed between Azure B and sodium carboxymethylcellulose.This fact was further confirmed by reversal studies using alcohols, urea surfactants and electrolytes.The interaction parametersrevealed that binding between Azure B and anionic poloyelectrolytes was mainly due to electrostaticinteraction.},
     year = {2014}
    }
    

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    T1  - A Comparative Study of Metachromasy Induced in Azure B by Anionic Polyelctrolytes
    AU  - Nandini Ratnakar
    Y1  - 2014/09/23
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    DO  - 10.11648/j.sjc.s.2014020602.12
    T2  - Science Journal of Chemistry
    JF  - Science Journal of Chemistry
    JO  - Science Journal of Chemistry
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    PB  - Science Publishing Group
    SN  - 2330-099X
    UR  - https://doi.org/10.11648/j.sjc.s.2014020602.12
    AB  - The interaction of two cationic dyes, namely, Azure B (AB) with an anionic polyelectrolyte, namely, sodium heparinate (NaHep) has been investigated by Spectrophotometric method. The polymer induced metachromasy in the dyes resulting in the shift of the absorption maxima of the dyes towards shorter wavelengths. The stability of the complexes formed between Azure B and sodium alginate was found to be greater than that formed between Azure B and sodium carboxymethylcellulose.This fact was further confirmed by reversal studies using alcohols, urea surfactants and electrolytes.The interaction parametersrevealed that binding between Azure B and anionic poloyelectrolytes was mainly due to electrostaticinteraction.
    VL  - 2
    IS  - 6-2
    ER  - 

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Author Information
  • Department of Chemistry, MITE, Moodabidri-574 226 (DK), Karnataka, India

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