In this article, we propose a simple and effective methods to resolve the reaction diffusion equation for facilitated emigration of planar electrode in a steady state non-linear process that arises in the context of the electroactive polymer film. The mathematical modeling presented here suggest a substrate and an immobilized catalyst form a complex. By applying the two effective analytical approach namely Homotopy Analysis Method and Exp-Function Method, an approximate analytical expression for the substrate concentration for planar electrode is established. Moreover, the analytical approach of the current for the experimental outcomes is established. The efficiency of the methods is demonstrated by contrasting the numerical simulation with the Analytical findings. The derived analytical outcomes are compared with numerical data which is obtained by using Matlab software and it is transpires that they correspond adequately. Also the comparison of computational outcomes with dimensionless concentration of planar electrode substrate in its analytical representation established in table. In these table results depicts for different amount of reaction and diffusion parameters our new result agree rather well with the numerical findings. The error percentage of our results employing Homotopy Analysis Method and Exp-Function Method with numerical results presented. The solution is also graphically presented. It provides a satisfactory agreement for all parameter setting under comparison.
Published in | Applied and Computational Mathematics (Volume 13, Issue 6) |
DOI | 10.11648/j.acm.20241306.13 |
Page(s) | 236-244 |
Creative Commons |
This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited. |
Copyright |
Copyright © The Author(s), 2024. Published by Science Publishing Group |
Mathematical Modeling, Nonlinear Differential Equation, Reaction Diffusion Equation, Electroactive Polymer Film, Homotopy Analysis Method, Exp-Function Method
[1] | Lyons, M. E. G. Electroactive Polymer Electrochemistry Part I, Fundamentals, (Plenum Press) Springer Publications, New York. 1994, XIV(488), 237-374. |
[2] | Lyons, M. E. G. Electroactive Polymer Electrochemistry: Fundamentals, Part II, (Plenum Press) Springer Publications, New York. 1994; 1-235. |
[3] | Lyons, M. E. G. Electrocatalysis using electroactive polymers, electroactive composites and micro heterogeneous systems. Analyst, 1994, 119(5), 805-826. |
[4] | Lyons, M. E. G., Transport and kinetics in electroactive polymers. Advances in chemical physics. 1996, 94, 297-624. |
[5] | Rajendran, L., Swaminathan, R., Chitra Devi, M. A closer look of Nonlinear reaction diffusion equations, Nova Publisher. New York, 2020. |
[6] | Hillman, A. R., Linford, R. G., Electrochemical Science and Technology of Polymers, Applied surface science. 1987, 103-291. |
[7] | Lyons, M. E. G., Greer, J. C., Fitzgerland, C. A., Bannon, T., Barlett, P. N. Reactional diffusion with Nlichaelis-Menten kinetics in electroactive polymer films part 1 the steady state amperometric response, Analyst. 1996, 121, 715-731. |
[8] | Evans, G. P. The electrochemistry of conducting polymers, In Advances in Electrochemical Science and Engineering. 1990, 1, 1-74. |
[9] | Rahamathunissa, G., Rajendran, L. Modeling of nonlinear reaction-diffusion processes of amperometric polymer-modified electrodes, Journal of Theory and Computational Chemistry. 2008, 7(1), 113-138. |
[10] | Wring, S. A., Hart, J. P. Chemically Modified Carbon-Based Electrodes and Their Application as Electrochemical Sensors for the Analysis of Biologically Important Compounds, Analyst. 1992, 117(8), 1215-1229. |
[11] | Albery, W. J., Hillman, A. R. Modified electrodes, Annual report section: Physical chemistry. 1981, 78, 77-437. |
[12] | Albery, W. J., Gass, A. E. G., Shu, Z. X. Inhibited enzyme electrodes part 1: Theoretical model, Biosensors and Bioelectronics. 1990, 5, 367-378. |
[13] | Albery, W. J., Gass, A. E. G., Shu, Z. X. Inhibited enzyme electrodes Part II: Theoretical model, Biosensors and Bioelectronics. 1990, 5(5), 379-395. |
[14] | Rajendran, L. Analytical Solution for the steady state Chronoamperometric current for an EC’ reaction at spheroidal ultra-micro electrodes, Journal of theoretical and computational chemistry. 2006, 5(1), 11-24. |
[15] | Swaminathan, R., Venugopal, K., Rasi, M., Abukhaled, M., Rajendran, L. Analytical expressions for the concentration and current in the reduction of hydrogen peroxide at a metal dispersed conducting polymer film, Quimica Nova. 2020, 43, 58-65. |
[16] | Pirabaharan, P., Chitra Devi, M., Swaminathan, R., Rajendran, L., Lyons, M. E. G. Modelling the current Response and Sensitivity of Oxidase Enzyme Electrodes, Monitored Amperometrically by the consumption of Oxygen, Journal of electrochemistry. 2022, 3(2), 309-321. |
[17] | Dharmalingam, K. M., Veeramuni, M. Analytical solution of electroactive polymer film using Agbari Ganji method, Journal of electroanalytical chemistry. 2019; 844: 1-55. |
[18] | Usha Rani, R., Rajendran, L. Taylor series method for solving nonlinear reaction diffusion equation in the electroactive polymer film, Chemical physics letter. 2020, 754, 137573. |
[19] | Rekha, S., Usha Rani, R., Rajendran, L., Lyons, M. E. G. A new method to study the nonlinear reaction diffusion process in the electroactive polymer film using hyperbolic function method, International journal of electrochemical science. 2022, 17, 221261. |
[20] | Lyons, M. E. G., Bannon, T., Hinds, G., Rebouillt, S. Reaction/Diffusion with Michaeli’s Menten kinetics in electroactive polymer films Part 1. The transient amerometric response, Analyst. 1998, 123, 1947-1959. |
[21] | Swaminathan R., Saravanakumar R., Venugopal K., Rajendarn. Analytical solution of nonlinear problems in homogeneous reactions occur in the mass transfer boundary layer: Homotopy perturbation method, International journal electrochemical science. 2001, 16, 210644. |
[22] | Swaminathan, R., Lakshmi Narayanan, K., Mohan, V., Saranya, K., Rajendran, L. Reaction diffusion equation with michalei’s Menten kinetics in micro disk biosensor: Homotopy perturbation method, International journal of electrochemical science. 2019, 14(4), 3777-3794. |
[23] | Reena A., Karpagavalli S., Rajendran L., Manimegali B., Swaminathan R. Theoretical analysis of putrescine enzymatic biosensor with optical oxygen transducer in sensitive layer using Akbari Ganji Method, International journal of electrochemical science. 2023, 18(5), 100113. |
[24] | Ranjani, K., Swaminathan, R., Karpagavalli, S. Mathematical Modelling of a mono enzyme dual amperometric biosensor for enzyme-catalyzed reactions using homotopy analysis method and Akbari Ganji Method, International journal of electrochemical science. 2023, 18(9), 100220. |
[25] | Lyons, M. E. G., Michas, A., Barlett, P. N. Amperometric chemical sensors using micro heterogeneous system, Analyst. 1992, 117(8), 1271-1280. |
[26] | Liao, S. J. On the homotopy analysis method for nonlinear problems, Applied Mathematics and Computation. 2004, 147(2), 499-513. |
[27] | Liao, SJ. Comparison between the homotopy analysis method and homotopy perturbation method. Applied Mathematics and Computation. 2005; 169(2): 1186 – 1194. |
[28] | Liao, SJ. Homotopy Analysis Method: A new analytic method for nonlinear problems, Applied Mathematics and Mechanics. 1998, 19(10), 957-962. |
[29] | Liao, SJ. and Antonio Campo. Analytic solutions of the temperature distribution in Blasius viscous flow problems, Journal of Fluid Mechanics. 2002, 453, 411-425. |
[30] | Liao, SJ. An optimal homotopy analysis approach for strongly nonlinear differential equations, Communications in nonlinear science and Numerical simulation. 2010, 15(8), 2003-2016. |
[31] | He, J. H., Hong, Wu X. Exp-Function Method for nonlinear wave equations, Chaos Solitons and. Fractals. 2006, 30(3), 700-708. |
[32] | Bekir, A., Boz, A. Exact solutions for nonlinear evolution equations using Exp-Function Method, Physics Letter A. 2008, 372(10), 1619-1625. |
APA Style
Andiappan, U., Rajagopal, S. (2024). Mathematical Modeling of Reaction Diffusion Equation for Facilitated Emigration of Planar Electrode in a Non-Linear Process at Electroactive Polymer Film. Applied and Computational Mathematics, 13(6), 236-244. https://doi.org/10.11648/j.acm.20241306.13
ACS Style
Andiappan, U.; Rajagopal, S. Mathematical Modeling of Reaction Diffusion Equation for Facilitated Emigration of Planar Electrode in a Non-Linear Process at Electroactive Polymer Film. Appl. Comput. Math. 2024, 13(6), 236-244. doi: 10.11648/j.acm.20241306.13
@article{10.11648/j.acm.20241306.13, author = {Uma Andiappan and Swaminathan Rajagopal}, title = {Mathematical Modeling of Reaction Diffusion Equation for Facilitated Emigration of Planar Electrode in a Non-Linear Process at Electroactive Polymer Film }, journal = {Applied and Computational Mathematics}, volume = {13}, number = {6}, pages = {236-244}, doi = {10.11648/j.acm.20241306.13}, url = {https://doi.org/10.11648/j.acm.20241306.13}, eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.acm.20241306.13}, abstract = {In this article, we propose a simple and effective methods to resolve the reaction diffusion equation for facilitated emigration of planar electrode in a steady state non-linear process that arises in the context of the electroactive polymer film. The mathematical modeling presented here suggest a substrate and an immobilized catalyst form a complex. By applying the two effective analytical approach namely Homotopy Analysis Method and Exp-Function Method, an approximate analytical expression for the substrate concentration for planar electrode is established. Moreover, the analytical approach of the current for the experimental outcomes is established. The efficiency of the methods is demonstrated by contrasting the numerical simulation with the Analytical findings. The derived analytical outcomes are compared with numerical data which is obtained by using Matlab software and it is transpires that they correspond adequately. Also the comparison of computational outcomes with dimensionless concentration of planar electrode substrate in its analytical representation established in table. In these table results depicts for different amount of reaction and diffusion parameters our new result agree rather well with the numerical findings. The error percentage of our results employing Homotopy Analysis Method and Exp-Function Method with numerical results presented. The solution is also graphically presented. It provides a satisfactory agreement for all parameter setting under comparison. }, year = {2024} }
TY - JOUR T1 - Mathematical Modeling of Reaction Diffusion Equation for Facilitated Emigration of Planar Electrode in a Non-Linear Process at Electroactive Polymer Film AU - Uma Andiappan AU - Swaminathan Rajagopal Y1 - 2024/12/30 PY - 2024 N1 - https://doi.org/10.11648/j.acm.20241306.13 DO - 10.11648/j.acm.20241306.13 T2 - Applied and Computational Mathematics JF - Applied and Computational Mathematics JO - Applied and Computational Mathematics SP - 236 EP - 244 PB - Science Publishing Group SN - 2328-5613 UR - https://doi.org/10.11648/j.acm.20241306.13 AB - In this article, we propose a simple and effective methods to resolve the reaction diffusion equation for facilitated emigration of planar electrode in a steady state non-linear process that arises in the context of the electroactive polymer film. The mathematical modeling presented here suggest a substrate and an immobilized catalyst form a complex. By applying the two effective analytical approach namely Homotopy Analysis Method and Exp-Function Method, an approximate analytical expression for the substrate concentration for planar electrode is established. Moreover, the analytical approach of the current for the experimental outcomes is established. The efficiency of the methods is demonstrated by contrasting the numerical simulation with the Analytical findings. The derived analytical outcomes are compared with numerical data which is obtained by using Matlab software and it is transpires that they correspond adequately. Also the comparison of computational outcomes with dimensionless concentration of planar electrode substrate in its analytical representation established in table. In these table results depicts for different amount of reaction and diffusion parameters our new result agree rather well with the numerical findings. The error percentage of our results employing Homotopy Analysis Method and Exp-Function Method with numerical results presented. The solution is also graphically presented. It provides a satisfactory agreement for all parameter setting under comparison. VL - 13 IS - 6 ER -