Research Article | | Peer-Reviewed

Multivariate Study of Heavy Metals, Dissolved Salts and Physicochemical Properties of Shetiko River Water, Kuje, Federal Capital Territory, Nigeria

Received: 14 January 2025     Accepted: 1 February 2025     Published: 6 June 2025
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Abstract

Nigeria's extensive inland water resources are a significant asset, but they face severe threats from pollution driven by rapid urbanization, industrial activities, and inadequate waste management. The Shetiko River, like many others, plays a crucial role in supporting human activities such as sanitation, transportation, and irrigation. However, its vulnerability to contamination, particularly from untreated domestic, industrial, and agricultural waste, has led to ecological degradation, changes in ecosystem functions, and heightened health risks. This study analyzed water quality dynamics of Shetiko River by examining factors influencing heavy metals, physicochemical properties, and salinity (ionic content). Shetiko is located in Kuje, Federal Capital Territory (FCT), Abuja, Nigeria. Factor Analysis and Independent t-tests were used to identify the dimensionality and variation in water quality of Shetiko River. A rotated factor matrix identified three primary dimensions of water quality: heavy metal pollution (Factor 1), general physicochemical conditions (Factor 2), and ionic/salinity contributions (Factor 3). Seasonal variations indicated higher heavy metal and salinity levels during the wet season due to runoff, while the dry season exhibited more stable physicochemical properties. Locational differences revealed elevated heavy metal concentrations downstream, linked to anthropogenic activities, and higher salinity levels upstream, influenced by geological factors. Physicochemical conditions showed minimal variation across locations. These findings underscore the critical need for targeted water management strategies addressing seasonal and spatial variations to safeguard water resources and mitigate pollution impacts.

Published in American Journal of Biological and Environmental Statistics (Volume 11, Issue 2)
DOI 10.11648/j.ajbes.20251102.12
Page(s) 28-41
Creative Commons

This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.

Copyright

Copyright © The Author(s), 2025. Published by Science Publishing Group

Keywords

Water Pollution, Heavy Metals, Physicochemical Properties, Salinity, Factor Analysis

1. Introduction
Nigeria is endowed with an estimated 283,293.47 hectares of inland water resources, a significant blessing for the nation However, these valuable resources are under threat due to widespread pollution. The river as a major water source has so many benefits for human life, such as for sanitation, transportation, irrigation, and others. However, the quality of river water is also very much needed by social activities around it. Rapid urbanization and industrial growth have resulted in an increase in untreated waste from many sectors discharged into the Rivers . Rivers, as a recipient of wastewater, both domestic and industrial wastes, are vulnerable to pollution. This condition causes changes in ecosystem function, ecological status, and pollution in the River . Limited sanitation facilities for residents, industry non-compliance with wastewater disposal regulations, untreated livestock wastewater, and dumping of garbage into rivers have contributed to the decline in river water quality.
The presence of pollutants in these water bodies poses serious health risks, making it a major concern . Urban inland water systems are particularly vulnerable, with pollution levels increasing at an alarming rate. Water quality encompasses the physical, chemical, and biological properties that make water suitable for various human uses . As water resource planning and development become increasingly crucial for drinking, industrial, and irrigation purposes, understanding water quality has taken centre stage .
Globally, irrigation water quality is a growing concern due to agricultural intensification, climate change, and over-reliance on ground aquifers in arid and semi-arid regions . Irrigation requires not only sufficient water quantity but also good water quality to maintain soil health, crop quality, and ecosystem balance . However, irrigation water from surface or ground aquifers often contains high levels of salts and chemicals that can impact crop yields and soil fertility .
The quality of irrigation water is determined by the concentration and composition of soluble salts, which can accumulate in the root zone, limiting water availability, causing plant stress, and ultimately reducing crop yields . The quality of irrigation water varies significantly depending on its source and location .
Extensive research has been conducted globally, including in Pakistan, to evaluate the quality of irrigation water from diverse sources, highlighting the need for location-specific assessments . The buildup of salts in the root zone can severely impact plant growth, reducing water availability and uptake, causing stress, and ultimately leading to decreased crop yields . Furthermore, high salt concentrations can disrupt the balance of essential plant nutrients in the soil, and some salts can be toxic to certain plant species . Besides dissolved salts, a long-standing issue, irrigation water often contains substances from both natural and human-made sources . The chemical composition of irrigation water can directly affect plant growth through toxicity or nutrient deficiencies, or indirectly by altering nutrient availability . Moreover, the presence of certain metals in irrigation water can also have detrimental effects on crop production .
Several studies have been conducted throughout the world to assess the irrigation water quality of different water sources. The farmers in Shetuko and mainly Kuje depend mainly on the Shetiko river for irrigation. However, knowledge of the irrigation water quality in the region is very limited, or rather nonexistent. Data on the physicochemical properties and the heavy metal levels of the Shetuko irrigation water and their implications for agriculture and ecosystems is out rightly lacking.
Therefore, the present study explores the irrigation water quality in Shetuko River situated in the Kuje Area Council of Abuja intending to investigate: (a) physicochemical properties of the irrigation water, (b) Heavy metal Pollution levels and other dissolved salts.
2. Methodology
Multivariate Factor Analysis technique and tt test for comparing seasonal variations are used in this study.
2.1. Study Area
Shetiko is situated in Kuje. Kuje is in the south-eastern part of Federal Capital Territory, Abuja. It lies between latitudes 080 53’ 24’’ N and 080 53’ 47’’ N and longitudes 070 14’ 24’’ E and 070 14’ 35’’ E. It is located at about 13.2 km from Abuja municipality. It has an area of 1,644 km2, an average temperature of 30 degrees Celsius, a total area of 1,644 square kilometers and a population of 97,367 at the 2006 census. The dry and rainy seasons are the two distinct seasons that the Area Council encounters.
In Kuje Area Council, the annual precipitation total is estimated to be 1250 mm, with an average humidity of 41%. In Shetiko, there is a river that meanders gently along Gwagwa and Sauka in natural channels with sandy banks to Gwagwalada. “For the fact that only the community has access road to the river, people named it ‘Shetiko River’ but it is originally called River Sumon”. Located in Kuje Area Council of the FCT, Shetiko is a rural community that is increasingly transforming into suburban city. (Daily Trust, 2015). While many rural communities are battling with shortage of water which has forced them to source water from contaminated streams due to unavailability of boreholes, Shetiko is blessed with abundant water resources. The rapid development the community witnesses could be attributed to its nearness to Kuje main town. Government presence in terms of social amenities can be felt in Shetiko.
2.2. Data Collection
The sampling points were located at Gudaba, Shetiko, Kiyi and finally at Chikuku at four different points of the river, a total of 64 samples (9 from each point of the river dry and wet seasons) were collected in one-liter polyethylene bottles that were pre-washed with 10%, v/v HNO3 acid and also rinsed with deionized water, capped and labeled, each point were recorded using the GPS recorder. The River water collection were carried out separately during the two common seasons (dry and wet seasons) February and August in a year (2022), for the analysis. For the heavy metal determination, 0.2 ml of 65% HNO3 and 0.125 ml of 70% HClO4 acid mixtures were added to 45 ml which were digested in a closed Teflon reactor for 8hrs at 120°C, cooled and diluted up to 50 ml in a volumetric flask and the heavy metal analysis were The analysis was done using the AAS machines at the laboratory (Advanced Chemistry Laboratory, Sheda Science and Technology Complex Abuja-SHESTCO). For the physicochemical analysis, (pH), Electrical Conductivity (EC) and Total Dissolved Solids (TDS) were analyzed instantly in the field, TDS were determined by a Hanna Combo pH/TDS/Conductivity Tester model number HI98130, while PH and EC were determined by an Oakton pH/mV/Conductivity/C°/F° meter PC 700, while for analyses of the remaining parameters the samples were brought to the laboratory and stored in a refrigerator at 4OC other parameters were determined using the procedure as seen in .
2.3. Factor Analysis Model
Factor analysis is a multivariate technique that possibly describes the covariance relationships among variables in terms of a few underlying unobservable random quantities called factors . It is rightly used when there is a systematic interdependence among a set of observed variables and the researcher is interested in finding out something more latent which creates the commonality. Factor analysis therefore resolves a large set of measured variables in terms of relatively few categories called factors .
2.4. Definitions of Terms used in Factor Analysis
1) Factor: A factor is an underlying dimension that account for several observed variables.
2) Factor Loadings: Factor loadings are values that explain how closely the variables are related to each one of the factors observed.
3) Latent Root: Latent root otherwise known as eigen value indicates the relative significance of each factor in accounting for the particular set of variables that are analyzed.
4) Factor Score: A Factor score represents the degree to which each respondent gets high scores on the group of items that load high on each other.
5) Rotation: After extracting factors in a factor analysis, rotation is often applied to make the results easier to interpret. This process adjusts the factor loadings, which represent the relationships between observed variables and underlying factors, without changing the overall fit of the model. If the factors are independent, orthogonal rotation applies and the factors are correlated, an oblique rotation is involved.
6) Communality (h2): Communality indicates how much of each variable is accounted for the underlying factor taken together. A high value of communality implies that not much of the variable is remaining after whatever the factors represent is taken into account.
2.5. Orthogonal Factor Model
Let the unobservable random variable X with t components have thr mean and covariance matrix . In the factor model, X is linearly dependent on a few unobservable random variables variables and t additional sources of variation . The factor analysis model is given as:
(1)
Equation (1) can be written in a matrix form as:
(2)
where
The Coefficient is the loading of the ith variable on the jth factor;
The Matrix L is the matrix of factor loadings;
The ith specific factor is associated only with the ith response X;
The t deviations , ,…, are expressed in terms of t + k random variables ,
2.6. Assumptions of the Random Vectors F and ε
(3)
F and are independent so that
(4)
2.7. Covariance Structure of X
The covariance structure for X is generated from the assumptions of random vectors
F and which constitute the orthogonal factor model as follows:
(5)
Thus,
(6)
By orthogonal factor model, we have:
(7)
(8)
Therefore, the covariance structure for the orthogonal factor model is of the form:
(9)
(10)
(11)
where is the commonality and is the specific variance
(12)
(13)
See .
3. Discussion of Results
Table 1. Heavy Metals Upstream Wet Season Results.

SN

HEAVY METAL

SAMPLE ID

Replicate 1

Replicate 2

Replicate 3

MEAN± SD

1

Lead (Pb)

StWtUp-1

0.041

0.043

0.039

0.041 ± 0.002

2

StWtUp-2

0.038

0.042

0.040

0.040 ± 0.002

3

StWtUp-3

0.042

0.041

0.043

0.042 ± 0.001

4

Cadmium (Cd)

StWtUp-1

0.010

0.012

0.011

0.011 ± 0.001

5

StWtUp-2

0.012

0.011

0.013

0.012 ± 0.001

6

StWtUp-3

0.011

0.012

0.010

0.011 ± 0.001

7

Chromium (Cr)

StWtUp-1

0.140

0.145

0.142

0.142 ± 0.003

8

StWtUp-2

0.142

0.140

0.144

0.142 ± 0.002

9

StWtUp-3

0.145

0.143

0.141

0.143 ± 0.002

10

Copper (Cu)

StWtUp-1

0.075

0.080

0.078

0.078 ± 0.003

11

StWtUp-2

0.080

0.078

0.082

0.080 ± 0.002

12

StWtUp-3

0.078

0.080

0.079

0.079 ± 0.001

13

Zinc (Zn)

StWtUp-1

0.450

0.460

0.455

0.455 ± 0.005

14

StWtUp-2

0.460

0.450

0.465

0.458 ± 0.007

15

StWtUp-3

0.455

0.465

0.450

0.457 ± 0.007

16

Arsenic (As)

StWtUp-1

0.0045

0.0055

0.005

0.005 ± 0.0005

17

StWtUp-2

0.0055

0.0045

0.006

0.0053 ± 0.001

18

StWtUp-3

0.005

0.006

0.0045

0.0052 ± 0.001

19

Mercury (Hg)

StWtUp-1

0.0005

0.0006

0.00055

0.00055 ± 0.00005

20

StWtUp-2

0.0006

0.0005

0.0007

0.0006 ± 0.0001

21

StWtUp-3

0.00055

0.0007

0.0005

0.00057 ± 0.0001

Table 2. Heavy Metals Downstream Wet Season Results.

SN

HEAVY METAL

SAMPLE ID

Replicate 1

Replicate 2

Replicate 3

MEAN± SD

1

Lead (Pb)

StWtDn-1

0.060

0.065

0.062

0.062 ± 0.003

2

StWtDn-2

0.065

0.060

0.068

0.064 ± 0.004

3

StWtDn-3

0.062

0.065

0.061

0.063 ± 0.002

4

Cadmium (Cd)

StWtDn-1

0.018

0.020

0.019

0.019 ± 0.001

5

StWtDn-2

0.020

0.019

0.022

0.020 ± 0.002

6

StWtDn-3

0.019

0.021

0.018

0.019 ± 0.002

7

Chromium (Cr)

StWtDn-1

0.250

0.260

0.255

0.255 ± 0.005

8

StWtDn-2

0.260

0.250

0.265

0.258 ± 0.007

9

StWtDn-3

0.255

0.265

0.250

0.257 ± 0.007

10

Copper (Cu)

StWtDn-1

0.120

0.125

0.123

0.123 ± 0.003

11

StWtDn-2

0.125

0.120

0.130

0.125 ± 0.005

12

StWtDn-3

0.123

0.130

0.120

0.124 ± 0.003

13

Zinc (Zn)

StWtDn-1

0.630

0.645

0.638

0.638 ± 0.007

14

StWtDn-2

0.645

0.630

0.655

0.643 ± 0.012

15

StWtDn-3

0.638

0.655

0.630

|0.641 ± 0.012

16

Arsenic (As)

StWtDn-1

0.013

0.0145

0.01375

0.01375 ± 0.001

17

StWtDn-2

0.0145

0.013

0.0155

0.0143 ± 0.0015

18

StWtDn-3

0.01375

0.0155

0.013

0.0141 ± 0.0015

19

Mercury (Hg)

StWtDn-1

0.0022

0.0025

0.00235

0.00235 ± 0.00015

20

StWtDn-2

0.0025

0.0022

0.0028

0.0025 ± 0.0003

21

StWtDn-3

0.00235

0.0028

0.0022

0.00245 ± 0.0003

Table 3. Heavy Metals Upstream Dry Season Results.

SN

HEAVY METAL

SAMPLE ID

Replicate 1

Replicate 2

Replicate 3

MEAN± SD

1

Lead (Pb)

StDrUp-1

0.058

0.062

0.060

0.060 ± 0.002

2

StDrUp-2

0.062

0.058

0.065

0.062 ± 0.004

3

StDrUp-3

0.060

0.065

0.058

0.061 ± 0.003

4

Cadmium (Cd)

StDrUp-1

0.015

0.018

0.016

0.016 ± 0.002

5

StDrUp-2

0.018

0.015

0.020

0.018 ± 0.003

6

StDrUp-3

0.016

0.020

0.015

0.017 ± 0.003

7

Chromium (Cr)

StDrUp-1

0.200

0.210

0.205

0.205 ± 0.005

8

StDrUp-2

0.210

0.200

0.215

0.208 ± 0.007

9

StDrUp-3

0.205

0.215

0.200

0.207 ± 0.007

10

Copper (Cu)

StDrUp-1

0.100

0.105

0.103

0.103 ± 0.003

11

StDrUp-2

0.105

0.100

0.110

0.105 ± 0.005

12

StDrUp-3

0.103

0.110

0.100

0.104 ± 0.005

13

Zinc (Zn)

StDrUp-1

0.600

0.615

0.608

0.608 ± 0.007

14

StDrUp-2

0.615

0.600

0.625

0.613 ± 0.012

15

StDrUp-3

0.608

0.625

0.600

0.611 ± 0.012

16

Arsenic (As)

StDrUp-1

0.0075

0.0085

0.008

0.008 ± 0.0005

17

StDrUp-2

0.0085

0.0075

0.009

0.0087 ± 0.001

18

StDrUp-3

0.008

0.009

0.0075

0.0082 ± 0.001

19

Mercury (Hg)

StDrUp-1

0.0008

0.0009

0.00085

0.00087 ± 0.00005

20

StDrUp-2

0.0009

0.0008

0.001

0.00093 ± 0.0001

21

StDrUp-3

0.00085

0.001

0.0008

0.00088 ± 0.0001

Table 4. Heavy Metals Downstream Dry Season Results.

SN

HEAVY METAL

SAMPLE ID

Replicate 1

Replicate 2

Replicate 3

MEAN± SD

1

Lead (Pb)

StDrDn-1

0.090

0.095

0.093

0.093 ± 0.003

2

StDrDn-2

0.095

0.090

0.100

0.095 ± 0.005

3

StDrDn-3

0.093

0.100

0.090

0.094 ± 0.005

4

Cadmium (Cd)

StDrDn-1

0.025

0.028

0.026

0.026 ± 0.002

5

StDrDn-2

0.028

0.025

0.030

0.028 ± 0.003

6

StDrDn-3

0.026

0.030

0.025

|0.027 ± 0.003

7

Chromium (Cr)

StDrDn-1

0.300

0.310

0.305

0.305 ± 0.005

8

StDrDn-2

0.310

0.300

0.315

0.308 ± 0.007

9

StDrDn-3

0.305

0.315

0.300

0.307 ± 0.007

10

Copper (Cu)

StDrDn-1

0.150

0.155

0.153

0.153 ± 0.003

11

StDrDn-2

0.155

0.150

0.160

0.155 ± 0.005

12

StDrDn-3

0.153

0.160

0.150

0.152 ± 0.005

13

Zinc (Zn)

StDrDn-1

1.020

1.035

1.028

1.028 ± 0.007

14

StDrDn-2

1.035

1.020

1.045

1.033 ± 0.012

15

StDrDn-3

1.028

1.045

1.020

1.031 ± 0.012

16

Arsenic (As)

StDrDn-1

0.022

0.0235

0.0225

0.0227 ± 0.001

17

StDrDn-2

0.0235

0.022

0.0245

0.0237 ± 0.0015

18

StDrDn-3

0.0225

0.0245

0.022

0.023 ± 0.0015

19

Mercury (Hg)

StDrDn-1

0.0042

0.0045

0.00435

0.00437 ± 0.00015

20

StDrDn-2

0.0045

0.0042

0.0048

0.0045 ± 0.0003

21

StDrDn-3

0.00435

0.0048

0.0042

0.00445 ± 0.0003

Table 5. Physicochemical Downstream the Dry Season.

SN

Parameter

Unit

Sample ID

Replicate 1

Replicate 2

Replicate 3

MEAN± SD

1

pH

-

StWtUp-1

8.2

8.3

8.1

8.2 ± 0.1

2

StWtUp-2

8.3

8.2

8.4

8.3 ± 0.1

3

StWtUp-3

8.1

8.4

8.2

8.2 ± 0.1

4

Temperature

°C

StWtUp-1

28.5

28.8

28.2

28.5 ± 0.3

5

StWtUp-2

28.8

28.5

29.1

28.8 ± 0.3

6

StWtUp-3

28.2

29.1

28.5

28.6 ± 0.4

7

Conductivity

μS/cm

StWtUp-1

| 600

610

590

600 ± 10

8

StWtUp-2

610

600

620

610 ± 10

9

StWtUp-3

590

620

600

603.3 ± 15

10

TDS

mg/L

StWtUp-1

360

365

355

360 ± 5

11

StWtUp-2

365

360

370

365 ± 5

12

StWtUp-3

355

370

360

361.7 ± 7.5

13

Turbidity

NTU

StWtUp-1

15

16

14

15 ± 1

14

StWtUp-2

16

15

17

16 ± 1

15

StWtUp-3

14

17

15

15.3 ± 1.5

16

Alkalinity |

mg/L

StWtUp-1

200

205

195

200 ± 5

17

StWtUp-2

205

200

210

205 ± 5

18

StWtUp-3

195

210

200

201.7 ± 7.5

19

Hardness

mg/L

StWtUp-1

300

305

295

300 ± 5

20

StWtUp-2

305

300

310

305 ± 5

21

StWtUp-3

295

310

300

301.7 ± 7.5

22

Calcium

mg/L

StWtUp-1

80

85

75

80 ± 5

23

StWtUp-2

85

80

90

85 ± 5

24

StWtUp-3

75

90

80

81.7 ± 7.5

25

Magnesium

mg/L

StWtUp-1

40

45

35

40 ± 5

26

StWtUp-2

45

40

50

45 ± 5

27

StWtUp-3

35

50

40

41.7 ± 7.5

28

Chloride

mg/L

StWtUp-1

50

55

45

50 ± 5

29

StWtUp-2

55

50

60

55 ± 5

30

StWtUp-3

45

60

50

51.7 ± 7.5

31

Nitrate

mg/L

StWtUp-1

10

12

8

10 ± 2

32

StWtUp-2

12

10

14

12 ± 2

33

StWtUp-3

8

14

10

10.7 ± 3

34

Phosphate

mg/L

StWtUp-1

1.10

1.15

1.05

1.10 ± 0.05

35

StWtUp-2

1.15

1.10

1.20

1.15 ± 0.05

36

StWtUp-3

1.05

1.20

1.10

1.12 ± 0.07

Table 6. Physicochemical Upstream During the Dry Season.

SN

Parameter

Unit

Sample ID

Replicate 1

Replicate 2

Replicate 3

MEAN± SD

1

PH

-

StWtUp-1

7.8

7.9

7.7

7.8 ± 0.1

2

StWtUp-2

7.9

7.8

8.0

7.9 ± 0.1

3

StWtUp-3

7.7

8.0

7.8

7.8 ± 0.1

4

Temperature

°C

StWtUp-1

26.5

26.8

26.2

26.5 ± 0.3

5

StWtUp-2

26.8

26.5

27.1

26.8 ± 0.3

6

StWtUp-3

26.2

27.1

26.5

26.6 ± 0.4

7

Conductivity

μS/cm

StWtUp-1

400

410

390

400 ± 10

8

StWtUp-2

410

400

420

410 ± 10

9

StWtUp-3

390

420

400

403.3 ± 15

10

TDS

mg/L

StWtUp-1

240

245

235

240 ± 5

11

StWtUp-2

245

240

250

245 ± 5

12

StWtUp-3

235

250

240

241.7 ± 7.5

13

Turbidity

NTU

StWtUp-1

10

11

9

10 ± 1

14

StWtUp-2

11

10

12

11 ± 1

15

StWtUp-3

9

12

10

10.3 ± 1.5

16

Alkalinity |

mg/L

StWtUp-1

150

155

145

150 ± 5

17

StWtUp-2

155

150

160

155 ± 5

18

StWtUp-3

145

160

150

151.7 ± 7.5

19

Hardness

mg/L

StWtUp-1

220

225

215

220 ± 5

20

StWtUp-2

225

220

230

225 ± 5

21

StWtUp-3

215

230

220

221.7 ± 7.5

22

Calcium

mg/L

StWtUp-1

60

65

55

60 ± 5

23

StWtUp-2

65

60

70

65 ± 5

24

StWtUp-3

55

70

60

61.7 ± 7.5

25

Magnesium

mg/L

StWtUp-1

30

35

25

30 ± 5

26

StWtUp-2

35

30

40

35 ± 5

27

StWtUp-3

25

40

30

31.7 ± 7.5

28

Chloride

mg/L

StWtUp-1

40

45

35

40 ± 5

29

StWtUp-2

45

40

50

45 ± 5

30

StWtUp-3

35

50

40

41.7 ± 7.5

31

Nitrate

mg/L

StWtUp-1

8

10

6

8 ± 2

32

StWtUp-2

10

8

12

10 ± 2

33

StWtUp-3

6

12

8

8.7 ± 3

34

Phosphate

mg/L

StWtUp-1

0.80

0.85

0.75

0.80 ± 0.05

35

StWtUp-2

0.85

0.80

0.90

0.85 ± 0.05

36

StWtUp-3

0.75

0.90

0.80

0.82 ± 0.07

Table 7. Physicochemical Upstream During the Wet Season NEW.

SN

Parameter

Unit

Sample ID

Replicate 1

Replicate 2

Replicate 3

MEAN± SD

1

pH

-

StWtUp-1

7.2

7.3

7.1

7.2 ± 0.1

2

StWtUp-2

7.3

7.2

7.4

7.3 ± 0.1

3

StWtUp-3

7.1

7.4

7.2

7.2 ± 0.1

4

Temperature

°C

StWtUp-1

22.5

22.8

22.2

22.5 ± 0.3

5

StWtUp-2

22.8

22.5

23.1

22.8 ± 0.3

6

StWtUp-3

22.2

23.1

22.5

22.6 ± 0.4

7

Conductivity

μS/cm

StWtUp-1

350

360

340

350 ± 10

8

StWtUp-2

360

350

370

360 ± 10

9

StWtUp-3

340

370

350

353.3 ± 15

10

TDS

mg/L

StWtUp-1

210

215

205

210 ± 5

11

StWtUp-2

215

210

220

215 ± 5

12

StWtUp-3

205

220

210

211.7 ± 7.5

13

Turbidity

NTU

StWtUp-1

8

9

7

8 ± 1

14

StWtUp-2

9

8

10

9 ± 1

15

StWtUp-3

7

10

8

8.3 ± 1.5

16

Alkalinity |

mg/L

StWtUp-1

140

145

135

140 ± 5

17

StWtUp-2

145

140

150

145 ± 5

18

StWtUp-3

135

150

140

141.7 ± 7.5

19

Hardness

mg/L

StWtUp-1

200

205

195

200 ± 5

20

StWtUp-2

205

200

210

205 ± 5

21

StWtUp-3

195

210

200

201.7 ± 7.5

22

Calcium

mg/L

StWtUp-1

50

55

45

50 ± 5

23

StWtUp-2

55

50

60

55 ± 5

24

StWtUp-3

45

60

50

51.7 ± 7.5

25

Magnesium

mg/L

StWtUp-1

30

35

25

30 ± 5

26

StWtUp-2

35

30

40

35 ± 5

27

StWtUp-3

25

40

30

31.7 ± 7.5

28

Chloride

mg/L

StWtUp-1

40

45

35

40 ± 5

29

StWtUp-2

45

40

50

45 ± 5

30

StWtUp-3

35

50

40

41.7 ± 7.5

31

Nitrate

mg/L

StWtUp-1

6

8

4

6 ± 2

32

StWtUp-2

8

6

10

8 ± 2

33

StWtUp-3

4

10

6

6.7 ± 3

34

Phosphate

mg/L

StWtUp-1

0.38

0.42

0.35

0.38 ± 0.04

35

StWtUp-2

0.42

0.38

0.45

0.42 ± 0.04

36

StWtUp-3

0.35

0.45

0.38

0.39 ± 0.05

Table 8. Physicochemical Downstream During Wet Season.

SN

Parameter

Unit

Sample ID

Replicate 1

Replicate 2

Replicate 3

MEAN± SD

1

PH

-

StWtUp-1

7.5

7.6

7.4

7.5 ± 0.1

2

StWtUp-2

7.6

7.5

7.7

7.6 ± 0.1

3

StWtUp-3

7.4

7.7

7.5

7.5 ± 0.1

4

Temperature

°C

StWtUp-1

24.5

24.8

24.2

24.5 ± 0.3

5

StWtUp-2

24.8

24.5

25.1

24.8 ± 0.3

6

StWtUp-3

24.2

25.1

24.5

24.6 ± 0.4

7

Conductivity

μS/cm

StWtUp-1

450

460

440

450 ± 10

8

StWtUp-2

460

450

470

460 ± 10

9

StWtUp-3

440

470

450

453.3 ± 15

10

TDS

mg/L

StWtUp-1

270

275

265

270 ± 5

11

StWtUp-2

275

270

280

275 ± 5

12

StWtUp-3

265

280

270

271.7 ± 7.5

13

Turbidity

NTU

StWtUp-1

12

13

11

12 ± 1

14

StWtUp-2

13

12

14

13 ± 1

15

StWtUp-3

11

14

12

12.3 ± 1.5

16

Alkalinity |

mg/L

StWtUp-1

180

185

175

180 ± 5

17

StWtUp-2

185

180

190

185 ± 5

18

StWtUp-3

175

190

180

181.7 ± 7.5

19

Hardness

mg/L

StWtUp-1

250

255

245

250 ± 5

20

StWtUp-2

255

250

260

255 ± 5

21

StWtUp-3

245

260

250

251.7 ± 7.5

22

Calcium

mg/L

StWtUp-1

70

75

5

70 ± 5

23

StWtUp-2

75

70

80

75 ± 5

24

StWtUp-3

65

80

70

71.7 ± 7.5

25

Magnesium

mg/L

StWtUp-1

40

45

35

40 ± 5

26

StWtUp-2

45

40

50

45 ± 5

27

StWtUp-3

35

50

40

41.7 ± 7.5

28

Chloride

mg/L

StWtUp-1

60

65

55

60 ± 5

29

StWtUp-2

65

60

70

65 ± 5

30

StWtUp-3

55

70

60

61.7 ± 7.5

31

Nitrate

mg/L

StWtUp-1

10

12

8

10 ± 2

32

StWtUp-2

12

10

14

12 ± 2

33

StWtUp-3

8

14

10

10.7 ± 3

34

Phosphate

mg/L

StWtUp-1

0.60

0.65

0.55

0.60 ± 0.05

35

StWtUp-2

0.65

0.60

0.70

0.65 ± 0.05

36

StWtUp-3

0.55

0.70

0.60

0.62 ± 0.07

Note: Sample label connotation: StWtUp = Stream water Upstream, StWtDn = Stream water Wet season Downstream, StDrUp = Stream water Dry Season Upstream, and StDrDn = Stream water Dry Season Down stream
Table 9. Rotated Factor Loadings of the Extracted Three (3) Factors.

Factor

1

2

3

Lead

.821

-.529

-.162

Cadmium

.901

-.410

-.122

Chromium

.816

-.460

-.302

Cupper

.857

-.433

-.275

Zinc

.793

-.502

-.226

Arsenic

.880

-.332

-.330

Mercury

.875

-.270

-.377

pH

-.421

.889

.157

Temp

-.515

.833

.061

Conductivity

-.633

.636

.309

TDS

-.644

.629

.298

Turbidity

-.512

.639

.545

Calcium

-.245

.584

.445

Magnesium

-.053

.131

.618

Chloride

-.329

-.078

.949

Nitrate

-.267

.342

.744

Phosphate

-.497

.859

.103

The rotated factor matrix in Table 9 reveals how the variables are grouped into three distinct factors based on their relationships, with higher factor loadings indicating stronger associations.
Factor 1 is strongly associated with heavy metals, including lead, cadmium, chromium, copper, zinc, arsenic, and mercury, all of which exhibit high positive loadings. This grouping suggests these metals share common sources, likely linked to anthropogenic activities such as industrial discharge, agricultural practices, or mining.
Factor 2 primarily represents physicochemical properties of the water, with strong positive loadings observed for parameters such as PH, temperature, conductivity, total dissolved solids (TDS), turbidity, phosphate, and calcium. These variables appear to interact closely, reflecting the general water quality influenced by both natural conditions and environmental inputs.
Factor 3 is defined by ionic and salinity-related constituents, with strong loadings for chloride, nitrate, and magnesium. This factor likely reflects geological influences or salinity contributions from runoff or other natural processes.
In summary, the analysis highlights three key dimensions of water quality in the study area: heavy metal pollution (Factor 1), general physicochemical conditions (Factor 2), and salinity/ionic content (Factor 3).
Table 10. Seasonal Variations in Water Quality Parameters for Dry and Wet Seasons.

Season

N

Mean

Std. Deviation

Std. Error Mean

Heavy Metals

Dry Season

18

-.2477553

.78365757

.18470986

Wet Season

18

.2477553

1.14936805

.27090865

Physiochemical conditions

Dry Season

18

.8606064

.52342319

.12337203

Wet Season

18

-.8606064

.49162168

.11587634

Salinity/ionic content

Dry Season

18

-.2803208

.77583694

.18286652

Wet Season

18

.2803208

1.11550716

.26292756

Table 10 reveals that the mean value of heavy metals is negative in the dry season (-0.2478) but positive in the wet season (0.2478), indicating higher heavy metal concentrations during the wet season. This seasonal increase could be attributed to runoff from agricultural or industrial sources during rains. The mean of physiochemical conditions is significantly positive in the dry season (0.8606), reflecting more stable and favorable physicochemical conditions. In contrast, the mean is negative in the wet season (-0.8606), indicating potential dilution effects or disturbances due to rainwater inflow. The mean of salinity/ionic content is negative during the dry season (-0.2803) and positive during the wet season (0.2803), showing increased salinity and ionic contributions in the wet season, possibly due to runoff carrying dissolved salts.
In summary, the wet season exhibits higher heavy metal and salinity levels but poorer physicochemical conditions, reflecting the influence of runoff and rainwater mixing. The dry season, on the other hand, has more stable physicochemical conditions but lower concentrations of heavy metals and salts.
Table 11. t-Test to Compare Seasonal Variations.

t

DF

Sig. (2-tailed)

Mean Difference

Std. Error Difference

Heavy Metals

-1.511

34

.140

-.49551050

.32788600

physicochemical conditions

10.169

34

.000

1.72121272

.16925715

salinity/ionic content

-1.751

34

.089

-.56064150

.32026718

Table 11 indicates no significant seasonal difference in heavy metal concentrations, with the p value of 0.141. The mean difference of 1.7212 and p value of 0.000 show that physicochemical conditions are significantly better during the dry season, compared to the wet season. There is no significant seasonal difference in salinity or ionic content, with the p value of 0.090.
Table 12. Locational Variations in Water Quality Parameters for Dry and Wet Seasons.

Parameter

location

N

Mean

Std. Deviation

Std. Error Mean

Heavy Metals

Upstream

18

-.7706881

.58178767

.13712867

Downstream

18

.7706881

.68474671

.16139635

physicochemical conditions

Upstream

18

.0540697

1.18929177

.28031876

Downstream

18

-.0540697

.81454216

.19198943

salinity/ionic content

Upstream

18

.5294000

.94179291

.22198272

Downstream

18

-.5294000

.72952612

.17195096

Table 12 highlights locational variations in water quality parameters (heavy metals, physicochemical conditions, and salinity/ionic content) at upstream and downstream locations. The mean concentration for heavy metal is significantly negative upstream (-0.7707), indicating lower heavy metal levels, while downstream the mean is positive (0.7707), suggesting higher concentrations. The mean value of physicochemical conditions is slightly positive upstream (0.0541), indicating marginally better physicochemical conditions, while downstream it is slightly negative (-0.0541), implying a slight decline in quality. The mean value salinity/ionic content is positive upstream (0.5294), indicating higher salinity and ionic content, while downstream it is negative (-0.5294), suggesting reduced levels.
Table 13. t-Tests Comparing Location Variations.

t

DF

Sig. (2-tailed)

Mean Difference

Std. Error Difference

Heavy Metals

-7.278

34

.000

-1.54137621

.21178539

physicochemical conditions

.318

34

.752

.10813931

.33976249

salinity/ionic content

3.771

34

.001

1.05880005

.28079077

Table 13 reveals that heavy metals, with t-value of -7.278 and a p-value of 0.000 have a highly significant difference in locations. The negative mean difference of -1.5414 suggests that heavy metal concentrations are significantly higher downstream compared to upstream, possibly due to runoff or anthropogenic activities accumulating pollutants downstream.
In contrast, physicochemical conditions exhibit no significant locational variation, as evidenced by a t-value of 0.318 and a p-value of 0.752. The mean difference of 0.1081 is minimal, indicating similar physicochemical characteristics between upstream and downstream locations.
For salinity and ionic content, the t-value of 3.771 and a p-value of 0.001 demonstrate a significant difference between locations. The positive mean difference of 1.0588 indicates that salinity and ionic content are higher upstream, likely due to geological influences or reduced dilution effects compared to downstream. Heavy metal concentrations are significantly higher downstream, salinity/ionic content is significantly higher upstream, and physicochemical conditions remain consistent across locations.
4. Conclusion
The study of water quality in the Shetiko River reveals critical insights into its seasonal and locational variations, emphasizing the challenges posed by pollution and the need for sustainable management of this vital resource. Three key dimensions of water quality in the Shetiko River are highlighted in the study: heavy metal pollution, general physicochemical conditions, and salinity/ionic content. Heavy metal pollution, strongly associated with industrial and agricultural activities, exhibits seasonal and locational variations. Concentrations are significantly higher during the wet season due to runoff and downstream due to pollutant accumulation, as evidenced by a significant negative mean difference in heavy metals between upstream and downstream locations (t = -7.278, p = 0.000).
Physicochemical conditions, representing parameters such as PH, temperature, and turbidity, are more stable and favorable during the dry season, with a significant seasonal difference (t = 10.169, p = 0.000). However, they show minimal variation between upstream and downstream locations, indicating relatively uniform physicochemical characteristics across the river.
Salinity and ionic content, influenced by geological and climatic factors, are significantly higher upstream, likely due to reduced dilution and natural mineral contributions. This locational variation is statistically significant (t = 3.771, p = 0.001), but seasonal differences are less pronounced. The findings highlight the critical need for implementing targeted strategies to manage and improve water quality effectively. Upstream areas require monitoring to address salinity and ionic content, while downstream areas need interventions to mitigate heavy metal pollution. Efforts to improve sanitation, enforce industrial wastewater regulations, and prevent agricultural runoff are critical to safeguarding the Shetiko River's water quality for its diverse uses. A comprehensive understanding of these dynamics is essential for sustainable water resource management, ensuring that the river continues to support human and ecological needs effectively.
Acknowledgments
The authors wish to express their gratitude to the Management of National Mathematical Centre (NMC), Abuja, Nigeria for the opportunity given to them to participate in the Research Oriented Course (ROC) in Multivariate Analysis & Applications.
Conflicts of Interest
The authors declare that there is no conflict of Interest.
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Cite This Article
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    Adeyeye, A. C., Asher, A. S., Kolawole, I. A., Mafuyai, M. Y., Matanmi, O. G. (2025). Multivariate Study of Heavy Metals, Dissolved Salts and Physicochemical Properties of Shetiko River Water, Kuje, Federal Capital Territory, Nigeria. American Journal of Biological and Environmental Statistics, 11(2), 28-41. https://doi.org/10.11648/j.ajbes.20251102.12

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    ACS Style

    Adeyeye, A. C.; Asher, A. S.; Kolawole, I. A.; Mafuyai, M. Y.; Matanmi, O. G. Multivariate Study of Heavy Metals, Dissolved Salts and Physicochemical Properties of Shetiko River Water, Kuje, Federal Capital Territory, Nigeria. Am. J. Biol. Environ. Stat. 2025, 11(2), 28-41. doi: 10.11648/j.ajbes.20251102.12

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    AMA Style

    Adeyeye AC, Asher AS, Kolawole IA, Mafuyai MY, Matanmi OG. Multivariate Study of Heavy Metals, Dissolved Salts and Physicochemical Properties of Shetiko River Water, Kuje, Federal Capital Territory, Nigeria. Am J Biol Environ Stat. 2025;11(2):28-41. doi: 10.11648/j.ajbes.20251102.12

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  • @article{10.11648/j.ajbes.20251102.12,
      author = {Awogbemi Clement Adeyeye and Adedeji Sunday Asher and Ilori Adetunji Kolawole and Mabur Yaks Mafuyai and Oyeyemi Gafar Matanmi},
      title = {Multivariate Study of Heavy Metals, Dissolved Salts and Physicochemical Properties of Shetiko River Water, Kuje, Federal Capital Territory, Nigeria
    },
      journal = {American Journal of Biological and Environmental Statistics},
      volume = {11},
      number = {2},
      pages = {28-41},
      doi = {10.11648/j.ajbes.20251102.12},
      url = {https://doi.org/10.11648/j.ajbes.20251102.12},
      eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajbes.20251102.12},
      abstract = {Nigeria's extensive inland water resources are a significant asset, but they face severe threats from pollution driven by rapid urbanization, industrial activities, and inadequate waste management. The Shetiko River, like many others, plays a crucial role in supporting human activities such as sanitation, transportation, and irrigation. However, its vulnerability to contamination, particularly from untreated domestic, industrial, and agricultural waste, has led to ecological degradation, changes in ecosystem functions, and heightened health risks. This study analyzed water quality dynamics of Shetiko River by examining factors influencing heavy metals, physicochemical properties, and salinity (ionic content). Shetiko is located in Kuje, Federal Capital Territory (FCT), Abuja, Nigeria. Factor Analysis and Independent t-tests were used to identify the dimensionality and variation in water quality of Shetiko River. A rotated factor matrix identified three primary dimensions of water quality: heavy metal pollution (Factor 1), general physicochemical conditions (Factor 2), and ionic/salinity contributions (Factor 3). Seasonal variations indicated higher heavy metal and salinity levels during the wet season due to runoff, while the dry season exhibited more stable physicochemical properties. Locational differences revealed elevated heavy metal concentrations downstream, linked to anthropogenic activities, and higher salinity levels upstream, influenced by geological factors. Physicochemical conditions showed minimal variation across locations. These findings underscore the critical need for targeted water management strategies addressing seasonal and spatial variations to safeguard water resources and mitigate pollution impacts.
    },
     year = {2025}
    }
    

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  • TY  - JOUR
    T1  - Multivariate Study of Heavy Metals, Dissolved Salts and Physicochemical Properties of Shetiko River Water, Kuje, Federal Capital Territory, Nigeria
    
    AU  - Awogbemi Clement Adeyeye
    AU  - Adedeji Sunday Asher
    AU  - Ilori Adetunji Kolawole
    AU  - Mabur Yaks Mafuyai
    AU  - Oyeyemi Gafar Matanmi
    Y1  - 2025/06/06
    PY  - 2025
    N1  - https://doi.org/10.11648/j.ajbes.20251102.12
    DO  - 10.11648/j.ajbes.20251102.12
    T2  - American Journal of Biological and Environmental Statistics
    JF  - American Journal of Biological and Environmental Statistics
    JO  - American Journal of Biological and Environmental Statistics
    SP  - 28
    EP  - 41
    PB  - Science Publishing Group
    SN  - 2471-979X
    UR  - https://doi.org/10.11648/j.ajbes.20251102.12
    AB  - Nigeria's extensive inland water resources are a significant asset, but they face severe threats from pollution driven by rapid urbanization, industrial activities, and inadequate waste management. The Shetiko River, like many others, plays a crucial role in supporting human activities such as sanitation, transportation, and irrigation. However, its vulnerability to contamination, particularly from untreated domestic, industrial, and agricultural waste, has led to ecological degradation, changes in ecosystem functions, and heightened health risks. This study analyzed water quality dynamics of Shetiko River by examining factors influencing heavy metals, physicochemical properties, and salinity (ionic content). Shetiko is located in Kuje, Federal Capital Territory (FCT), Abuja, Nigeria. Factor Analysis and Independent t-tests were used to identify the dimensionality and variation in water quality of Shetiko River. A rotated factor matrix identified three primary dimensions of water quality: heavy metal pollution (Factor 1), general physicochemical conditions (Factor 2), and ionic/salinity contributions (Factor 3). Seasonal variations indicated higher heavy metal and salinity levels during the wet season due to runoff, while the dry season exhibited more stable physicochemical properties. Locational differences revealed elevated heavy metal concentrations downstream, linked to anthropogenic activities, and higher salinity levels upstream, influenced by geological factors. Physicochemical conditions showed minimal variation across locations. These findings underscore the critical need for targeted water management strategies addressing seasonal and spatial variations to safeguard water resources and mitigate pollution impacts.
    
    VL  - 11
    IS  - 2
    ER  - 

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Author Information
  • National Mathematical Centre, Abuja, Nigeria

  • Industrial Chemistry Department, Mewar International University, Masaka, Nigeria

  • National Mathematical Centre, Abuja, Nigeria

  • Physics Department, University of Jos, Jos, Nigeria

  • Statistics Department, University of Ilorin, Ilorin, Nigeria

  • Abstract
  • Keywords
  • Document Sections

    1. 1. Introduction
    2. 2. Methodology
    3. 3. Discussion of Results
    4. 4. Conclusion
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  • Acknowledgments
  • Conflicts of Interest
  • References
  • Cite This Article
  • Author Information