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Voltammetric Study of the Redox Current Peaks of Pb(II) Mediated by GCE in Normal Saline

Received: 20 September 2016     Accepted: 14 December 2016     Published: 18 October 2017
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Abstract

Lead ion of sulfate was studied electrochemically analysis, using cyclic voltammetric technique by glassy carbon electrode (GCE) in normal saline solution (0.9%NaCl). The results of the study have been found oxidation and reduction current peaks of lead ion in normal saline at -550 mV and -650mV respectively. It was studied the electrochemical properties of the redox current peaks of Pb(II) with different reagents such as glucose, uric acid, urea and ascorbic acid in normal saline. The redox current peaks of Pb(II) were enhanced through using each of glucose, uric acid and urea, but in ascorbic acid the reduction current peak was reduced. Also, the other phenomena of the reduction current peak of Pb(II) was disappeared when using blood as an electrolyte because the lead ions act as oxidant pollutant in blood medium.

Published in European Journal of Biophysics (Volume 5, Issue 3)
DOI 10.11648/j.ejb.20170503.11
Page(s) 48-56
Creative Commons

This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.

Copyright

Copyright © The Author(s), 2017. Published by Science Publishing Group

Keywords

Pb(II), Cyclic Voltammetry, GCE, Ascorbic Acid, Urea, Uric Acid, Glucose

References
[1] M. M. Radhi, W. T. Tan, M. Z. B Ab Rahman, and A. B. Kassim, Electrochemical Reduction of Mn (II) Mediated by C60/Li+, Modified Glassy Carbon Electrode. Int. J. Electrochem. Sci., 5 (2010) 254–266.
[2] Muhammed Mizher Radhi, Wee Tee Tan, Mohamad Zaki B. Ab Rahman and Anuar Bin Kassim, voltammetric detection of Hg(II) at C60, Activated carbon and MWCNT modified glassy carbon electrode, Research journal of applied sciences 5 (2): 59-64, 2010.
[3] W. T. TAN, M. M. RADHI, M. Z. ABRAHMAN and A. KASSIM, Electrochemical redox of Cd(II) mediated by activated carbon modified glassy carbon electrode, Oriental Journal of Chemistry Vol. 26 (2), 339-347 (2010).
[4] W. Tan, M. Radhi, M. Ab Rahman1 and A. Kassim, Electrochemical Reduction of Manganese Mediated by Carbon Nanotubes/Li+ Modified Glassy Carbon Electrodes Asian journal of chemistry Volume: 23 Issue: 6 Page: 2401–2406 (2011).
[5] CRC Handbook of Chemistry and Physics, 83rd Edition, CRC Press, 2002.
[6] Zumdahl, Steven S. (2009). Chemical Principles 6th Ed. Houghton Mifflin Company. p. A22. ISBN 0-618-94690-X.
[7] Nurul Hudah bt Rahman, Tan Wee Tee and Kamaliah Sirat, Adsorption Enhancement of Pb(II) ion in the Presence of Nicotinic Acid during Cyclic Voltammetry, Int. J. Electrochem. Sci., 6 (2011) 3118–3128.
[8] Kevin C. Honeychurch, The voltammetric behaviour of lead at a hand drawn pencil electrode and its trace determination in water by stripping voltammetry, Anal. Methods, 2015, 7, 2437-2443.
[9] Hilding-Ohlsson, Astrid, Fauerbach, Jonathan A., Sacco, Natalia J., Bonetto, M. Celina, Cortón, Eduardo, Voltamperometric Discrimination of Urea and Melamine Adulterated Skimmed Milk Powder, Sensors (Basel, Switzerland) 2012; 12 (9): 12220-12234.
[10] Prashant Mehta and R. S. Sindal, cyclic voltammetric study of pb (II) indifferent sodium salts as supportingelectrolytes, Int. J. Chem. Sci.: 8 (1), 2010, 345-350.
[11] C. Garnier. L. Lesven. G. Billon. A. Magnier. Ø. Mikkelsen. I. Pižeta, Voltammetric procedure for trace metal analysis in polluted natural waters using homemade bare gold-disk microelectrodes, Anal Bioanal Chem DOI 10.1007/s00216-006-0625-9. Springer-Verlag 2006.
[12] Li F1, Zheng HL., Guang Pu Xue Yu Guang Pu Fen Xi., Analysis of Pb(II), Cd(II) and Cu(II) in Chinese medicine by the system of porphyrin complexes and sulfhydryl cotton fiber. 2004 Feb; 24 (2): 197-9.
[13] Ashraf Salmanipour, Mohammad Ali Taher, An electrochemical sensor for stripping analysis of Pb(II) based on multiwalled carbon nanotube functionalized with 5-Br-PADAP, Journal of Solid State Electrochemistry, 2011; 15 (11-12).
[14] Haisheng Zhang, Weiping Zhou, Hongqing Wang, Yuyuan Wang, Fangfang He, Zhiqiang Cheng, Honglin Li, Jinhui Tang, Selective Separation and Analysis of Pb(II) Using a New Surface Imprinted Multi-Walled Carbon Nanotubes Combined with AAS, JASMI. Vol.2 No. 2, June 2012, PP. 60-67.
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    Muhammed Mizher Radhi. (2017). Voltammetric Study of the Redox Current Peaks of Pb(II) Mediated by GCE in Normal Saline. European Journal of Biophysics, 5(3), 48-56. https://doi.org/10.11648/j.ejb.20170503.11

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    ACS Style

    Muhammed Mizher Radhi. Voltammetric Study of the Redox Current Peaks of Pb(II) Mediated by GCE in Normal Saline. Eur. J. Biophys. 2017, 5(3), 48-56. doi: 10.11648/j.ejb.20170503.11

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    AMA Style

    Muhammed Mizher Radhi. Voltammetric Study of the Redox Current Peaks of Pb(II) Mediated by GCE in Normal Saline. Eur J Biophys. 2017;5(3):48-56. doi: 10.11648/j.ejb.20170503.11

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  • @article{10.11648/j.ejb.20170503.11,
      author = {Muhammed Mizher Radhi},
      title = {Voltammetric Study of the Redox Current Peaks of Pb(II) Mediated by GCE in Normal Saline},
      journal = {European Journal of Biophysics},
      volume = {5},
      number = {3},
      pages = {48-56},
      doi = {10.11648/j.ejb.20170503.11},
      url = {https://doi.org/10.11648/j.ejb.20170503.11},
      eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ejb.20170503.11},
      abstract = {Lead ion of sulfate was studied electrochemically analysis, using cyclic voltammetric technique by glassy carbon electrode (GCE) in normal saline solution (0.9%NaCl). The results of the study have been found oxidation and reduction current peaks of lead ion in normal saline at -550 mV and -650mV respectively. It was studied the electrochemical properties of the redox current peaks of Pb(II) with different reagents such as glucose, uric acid, urea and ascorbic acid in normal saline. The redox current peaks of Pb(II) were enhanced through using each of glucose, uric acid and urea, but in ascorbic acid the reduction current peak was reduced. Also, the other phenomena of the reduction current peak of Pb(II) was disappeared when using blood as an electrolyte because the lead ions act as oxidant pollutant in blood medium.},
     year = {2017}
    }
    

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    T1  - Voltammetric Study of the Redox Current Peaks of Pb(II) Mediated by GCE in Normal Saline
    AU  - Muhammed Mizher Radhi
    Y1  - 2017/10/18
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    T2  - European Journal of Biophysics
    JF  - European Journal of Biophysics
    JO  - European Journal of Biophysics
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    EP  - 56
    PB  - Science Publishing Group
    SN  - 2329-1737
    UR  - https://doi.org/10.11648/j.ejb.20170503.11
    AB  - Lead ion of sulfate was studied electrochemically analysis, using cyclic voltammetric technique by glassy carbon electrode (GCE) in normal saline solution (0.9%NaCl). The results of the study have been found oxidation and reduction current peaks of lead ion in normal saline at -550 mV and -650mV respectively. It was studied the electrochemical properties of the redox current peaks of Pb(II) with different reagents such as glucose, uric acid, urea and ascorbic acid in normal saline. The redox current peaks of Pb(II) were enhanced through using each of glucose, uric acid and urea, but in ascorbic acid the reduction current peak was reduced. Also, the other phenomena of the reduction current peak of Pb(II) was disappeared when using blood as an electrolyte because the lead ions act as oxidant pollutant in blood medium.
    VL  - 5
    IS  - 3
    ER  - 

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Author Information
  • Radiological Techniques Department, Health and Medical Technology College-Baghdad, Middle Technical University, Baghdad, Iraq

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