Decreasing COD Levels and Colors of Textile Industrial Waste with Electro-fenton Method

Ahmad Rosyid Priyadi; Naniek Ratni Juliardi

doi:doi:10.11648/j.ijec.20210502.12

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Decreasing COD Levels and Colors of Textile Industrial Waste with Electro-fenton Method

Ahmad Rosyid Priyadi, Naniek Ratni Juliardi

Published in International Journal of Environmental Chemistry (Volume 5, Issue 2)

Received: 25 April 2021 Accepted: 11 May 2021 Published: 5 October 2021

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Abstract

The wastewater from the coloring process in the textile industry threads and fabrics generally contains Azo compounds and organic pollutants which are difficult to decompose biologically and require a long time. The handling of these organic pollutants can be carried out with alternative advanced oxidation processes (AOPs) technology including the Electro-Fenton method. This study aims to obtain optimum operating conditions reduction of chemical oxygen demand (COD) and color in textile industry wastewater using the Electro-Fenton method. Processing is done by using the Electro-Fenton Method in batches with a time variation of 30.60,90,120,180 minutes. Using variations of electrical voltage of 6 volts with electrode distance is 2cm, 7 volts with electrode distance is 4cm, 8 volts with electrode distance is 6cm, variations of fenton doses based on the ratio of the molar ratio of H₂O₂:FeSO₄ of (10:0.1), (10:0.2), (10:0,3). In addition to batching, this study also carried out a continuous Electro-Fenton experiment using electric voltage and electrode distance and the best contact time of the batch process. Based on the research, the processing efficiency of COD and Color in the textile industry wastes produced using the Electro-Fenton method of 94.1%, and 99.2%, respectively, on the ratio of the molar ratio of H₂O₂:FeSO₄10:0.1 with a voltage of 7 volt and 4 cm electrode distance in 180 minutes contact time and pH condition 4.

Published in	International Journal of Environmental Chemistry (Volume 5, Issue 2)
DOI	10.11648/j.ijec.20210502.12
Page(s)	23-30
Creative Commons	This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.
Copyright	Copyright © The Author(s), 2024. Published by Science Publishing Group

Keywords

Wastewater, Textile Industry, Electro-Fenton, Chemical Oxygen Demand, Color

References

[1]	Agustina, T. E., & Badewasta, H. (2009). Pengolahan Limbah Cair Industri Batik Cap Khas Palembang Dengan Proses Filtrasi Dan Adsorpsi.
[2]	Atmaca, E. (2009). Treatment Of Landfill Leachate By Using Electro-Fenton Method. Journal of hazardous materials, 163 (1), 109-114.
[3]	Babuponnusami, A., & Muthukumar, K. (2014). A Review On Fenton And Improvements To The Fenton Process For Wastewater Treatment. Journal of Environmental Chemical Engineering, 2 (1), 557-572.
[4]	Budiyono. (2008). Kriya Tekstil Untuk SMK, Direktorat Pembinaaan Sekolah Menengah Kejuruan, Direktorat Jenderal Manajemen Pendidikan Dasar dan Menengah, Departemen Pendidikan Nasional, Jakarta.
[5]	Dalvand, A., Nabizadeh, R., Ganjali, M. R., Khoobi, M., Nazmara, S., & Mahvi, A. H. (2016). Modeling Of Reactive Blue 19 Azo Dye Removal From Colored Textile Wastewater Using L-Arginine-Functionalized Fe3O4 Nanoparticles: Optimization, Reusability, Kinetic And Equilibrium Studies. Journal of Magnetism and Magnetic Materials, 404, 179-189.
[6]	Fogler, H. S. (2010). Essentials of Chemical Reaction Engineering: Essenti Chemica Reactio Engi: Pearson Education.
[7]	Fu, F., Wang, Q., & Tang, B. (2010). Effective degradation of CI Acid Red 73 by advanced Fenton process. Journal of hazardous materials, 174 (1-3), 17-22.
[8]	Guivarch, E., Trevin, S., Lahitte, C., & Oturan, M. A. (2003). Degradation of azo dyes in water by electro-Fenton process. Environmental Chemistry Letters, 1 (1), 38-44.
[9]	Harisha, S., Keshavayya, J. S., & BE Kumara Viswanath, C. (2017). Synthesis, Characterization And Electrochemical Studies Of Azo Dyes Derived From Barbituric Acid. Dyes and Pigments, 136, 742-753.
[10]	Holt, P. K., Barton, G. W., & Mitchell, C. A. (2005). The Future For Electrocoagulation As A Localised Water Treatment Technology. Chemosphere, 59 (3), 355-367.
[11]	Isarain-Chávez, E., de la Rosa, C., Godínez, L. A., Brillas, E., & Peralta-Hernández, J. M. (2014). Comparative Study Of Electrochemical Water Treatment Processes For A Tannery Wastewater Effluent. Journal of electroanalytical chemistry, 713, 62-69.
[12]	Jannah, F., Rezagama, A., & Arianto, F. (2017). Pengolahan Zat Warna Turunan Azo dengan Metode Fenton (Fe²⁺+H₂O₂) dan Ozonasi (O₃). Jurnal Teknik Lingkungan, 6 (3), 1-11.
[13]	Joseph, J. M., Destaillats, H., Hung, H. -M., & Hoffmann, M. R. (2000). The Sonochemical Degradation of Azobenzene and Related Azo Dyes: Rate Enhancements Via Fenton's Reactions. The Journal of Physical Chemistry A, 104 (2), 301-307.
[14]	Laksono, S. (2012). Pengolahan Biologis Limbah Batik dengan Media Biofilter. Skripsi. Universitas Indonesia, Depok.
[15]	Maletzky, P., & Bauer, R. (1998). The photo-Fenton method—degradation of nitrogen containing organic compounds. Chemosphere, 37 (5), 899-909.
[16]	Narissi, D. H. (2014). Analisis Frekuensi Kumulatif Mikronukleus Usapan Epitel Mukosa Pengrajin Batik di Yogyakarta Akibat Paparan Bahan Pewarna Azo. Universitas Gadjah Mada.
[17]	Riyanto, P. D. (2013). Elektrokimia Dan Aplikasinya. Graha Ilmu. Yogyakarta.
[18]	Saptaaji, R. (2007). Studi Pendahuluan Mengenai Degradasi Zat Warna Azo (Metil Orange) dalam Pelarut Air Menggunakan Mesin Berkas Elektron 350 keV/10 mA. Paper presented at the Jurnal Forum Nuklir.
[19]	Sharma, S., Ruparelia, J., & Patel, M. L. (2011). A General Review On Advanced Oxidation Processes For Waste Water Treatment. Paper presented at the Nirma University International Conference, Ahmedabad, Gujarat.
[20]	Stasinakis, A. (2008). Use of Selected Advanced Oxidation Processes (AOPS) For Wastewater Treatment–A Mini Review. Global NEST journal, 10 (3), 376-385.
[21]	Tamas, I. N. (2017). Proses Fenton Pada Pengolahan Lindi TPA Ngipik, Gresik. Institut Teknologi Sepuluh Nopember.
[22]	Tisa, F., Raman, A. A. A., & Daud, W. M. A. W. (2014). Applicability of Fluidized Bed Reactor in Recalcitrant Compound Degradation through Advanced Oxidation Processes: A Review. Journal of environmental management, 146, 260-275.
[23]	Tunç, S., Gürkan, T., & Duman, O. (2012). On-Line Spectrophotometric Method for The Determination of Optimum Operation Parameters On The Decolorization of Acid Red 66 And Direct Blue 71 From Aqueous Solution By Fenton Process. Chemical Engineering Journal, 181, 431-442.
[24]	Vatanpour, V., Daneshvar, N., & Rasoulifard, M. H. (2009). Electro-Fenton Degradation of Synthetic Dye Mixture: Influence of Intermediates. Cell, 15, 16.
[25]	Woodard, F. (2001). Industrial Waste Treatment Handbook: Elsevier.

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APA Style

Ahmad Rosyid Priyadi, Naniek Ratni Juliardi. (2021). Decreasing COD Levels and Colors of Textile Industrial Waste with Electro-fenton Method. International Journal of Environmental Chemistry, 5(2), 23-30. https://doi.org/10.11648/j.ijec.20210502.12

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ACS Style

Ahmad Rosyid Priyadi; Naniek Ratni Juliardi. Decreasing COD Levels and Colors of Textile Industrial Waste with Electro-fenton Method. Int. J. Environ. Chem. 2021, 5(2), 23-30. doi: 10.11648/j.ijec.20210502.12

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AMA Style

Ahmad Rosyid Priyadi, Naniek Ratni Juliardi. Decreasing COD Levels and Colors of Textile Industrial Waste with Electro-fenton Method. Int J Environ Chem. 2021;5(2):23-30. doi: 10.11648/j.ijec.20210502.12

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@article{10.11648/j.ijec.20210502.12,
  author = {Ahmad Rosyid Priyadi and Naniek Ratni Juliardi},
  title = {Decreasing COD Levels and Colors of Textile Industrial Waste with Electro-fenton Method},
  journal = {International Journal of Environmental Chemistry},
  volume = {5},
  number = {2},
  pages = {23-30},
  doi = {10.11648/j.ijec.20210502.12},
  url = {https://doi.org/10.11648/j.ijec.20210502.12},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ijec.20210502.12},
  abstract = {The wastewater from the coloring process in the textile industry threads and fabrics generally contains Azo compounds and organic pollutants which are difficult to decompose biologically and require a long time. The handling of these organic pollutants can be carried out with alternative advanced oxidation processes (AOPs) technology including the Electro-Fenton method. This study aims to obtain optimum operating conditions reduction of chemical oxygen demand (COD) and color in textile industry wastewater using the Electro-Fenton method. Processing is done by using the Electro-Fenton Method in batches with a time variation of 30.60,90,120,180 minutes. Using variations of electrical voltage of 6 volts with electrode distance is 2cm, 7 volts with electrode distance is 4cm, 8 volts with electrode distance is 6cm, variations of fenton doses based on the ratio of the molar ratio of H2O2:FeSO4 of (10:0.1), (10:0.2), (10:0,3). In addition to batching, this study also carried out a continuous Electro-Fenton experiment using electric voltage and electrode distance and the best contact time of the batch process. Based on the research, the processing efficiency of COD and Color in the textile industry wastes produced using the Electro-Fenton method of 94.1%, and 99.2%, respectively, on the ratio of the molar ratio of H2O2:FeSO4 10:0.1 with a voltage of 7 volt and 4 cm electrode distance in 180 minutes contact time and pH condition 4.},
 year = {2021}
}

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TY  - JOUR
T1  - Decreasing COD Levels and Colors of Textile Industrial Waste with Electro-fenton Method
AU  - Ahmad Rosyid Priyadi
AU  - Naniek Ratni Juliardi
Y1  - 2021/10/05
PY  - 2021
N1  - https://doi.org/10.11648/j.ijec.20210502.12
DO  - 10.11648/j.ijec.20210502.12
T2  - International Journal of Environmental Chemistry
JF  - International Journal of Environmental Chemistry
JO  - International Journal of Environmental Chemistry
SP  - 23
EP  - 30
PB  - Science Publishing Group
SN  - 2640-1460
UR  - https://doi.org/10.11648/j.ijec.20210502.12
AB  - The wastewater from the coloring process in the textile industry threads and fabrics generally contains Azo compounds and organic pollutants which are difficult to decompose biologically and require a long time. The handling of these organic pollutants can be carried out with alternative advanced oxidation processes (AOPs) technology including the Electro-Fenton method. This study aims to obtain optimum operating conditions reduction of chemical oxygen demand (COD) and color in textile industry wastewater using the Electro-Fenton method. Processing is done by using the Electro-Fenton Method in batches with a time variation of 30.60,90,120,180 minutes. Using variations of electrical voltage of 6 volts with electrode distance is 2cm, 7 volts with electrode distance is 4cm, 8 volts with electrode distance is 6cm, variations of fenton doses based on the ratio of the molar ratio of H2O2:FeSO4 of (10:0.1), (10:0.2), (10:0,3). In addition to batching, this study also carried out a continuous Electro-Fenton experiment using electric voltage and electrode distance and the best contact time of the batch process. Based on the research, the processing efficiency of COD and Color in the textile industry wastes produced using the Electro-Fenton method of 94.1%, and 99.2%, respectively, on the ratio of the molar ratio of H2O2:FeSO4 10:0.1 with a voltage of 7 volt and 4 cm electrode distance in 180 minutes contact time and pH condition 4.
VL  - 5
IS  - 2
ER  -

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Author Information

Ahmad Rosyid Priyadi

Environmental Engineering Study Program, “Veterans” National Development University, Surabaya, East Java, Indonesia
Naniek Ratni Juliardi

Environmental Engineering Study Program, “Veterans” National Development University, Surabaya, East Java, Indonesia

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APA Style

Ahmad Rosyid Priyadi, Naniek Ratni Juliardi. (2021). Decreasing COD Levels and Colors of Textile Industrial Waste with Electro-fenton Method. International Journal of Environmental Chemistry, 5(2), 23-30. https://doi.org/10.11648/j.ijec.20210502.12

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ACS Style

Ahmad Rosyid Priyadi; Naniek Ratni Juliardi. Decreasing COD Levels and Colors of Textile Industrial Waste with Electro-fenton Method. Int. J. Environ. Chem. 2021, 5(2), 23-30. doi: 10.11648/j.ijec.20210502.12

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AMA Style

Ahmad Rosyid Priyadi, Naniek Ratni Juliardi. Decreasing COD Levels and Colors of Textile Industrial Waste with Electro-fenton Method. Int J Environ Chem. 2021;5(2):23-30. doi: 10.11648/j.ijec.20210502.12

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@article{10.11648/j.ijec.20210502.12,
  author = {Ahmad Rosyid Priyadi and Naniek Ratni Juliardi},
  title = {Decreasing COD Levels and Colors of Textile Industrial Waste with Electro-fenton Method},
  journal = {International Journal of Environmental Chemistry},
  volume = {5},
  number = {2},
  pages = {23-30},
  doi = {10.11648/j.ijec.20210502.12},
  url = {https://doi.org/10.11648/j.ijec.20210502.12},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ijec.20210502.12},
  abstract = {The wastewater from the coloring process in the textile industry threads and fabrics generally contains Azo compounds and organic pollutants which are difficult to decompose biologically and require a long time. The handling of these organic pollutants can be carried out with alternative advanced oxidation processes (AOPs) technology including the Electro-Fenton method. This study aims to obtain optimum operating conditions reduction of chemical oxygen demand (COD) and color in textile industry wastewater using the Electro-Fenton method. Processing is done by using the Electro-Fenton Method in batches with a time variation of 30.60,90,120,180 minutes. Using variations of electrical voltage of 6 volts with electrode distance is 2cm, 7 volts with electrode distance is 4cm, 8 volts with electrode distance is 6cm, variations of fenton doses based on the ratio of the molar ratio of H2O2:FeSO4 of (10:0.1), (10:0.2), (10:0,3). In addition to batching, this study also carried out a continuous Electro-Fenton experiment using electric voltage and electrode distance and the best contact time of the batch process. Based on the research, the processing efficiency of COD and Color in the textile industry wastes produced using the Electro-Fenton method of 94.1%, and 99.2%, respectively, on the ratio of the molar ratio of H2O2:FeSO4 10:0.1 with a voltage of 7 volt and 4 cm electrode distance in 180 minutes contact time and pH condition 4.},
 year = {2021}
}

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TY  - JOUR
T1  - Decreasing COD Levels and Colors of Textile Industrial Waste with Electro-fenton Method
AU  - Ahmad Rosyid Priyadi
AU  - Naniek Ratni Juliardi
Y1  - 2021/10/05
PY  - 2021
N1  - https://doi.org/10.11648/j.ijec.20210502.12
DO  - 10.11648/j.ijec.20210502.12
T2  - International Journal of Environmental Chemistry
JF  - International Journal of Environmental Chemistry
JO  - International Journal of Environmental Chemistry
SP  - 23
EP  - 30
PB  - Science Publishing Group
SN  - 2640-1460
UR  - https://doi.org/10.11648/j.ijec.20210502.12
AB  - The wastewater from the coloring process in the textile industry threads and fabrics generally contains Azo compounds and organic pollutants which are difficult to decompose biologically and require a long time. The handling of these organic pollutants can be carried out with alternative advanced oxidation processes (AOPs) technology including the Electro-Fenton method. This study aims to obtain optimum operating conditions reduction of chemical oxygen demand (COD) and color in textile industry wastewater using the Electro-Fenton method. Processing is done by using the Electro-Fenton Method in batches with a time variation of 30.60,90,120,180 minutes. Using variations of electrical voltage of 6 volts with electrode distance is 2cm, 7 volts with electrode distance is 4cm, 8 volts with electrode distance is 6cm, variations of fenton doses based on the ratio of the molar ratio of H2O2:FeSO4 of (10:0.1), (10:0.2), (10:0,3). In addition to batching, this study also carried out a continuous Electro-Fenton experiment using electric voltage and electrode distance and the best contact time of the batch process. Based on the research, the processing efficiency of COD and Color in the textile industry wastes produced using the Electro-Fenton method of 94.1%, and 99.2%, respectively, on the ratio of the molar ratio of H2O2:FeSO4 10:0.1 with a voltage of 7 volt and 4 cm electrode distance in 180 minutes contact time and pH condition 4.
VL  - 5
IS  - 2
ER  -

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