Simulation and Analysis of Methylammonium Lead Iodide (CH3NH3PbI3) Perovskite Solar Cell with Au Contact Using SCAPS 1D Simulator

Ali Husainat; Warsame Ali; Penrose Cofie; John Attia; John Fuller

doi:doi:10.11648/j.ajop.20190702.12

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Simulation and Analysis of Methylammonium Lead Iodide (CH₃NH₃PbI₃) Perovskite Solar Cell with Au Contact Using SCAPS 1D Simulator

Ali Husainat, Warsame Ali, Penrose Cofie, John Attia, John Fuller

Published in American Journal of Optics and Photonics (Volume 7, Issue 2)

Received: 17 July 2019 Accepted: 10 August 2019 Published: 20 August 2019

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Abstract

Hybrid organic-inorganic perovskite solar cells have attracted the attention of researchers and scientists throughout the world. From 2009, when actual research work began on photovoltaic perovskite applications, a lab power conversion efficiency above 23.3% have been achieved. Whereas, silicon solar cells have only achieved power conversion efficiencies around 17.5% in both residential and commercial applications. A typical perovskite solar cell consists of 6 main layers of different materials: a glass layer, a thin layer of fluorine-doped tin oxide substrate (FTO), an electron transport layer of TiO₂, a perovskite active layer known as methylammonium lead iodide (CH₃NH₃PbI₃), a hole transport layer of Spiro-Ometad, and a gold (Au) electrode. This paper summarizes the research that focused on the selective use of the perovskite solar cell’s composite materials, specifically, the Spiro-Ometad layer, the methylammonium lead iodide layer (CH₃NH₃PbI₃), and the TiO₂ layer with a variation of the thickness of the perovskite layer. Initial simulation results show a power conversion efficiency of 20.34% when using a gold (Au) electrode. Further research is needed, in which new technology for device fabrication will create homogeneous thin-film layers that will be tested for increased efficiency.

Published in	American Journal of Optics and Photonics (Volume 7, Issue 2)
DOI	10.11648/j.ajop.20190702.12
Page(s)	33-40
Creative Commons	This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.
Copyright	Copyright © The Author(s), 2019. Published by Science Publishing Group

Keywords

Modeling, Simulation, Perovskite Solar Cell, Photovoltaics, Inorganic Materials, Organic Materials

References

[1]	Frost JM, Butler KT, Brivio F, Hendon CH, Schilfgaarde MV, and Walsh A. Atomistic origin of high performance in. Hybrid halide perovskite solar cells. Nano Lett. 2014; 14: 2484-2590.
[2]	Baikie T, Fang YN, Kadro JM, Schreyer M, Wei FX, Mhaisalkar SG, Gratzel M, and White TJ "Synthesis And Crystal Chemistry Of The Hybrid Perovskite". https://pubs.rsc.org/en/content/articlelanding/2013/ta/c3ta10518k sensitized solar cell applications. J. Mater. Chem. A. 2013; 1: 5628–5641.
[3]	Stoumpos C, Malliakas CD, and Kanatzidis MG."Thermochromic Halide Perovskite Solar Cells \|Nature materials." https://www.nature.com/articles/s41563-017-0006-2013; 52: 9019–9038.
[4]	"Synthesis And crystal Chemistry Of The Hybrid Perovskite"https://pubs.rsc.org/en/content/articlelanding/2013/ta/c3ta10518k.
[5]	Yin WJ, Yang JH, Kang J, Yan Y, and Wei SH. Halide perovskite materials for Solar cells: a theoretical review. J. Mater. Chem. A. 2014.
[6]	Walsh A, Watson GW. The origin of the stereochemically active Pb (II) lone Pair: DFT calculations on PbO and PbS. Journal of Solid-State Chemistry. 2005; 178: 1422–1428.
[7]	Walsh A, Payne DJ, Egdell RG, and Watson GW. Stereochemistry of post-Transition metal oxides: revision of the classical lone pair model. Chem. Soc. Rev. 2011; 40: 4455 446.
[8]	Keith T. Butler, Jarvis M. Frost, and Aron Walsh, Band alignment of the hybrid Halide perovskites CH₃NH₃PbCl₃, CH₃NH₃PbBr₃, and CH₃NH₃PbI₃. Materials Horizons. 2014; 2: 228-231.
[9]	Gray, D. E. American Institute of Physics Handbook, 3^rd ed.; McGraw-Hill: New York, 1982.
[10]	Lide, D. R. CRC Handbook of Chemistry and Physics, 73^rd ed; CRC Press: Boca Raton, FL, 1994.
[11]	Stranks, S. D.; Eperon, G. E.; Grancini, G.; Menelaou, C.; Alcocer, M. J. P.; Leijtens, T.; Herz, L. M.; Petrozza, A.; Snaith, H. J. Electron-Hole Diffusion Lengths Exceeding Micrometer in an Organometal Trihalide Perovskite Absorber. Science 2013, 342, 341−344.
[12]	Lee MM, Teuscher J, Miyasaka T, Murakami TN, and Snaith HJ. Efficient hybrid Solar cells based on meso- superstructure organometal halide perovskites. Science. 2012; 338: 643-647.
[13]	"Strong-Covalency-induced-Recombination-CentersIn..." http://pubs.acs.org/doi/abs/10.1021/ja5079305.26May. 2019.
[14]	Liu F, Zhu J, Wei J, Li Y, Li M, Yang S, Zhang B, Yao J, and Dai S. Numerical simulation: Toward the design of high-efficiency planar perovskite solar cells. Applied Physics Letters. 2014; 104: 253508.
[15]	Walsh A, Watson GW. The origin of the stereochemically active Pb (II) lone pair: DFT calculations on PbO and PbS. Journal of Solid-State chemistry. 005; 178: 1422–1428.
[16]	Miyasaka T, Kojima A, Teshima K, and Shirai Y. Organometal halide perovskite As a visible- light sensitizer for photovoltaic cells. Jour. of Americ. Chem. Soc. 2009; 131: 6050-6051.
[17]	Walsh A, Payne DJ, Egdell RG, and Watson GW. Stereochemistry of post-transition metal oxides: revision of the classical lone pair model. Chem. Soc. Rev. 2011; 40: 4455–446.
[18]	G. Haacke, the New figure of merit for transparent conductors, J. Appl. Phys. 47.
[19]	Lee MM, Teuscher J, Miyasaka T, Murakami TN, and Snaith HJ. Efficient hybrid Solar cells based on meso-superstructure organometal halide perovskites. Science. 2012; 338: 643-647.
[20]	Jeon NJ, Lee HG, Kim YC, Seo J, Noh JH, Lee J, and Seok SI. O-Methoxy Substituents in Spiro-OMeTAD for Efficient inorganic-organic Hybrid Perovskite Solar Cells. J. Am. Chem. Soc. 2014; 136: 7837−7840.
[21]	Wang JT, Ball JM, Barea EM, Abate A, Alexander-Webber JA, Huang J, Saliba M, Mora-Sero I, Bisquert J, Snaith HJ, and Nicholas RJ. Low-temperature processed electron collection layers of graphene/TiO₂ nanocomposites in thin film perovskite solarCells. Nano Letters. 2014; 14: 724-730.
[22]	Wojciechowski K, Saliba M, Leijtens T, Abate A, and Snaith HJ. Sub-1500 C Processed meso-super structured perovskite solar cells with enhanced efficiency. Energy Environ Sci. 2014; 7: 1142-1147.
[23]	Jeon NJ, Lee HG, Kim YC, Seo J, Noh JH, Lee J, and Seok SI. O-Methoxy SubstituentsIn Spiro-OMeTAD for Efficient organic−OrganicHybrid perovskite Solar Cells. J. Am. Chem. Soc. 2014; 136: 7837−7840.
[24]	Zhou H, Chen Q, Li G, Luo S, Song T, Duan HS, Hong Z, Yu J, Liu Y, Yang Y. Interface Engineering of highly efficient perovskite solar cells. Science. 2014; 345: 542546.
[25]	Green MA, Emery K, Hishikawa Y, Warta W, and Dunlop ED. Solar cell efficiency tables (Version 45). Prog. Photovolt: res. Appl. 2015; 23: 1-9.

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APA Style

Ali Husainat, Warsame Ali, Penrose Cofie, John Attia, John Fuller. (2019). Simulation and Analysis of Methylammonium Lead Iodide (CH3NH3PbI3) Perovskite Solar Cell with Au Contact Using SCAPS 1D Simulator. American Journal of Optics and Photonics, 7(2), 33-40. https://doi.org/10.11648/j.ajop.20190702.12

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ACS Style

Ali Husainat; Warsame Ali; Penrose Cofie; John Attia; John Fuller. Simulation and Analysis of Methylammonium Lead Iodide (CH3NH3PbI3) Perovskite Solar Cell with Au Contact Using SCAPS 1D Simulator. Am. J. Opt. Photonics 2019, 7(2), 33-40. doi: 10.11648/j.ajop.20190702.12

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AMA Style

Ali Husainat, Warsame Ali, Penrose Cofie, John Attia, John Fuller. Simulation and Analysis of Methylammonium Lead Iodide (CH3NH3PbI3) Perovskite Solar Cell with Au Contact Using SCAPS 1D Simulator. Am J Opt Photonics. 2019;7(2):33-40. doi: 10.11648/j.ajop.20190702.12

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@article{10.11648/j.ajop.20190702.12,
  author = {Ali Husainat and Warsame Ali and Penrose Cofie and John Attia and John Fuller},
  title = {Simulation and Analysis of Methylammonium Lead Iodide (CH3NH3PbI3) Perovskite Solar Cell with Au Contact Using SCAPS 1D Simulator},
  journal = {American Journal of Optics and Photonics},
  volume = {7},
  number = {2},
  pages = {33-40},
  doi = {10.11648/j.ajop.20190702.12},
  url = {https://doi.org/10.11648/j.ajop.20190702.12},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajop.20190702.12},
  abstract = {Hybrid organic-inorganic perovskite solar cells have attracted the attention of researchers and scientists throughout the world. From 2009, when actual research work began on photovoltaic perovskite applications, a lab power conversion efficiency above 23.3% have been achieved. Whereas, silicon solar cells have only achieved power conversion efficiencies around 17.5% in both residential and commercial applications. A typical perovskite solar cell consists of 6 main layers of different materials: a glass layer, a thin layer of fluorine-doped tin oxide substrate (FTO), an electron transport layer of TiO2, a perovskite active layer known as methylammonium lead iodide (CH3NH3PbI3), a hole transport layer of Spiro-Ometad, and a gold (Au) electrode. This paper summarizes the research that focused on the selective use of the perovskite solar cell’s composite materials, specifically, the Spiro-Ometad layer, the methylammonium lead iodide layer (CH3NH3PbI3), and the TiO2 layer with a variation of the thickness of the perovskite layer. Initial simulation results show a power conversion efficiency of 20.34% when using a gold (Au) electrode. Further research is needed, in which new technology for device fabrication will create homogeneous thin-film layers that will be tested for increased efficiency.},
 year = {2019}
}

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TY  - JOUR
T1  - Simulation and Analysis of Methylammonium Lead Iodide (CH3NH3PbI3) Perovskite Solar Cell with Au Contact Using SCAPS 1D Simulator
AU  - Ali Husainat
AU  - Warsame Ali
AU  - Penrose Cofie
AU  - John Attia
AU  - John Fuller
Y1  - 2019/08/20
PY  - 2019
N1  - https://doi.org/10.11648/j.ajop.20190702.12
DO  - 10.11648/j.ajop.20190702.12
T2  - American Journal of Optics and Photonics
JF  - American Journal of Optics and Photonics
JO  - American Journal of Optics and Photonics
SP  - 33
EP  - 40
PB  - Science Publishing Group
SN  - 2330-8494
UR  - https://doi.org/10.11648/j.ajop.20190702.12
AB  - Hybrid organic-inorganic perovskite solar cells have attracted the attention of researchers and scientists throughout the world. From 2009, when actual research work began on photovoltaic perovskite applications, a lab power conversion efficiency above 23.3% have been achieved. Whereas, silicon solar cells have only achieved power conversion efficiencies around 17.5% in both residential and commercial applications. A typical perovskite solar cell consists of 6 main layers of different materials: a glass layer, a thin layer of fluorine-doped tin oxide substrate (FTO), an electron transport layer of TiO2, a perovskite active layer known as methylammonium lead iodide (CH3NH3PbI3), a hole transport layer of Spiro-Ometad, and a gold (Au) electrode. This paper summarizes the research that focused on the selective use of the perovskite solar cell’s composite materials, specifically, the Spiro-Ometad layer, the methylammonium lead iodide layer (CH3NH3PbI3), and the TiO2 layer with a variation of the thickness of the perovskite layer. Initial simulation results show a power conversion efficiency of 20.34% when using a gold (Au) electrode. Further research is needed, in which new technology for device fabrication will create homogeneous thin-film layers that will be tested for increased efficiency.
VL  - 7
IS  - 2
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Author Information

Ali Husainat

Department of Electrical and Computer Engineering, Prairie View A&M University, Prairie View, USA
Warsame Ali

Department of Electrical and Computer Engineering, Faculty of Electrical Engineering, Prairie View A&M University, Prairie View, USA
Penrose Cofie

Department of Electrical and Computer Engineering, Faculty of Electrical Engineering, Prairie View A&M University, Prairie View, USA
John Attia

Department of Electrical and Computer Engineering, Faculty of Electrical Engineering, Prairie View A&M University, Prairie View, USA
John Fuller

Department of Electrical and Computer Engineering, Faculty of Electrical Engineering, Prairie View A&M University, Prairie View, USA

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Ali Husainat, Warsame Ali, Penrose Cofie, John Attia, John Fuller. (2019). Simulation and Analysis of Methylammonium Lead Iodide (CH3NH3PbI3) Perovskite Solar Cell with Au Contact Using SCAPS 1D Simulator. American Journal of Optics and Photonics, 7(2), 33-40. https://doi.org/10.11648/j.ajop.20190702.12

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ACS Style

Ali Husainat; Warsame Ali; Penrose Cofie; John Attia; John Fuller. Simulation and Analysis of Methylammonium Lead Iodide (CH3NH3PbI3) Perovskite Solar Cell with Au Contact Using SCAPS 1D Simulator. Am. J. Opt. Photonics 2019, 7(2), 33-40. doi: 10.11648/j.ajop.20190702.12

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AMA Style

Ali Husainat, Warsame Ali, Penrose Cofie, John Attia, John Fuller. Simulation and Analysis of Methylammonium Lead Iodide (CH3NH3PbI3) Perovskite Solar Cell with Au Contact Using SCAPS 1D Simulator. Am J Opt Photonics. 2019;7(2):33-40. doi: 10.11648/j.ajop.20190702.12

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@article{10.11648/j.ajop.20190702.12,
  author = {Ali Husainat and Warsame Ali and Penrose Cofie and John Attia and John Fuller},
  title = {Simulation and Analysis of Methylammonium Lead Iodide (CH3NH3PbI3) Perovskite Solar Cell with Au Contact Using SCAPS 1D Simulator},
  journal = {American Journal of Optics and Photonics},
  volume = {7},
  number = {2},
  pages = {33-40},
  doi = {10.11648/j.ajop.20190702.12},
  url = {https://doi.org/10.11648/j.ajop.20190702.12},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajop.20190702.12},
  abstract = {Hybrid organic-inorganic perovskite solar cells have attracted the attention of researchers and scientists throughout the world. From 2009, when actual research work began on photovoltaic perovskite applications, a lab power conversion efficiency above 23.3% have been achieved. Whereas, silicon solar cells have only achieved power conversion efficiencies around 17.5% in both residential and commercial applications. A typical perovskite solar cell consists of 6 main layers of different materials: a glass layer, a thin layer of fluorine-doped tin oxide substrate (FTO), an electron transport layer of TiO2, a perovskite active layer known as methylammonium lead iodide (CH3NH3PbI3), a hole transport layer of Spiro-Ometad, and a gold (Au) electrode. This paper summarizes the research that focused on the selective use of the perovskite solar cell’s composite materials, specifically, the Spiro-Ometad layer, the methylammonium lead iodide layer (CH3NH3PbI3), and the TiO2 layer with a variation of the thickness of the perovskite layer. Initial simulation results show a power conversion efficiency of 20.34% when using a gold (Au) electrode. Further research is needed, in which new technology for device fabrication will create homogeneous thin-film layers that will be tested for increased efficiency.},
 year = {2019}
}

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TY  - JOUR
T1  - Simulation and Analysis of Methylammonium Lead Iodide (CH3NH3PbI3) Perovskite Solar Cell with Au Contact Using SCAPS 1D Simulator
AU  - Ali Husainat
AU  - Warsame Ali
AU  - Penrose Cofie
AU  - John Attia
AU  - John Fuller
Y1  - 2019/08/20
PY  - 2019
N1  - https://doi.org/10.11648/j.ajop.20190702.12
DO  - 10.11648/j.ajop.20190702.12
T2  - American Journal of Optics and Photonics
JF  - American Journal of Optics and Photonics
JO  - American Journal of Optics and Photonics
SP  - 33
EP  - 40
PB  - Science Publishing Group
SN  - 2330-8494
UR  - https://doi.org/10.11648/j.ajop.20190702.12
AB  - Hybrid organic-inorganic perovskite solar cells have attracted the attention of researchers and scientists throughout the world. From 2009, when actual research work began on photovoltaic perovskite applications, a lab power conversion efficiency above 23.3% have been achieved. Whereas, silicon solar cells have only achieved power conversion efficiencies around 17.5% in both residential and commercial applications. A typical perovskite solar cell consists of 6 main layers of different materials: a glass layer, a thin layer of fluorine-doped tin oxide substrate (FTO), an electron transport layer of TiO2, a perovskite active layer known as methylammonium lead iodide (CH3NH3PbI3), a hole transport layer of Spiro-Ometad, and a gold (Au) electrode. This paper summarizes the research that focused on the selective use of the perovskite solar cell’s composite materials, specifically, the Spiro-Ometad layer, the methylammonium lead iodide layer (CH3NH3PbI3), and the TiO2 layer with a variation of the thickness of the perovskite layer. Initial simulation results show a power conversion efficiency of 20.34% when using a gold (Au) electrode. Further research is needed, in which new technology for device fabrication will create homogeneous thin-film layers that will be tested for increased efficiency.
VL  - 7
IS  - 2
ER  -

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