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Application of Date Stones on the Process of Removing Erythrosine Dye from Industrial Effluents

Received: 4 July 2022    Accepted: 17 August 2022    Published: 31 August 2022
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Abstract

The date stones were obtained from the market place and the feasibility of utilizing low-cost carbonized date stones for the removal of erythrosine dye from an aqueous media was carefully conducted under laboratory restricted conditions. Experimental parameters such as temperature, pH, dosage, and concentration were painstakingly maintained. Outcomes show the efficient removal of the contaminant by the substrate CDS (Carbonized date stones), Kinetics models “pseudo-first and pseudo second order was applied. Afterwards, the Langmuir and Freundlich adsorption isotherms were utilized to identify the adsorption mechanisms. The mechanism of this adsorption process displayed Langmuir adsorption isotherm which is a monolayer with R2 value of 0.9780 which is higher than that of Freundlich with R2 value of 0.8933. Also, the research work showed that the adhered and suitable kinetic model for the removal of erythrosine dye using carbonized date stones was pseudo second order due to the adsorption capacity of the dye at equilibrium qe was high at the value of 1.8900 to 8.3689 in pseudo second order compared to pseudo-first order with 7.4567.

Published in International Journal of Environmental Chemistry (Volume 6, Issue 2)
DOI 10.11648/j.ijec.20220602.11
Page(s) 36-41
Creative Commons

This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.

Copyright

Copyright © The Author(s), 2024. Published by Science Publishing Group

Keywords

Erythrosine Dye, Date Stones, Adsorption

References
[1] Saha P., Das Mishra R. and Husk R. (2012), Adsorption of safranin onto chemically modified rice husk in an upward flow packed bed reactor: artificial neural network modeling. Biotechnology Advances, 44, 7579-7583.
[2] Bartonova L., Ruppenthalova L. and Ritz M. (2017), Adsorption of Naphthol Green B on unburned carbon: 2- and 3-parameter linear and non-linear equilibrium modeling. Chinese Journal of Chemical Engineering, 25, 37-44.
[3] Aksu Z. (2005), Application of biosorption for the removal of organic pollutants: A review. Process Biochemistry, 40, 997-1026.
[4] Hamdaoui O. (2006), Batch study of liquid-phase adsorption of methylene blue using cedar sawdust and crushed brick. Journal of Hazardous Materials, 135, 264-273.
[5] Verma A. K., Dash R. R. and Bhunia P. (2012), A Review on Chemical Coagulation/Flocculation Technologies for Removal of Colour from Textile Wastewaters. Journal of Environmental Management, 93, 154-168.
[6] Karcher S., Kornmüller A. and Jekel M. (2002), Anion exchange resins for removal of reactive dyes from textile wastewaters. Water Research 36, 4717-4724.
[7] Avlonitis S. A., Poulios I., Sotiriou D., Pappas M. and Moutesidis K. (2008), Simulated cotton dye effluents treatment and reuse by nanofiltration. Desalination, 221, 259-267.
[8] El Haddad M., Regti A., Laamari M. R., Mamouni R. and Saffaj N. (2014), Use of Fenton reagent as advanced oxidative process for removing textile dyes from aqueous solutions. Journal of Materials and Environmental Science, 5, 667-674.
[9] Aleboyeh A., Moussa Y. and Aleboyeh H. (2005), The effect of operational parameters on UV/H2O2 decolourisation of Acid Blue 74. Dyes and Pigments, 66, 129-134.
[10] Alaton I. A., Balcioglu I. A. and Bahnemann D. W. (2002), Advanced oxidation of a reactive dye bath effluent: comparison of O3, H2O2/UV-C and TiO2/UV-A processes. Water Resources, 36, 1143-1154.
[11] Chellaiah E. R. (2018), Cadmium (heavy metals) bioremediation by Pseudomonas aeruginosa: a minireview. Applied Water Science, 8, 154.
[12] Iqbal M. J. and Ashiq M. N. (2007), Adsorption of dyes from aqueous solutions on activated charcoal. Journal of Hazardous Materials, 139, 57-66.
[13] Attia A. A., Girgis B. S. and Khedr S. (2003), Capacity of activated carbon derived from pistachio shells by H3PO4 in the removal of dyes and phenolics. Journal of Chemical Technology & Biotechnology, 78, 611-619.
[14] Maaloul N., Oulego P., Rendueles M., Ghorbal A. and Díaz M. (2017), Novel biosorbents from almond shells: Characterization and adsorption properties modeling for Cu(II) ions from aqueous solutions. Journal of Environmental Chemical Engineering, 5, 2944-2954.
[15] Hameed B. H., Ahmad A. L. and Latiff K. N. A. (2007), Adsorption of basic dye methylene blue onto activated carbon prepared from rattan sawdust. Dyes and Pigments, 75, 143-149.
[16] Deng H., Yang L., Tao G. and Dai J. (2009), Preparation and characterization of activated carbon from cotton stalk by microwave assisted chemical activation-application in methylene blue adsorption from aqueous solution. Journal of Hazardous Materials, 166, 1514-1521.
[17] Foo K. Y. and Hameed B. H. (2012), Preparation, Characterization and evaluation of adsorptive properties of orange peel based activated carbon via microwave induce K2CO3 activation. Bioresource Technology, 104, 679-689.
[18] Lua A. C. and Jia Q. P. (2009), Adsorption of phenol by oil-palm- shell activated. Chemical Engineering Journal, 150, 455-461.
[19] Gong R., Ding Y., Li M., Yang C., Liu H. and Sun Y. (2005), Utilization of powdered peanut hull as biosorbent for removal of anionic dyes from aqueous solution. Dyes and Pigments, 64, 187-192.
[20] Valix M., Cheung W. H. and McKay G. (2004), Preparation of activated carbon using low temperature carbonization and physical activation of high ash raw bagasse for acid dye adsorption. Chemosphere, 56, 493-501.
[21] Ibrahim S. C., Hanafiah M. K. A. M. and Yahya M. Z. A. (2006), Removal of cadmium from aqueous solution by adsorption on sugarcane bagasse. American-Eurasian Journal of Agricultural & Environmental Sciences, 1, 179-184.
[22] Amina A. A., Badie S. G. and Nady A. F. (2008), Removal of methylene blue by carbons derived from peach stones by H3PO4 activation: Batch and column studies. Dyes and Pigments, 76, 282-289.
[23] Çaglar E., Donar Y. O., Sinag A., Birogul I., Bilge S., Aydincak K. and Pliekhov O. (2018), Adsorption of anionic and cationic dyes on biochars., produced by hydrothermal carbonization of waste biomass: effect of surface functionalization and ionic strength. Turkish Journal of Chemistry, 42, 86-99.
[24] Alkan M., Doğan M., Turhan Y., Demirbaş O. and Turan P. (2008), Adsorption kinetics and mechanism of maxilon blue 5G dye on sepiolite from aqueous solutions. Chemical Engineering Journal, 139, 213-223.
[25] Boonamnuayvitaya V., Chaiya C., Tanthapanichakoon W. and Jarudilokkul S. (2004), Removal of heavy metals by adsorbent prepared from pyrolyzed coffee residues and clay. Separation and Purification Technology, 35, 11-22.
[26] Bulut E., Ozacar M. and Sengil I. A. (2008), Equilibrium and kinetic data and process design for adsorption of Congo Red onto bentonite. Journal of Hazardous Materials, 154, 613-622.
[27] Chen S. and Zeng H. (2003), Improvement of the reduction capacity of activated carbon fiber. Carbon, 41, 1265-1271.
[28] Cheng W., Liu G., Wang X. and Han L. (2017), Adsorption Removal of Glycidyl Esters from Palm Oil and Oil Model Solution by Using Acid-Washed Oil Palm Wood-Based Activated Carbon: Kinetic and Mechanism Study. Journal of Agricultural and Food Chemistry, 65, 9753-9762.
[29] Doğan M., Abak H. and Alkan M. (2008), Biosorption of Methylene Blue from Aqueous Solutions by Hazelnut Shells: Equilibrium., Parameters and Isotherms. Water, Air, & Soil Pollution, 192, 141-153.
[30] Ge Y. Q., Zhang W. Q., Xue G. and Zhao J. C. (2015), Carbonization of Chlorinated Organic Residual Liquid for Energy Source Generation. Journal of Materials Science and Chemical Engineering, 3, 95-103.
[31] Hui H., Jubin Z., Kangli L. and Yayun T. (2015), Characterization of Acidosasa edulis shoot shell and its biosorption of copper ions from aqueous solution. Journal of Environmental Chemical Engineering, 3, 357-364.
[32] Jain M., Garg V. K., Garg U. K., Kadirvelu K. and Sillanpää M. (2015), Cadmium Removal from Wastewater using Carbonaceous Adsorbents Prepared from Sunflower Waste. International Journal of Environmental Research, 9, 1079- 1088.
[33] Jawad A. H., Rashid A. R., Ishak M. A. M. and Wilson L. D. (2016), Adsorption of methylene blue onto activated carbon developed from biomass waste by H2SO4 activation: kinetic equilibrium and thermodynamic studies. Desalination and Water Treatment, 57, 25194-25206.
[34] Kadirvelu K., Kavipriya M., Karthika C., Radhika M., Vennilamani N. and Pattabhi S. (2003), Utilization of various agricultural wastes for activated carbon preparation and application for the removal of dyes and metal ions from aqueous solutions. Bioresource Technology, 87, 129-132.
[35] Mausul U., Haliru A., Amina D., Muhammad G., and Abdurrahaman A. (2022), Removal of chromium from an aqueous solution using river sediment from kashere, gombe state, Nigeria. International journal of scientific and research publications, vol 12 ISSN 2250-3153.
[36] Mausul U., Haliru A., Amina D., Muhammad G., and Abdurrahaman A. (2022), Removal of lead from an aqueous solution using river sediment from kashere, gombe state, North Eastern Nigeria. International journal of advances in engineering and management ISSN 2395-5252.
Cite This Article
  • APA Style

    Mausul Umar, Haliru Aivada Kadir, Amina Doho, Yoro Mela, Muhammad Garba, et al. (2022). Application of Date Stones on the Process of Removing Erythrosine Dye from Industrial Effluents. International Journal of Environmental Chemistry, 6(2), 36-41. https://doi.org/10.11648/j.ijec.20220602.11

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    ACS Style

    Mausul Umar; Haliru Aivada Kadir; Amina Doho; Yoro Mela; Muhammad Garba, et al. Application of Date Stones on the Process of Removing Erythrosine Dye from Industrial Effluents. Int. J. Environ. Chem. 2022, 6(2), 36-41. doi: 10.11648/j.ijec.20220602.11

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    AMA Style

    Mausul Umar, Haliru Aivada Kadir, Amina Doho, Yoro Mela, Muhammad Garba, et al. Application of Date Stones on the Process of Removing Erythrosine Dye from Industrial Effluents. Int J Environ Chem. 2022;6(2):36-41. doi: 10.11648/j.ijec.20220602.11

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  • @article{10.11648/j.ijec.20220602.11,
      author = {Mausul Umar and Haliru Aivada Kadir and Amina Doho and Yoro Mela and Muhammad Garba and Auwal Aliyu},
      title = {Application of Date Stones on the Process of Removing Erythrosine Dye from Industrial Effluents},
      journal = {International Journal of Environmental Chemistry},
      volume = {6},
      number = {2},
      pages = {36-41},
      doi = {10.11648/j.ijec.20220602.11},
      url = {https://doi.org/10.11648/j.ijec.20220602.11},
      eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ijec.20220602.11},
      abstract = {The date stones were obtained from the market place and the feasibility of utilizing low-cost carbonized date stones for the removal of erythrosine dye from an aqueous media was carefully conducted under laboratory restricted conditions. Experimental parameters such as temperature, pH, dosage, and concentration were painstakingly maintained. Outcomes show the efficient removal of the contaminant by the substrate CDS (Carbonized date stones), Kinetics models “pseudo-first and pseudo second order was applied. Afterwards, the Langmuir and Freundlich adsorption isotherms were utilized to identify the adsorption mechanisms. The mechanism of this adsorption process displayed Langmuir adsorption isotherm which is a monolayer with R2 value of 0.9780 which is higher than that of Freundlich with R2 value of 0.8933. Also, the research work showed that the adhered and suitable kinetic model for the removal of erythrosine dye using carbonized date stones was pseudo second order due to the adsorption capacity of the dye at equilibrium qe was high at the value of 1.8900 to 8.3689 in pseudo second order compared to pseudo-first order with 7.4567.},
     year = {2022}
    }
    

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  • TY  - JOUR
    T1  - Application of Date Stones on the Process of Removing Erythrosine Dye from Industrial Effluents
    AU  - Mausul Umar
    AU  - Haliru Aivada Kadir
    AU  - Amina Doho
    AU  - Yoro Mela
    AU  - Muhammad Garba
    AU  - Auwal Aliyu
    Y1  - 2022/08/31
    PY  - 2022
    N1  - https://doi.org/10.11648/j.ijec.20220602.11
    DO  - 10.11648/j.ijec.20220602.11
    T2  - International Journal of Environmental Chemistry
    JF  - International Journal of Environmental Chemistry
    JO  - International Journal of Environmental Chemistry
    SP  - 36
    EP  - 41
    PB  - Science Publishing Group
    SN  - 2640-1460
    UR  - https://doi.org/10.11648/j.ijec.20220602.11
    AB  - The date stones were obtained from the market place and the feasibility of utilizing low-cost carbonized date stones for the removal of erythrosine dye from an aqueous media was carefully conducted under laboratory restricted conditions. Experimental parameters such as temperature, pH, dosage, and concentration were painstakingly maintained. Outcomes show the efficient removal of the contaminant by the substrate CDS (Carbonized date stones), Kinetics models “pseudo-first and pseudo second order was applied. Afterwards, the Langmuir and Freundlich adsorption isotherms were utilized to identify the adsorption mechanisms. The mechanism of this adsorption process displayed Langmuir adsorption isotherm which is a monolayer with R2 value of 0.9780 which is higher than that of Freundlich with R2 value of 0.8933. Also, the research work showed that the adhered and suitable kinetic model for the removal of erythrosine dye using carbonized date stones was pseudo second order due to the adsorption capacity of the dye at equilibrium qe was high at the value of 1.8900 to 8.3689 in pseudo second order compared to pseudo-first order with 7.4567.
    VL  - 6
    IS  - 2
    ER  - 

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Author Information
  • Department of Chemical Sciences, Federal University of Kashere, Gombe, Nigeria

  • Department of Quality Assurance & Control, Dangote Cement Plc, Lagos, Nigeria

  • Department of Chemical Sciences, Federal University of Kashere, Gombe, Nigeria

  • Department of Chemical Sciences, Federal University of Kashere, Gombe, Nigeria

  • Department of Chemical Sciences, Federal University of Kashere, Gombe, Nigeria

  • Department of Biological Sciences, Federal University Dutse, Jigawa, Nigeria

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