Application of Graphene Oxide in Composite Geothermal Floor

Zhiyong Zheng; Yuanting Zhu; Kaisen Zheng; Qi Li; An Mao

doi:doi:10.11648/j.ijmsa.20221101.13

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Application of Graphene Oxide in Composite Geothermal Floor

Zhiyong Zheng, Yuanting Zhu, Kaisen Zheng, Qi Li, An Mao

Published in International Journal of Materials Science and Applications (Volume 11, Issue 1)

Received: 30 December 2021 Accepted: 14 January 2022 Published: 25 January 2022

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Abstract

With the rapid development of China's solid wood composite flooring industry, the market of solid wood composite geothermal flooring is gradually huge. The adhesives used in traditional solid wood composite geothermal flooring are mainly urea formaldehyde resin and phenolic resin. Its bonded wood-based panel has the problems of formaldehyde emission and poor waterproof. With the enhancement of people's awareness of safety and environmental protection, the problem of formaldehyde has attracted more and more attention. Looking for various formaldehyde free adhesives that can replace urea formaldehyde resin has become a research hotspot. Graphene oxide is a new carbon material with excellent properties, which has high specific surface area and rich functional groups on the surface. In this study, powdered oxygraphene material and isocyanate resin were mixed in different proportions to press the three-layer solid wood composite floor substrate, and the bonding strength and thermal conductivity were tested to investigate the effect of graphene oxide powder on the bonding and thermal conductivity of isocyanate resin. The experimental results show that the viscosity of the resin system increases with the increase of the amount of graphene oxide powder; Graphene oxide powder with mesh number of 250 can significantly enhance the bonding strength of isocyanate, But when the amount is too large (10%) on the contrary, the bonding strength decreases. Graphene oxide powder with mesh number of 50 does not significantly enhance the bonding strength; adding graphene oxide powder can improve the thermal conductivity of the floor. With the increase of the proportion of graphene oxide, the thermal conductivity, thermal conductivity and electrothermal conversion rate of the floor are significantly improved, but graphene oxide with mesh number of 50 is not as good as graphite oxide with mesh number of 250 Alkene increased significantly. The addition of an appropriate amount of graphene oxide fine powder reduces the infiltration of resin into wood, enhances the bonding performance and thermal conductivity, provides a new possible way for the application of graphene oxide material and isocyanate in the substrate of solid wood composite floor, and provides a certain practical basis for the manufacturing process and application technology development of thermal conductive floor and geothermal floor.

Published in	International Journal of Materials Science and Applications (Volume 11, Issue 1)
DOI	10.11648/j.ijmsa.20221101.13
Page(s)	15-20
Creative Commons	This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.
Copyright	Copyright © The Author(s), 2024. Published by Science Publishing Group

Keywords

Graphene Oxide, Isocyanate, Three Layer Solid Wood Composite Floor, Base Panel, Bonding Strength

References

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[2]	Pizzi A. Synthetic adhesives for wood panels: Chemistry and Technology-a critical review. Rev. Adhesion Adhesives, 2014, 2 (1): 85-125.
[3]	A. Mao, E. B. Hassan, and M. G. Kim, The effects of adding melamine at different resin synthesis points of low mole ratio urea-melamine-formaldehyde (UMF) resins. BioResources, 8 (4), 5733-5748, 2013.
[4]	J. Luo, J. Zhang, Q. Gao, A. Mao, and J. Li, Toughening and enhancing melamine-urea-formaldehyde resin properties via in situ polymerization of dialdehyde starch and microphase separation. Polymers, 11, 1167-1185, 2019.
[5]	Q. Wang, N. Wu, X. Li, W. Hui, H. Lei, G. Du, Z. Wu, and S. Liu, Improving the performance of Eucalyptus wood particle board panels with low free formaldehyde emission urea-formaldehyde resin using Pectinase enzyme pre-treatments. BioResources, 13 (2), 2996-3004, 2018.
[6]	R. Wang, Z. Zhang, R. Chen, L. Zhao, C. Wang, and F. Chu, Synthesis of phenol-urea-formaldehyde resin and its reaction mechanism. Chemistry and Industry of Forest Products, 38 (1), 101-109, 2018.
[7]	Y. Pang, W. Xu, Q. Li, C. Li, and A. Mao, Research progress of bio-based wood adhesives. China Forest Products Industry, 45 (4), 3-7, 2018.
[8]	Q. Gao, C. Liu, J. Luo, X. Li, L. Chen, W. Wang, and J. Li, Effects of resin open time and melamine addition on cold pre-pressing performance of a urea-formaldehyde resin. European Journal of Wood and Wood products, 76 (4), 1253-1261, 2018.
[9]	Q. Li. M. Li, C. Chen, G. Cao, A. Mao, and H. Wan, Adhesives from polymeric methylene diphenyl diisocyanate resin and recycled polyols for plywood. Forest Products Journal, 67 (3/4), 275-282, 2017.
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[12]	P. Qu, H. Huang, G. Wu, E. Sun, and Z. Chang. Effects of hydrolysis degree of soy protein isolate on the structure and performance of hydrolyzed soy protein isolate/urea/formaldehyde copolymer resin. Journal of Applied Polymer Science, 132 (7): 41469-41477, 2015.
[13]	L. C, Y. Zhang, and X. N. Li. A high-performance bio-adhesive derived from soy protein isolate and condensed tannins. RSC Advances, 7 (34): 21226-21233, 2017.
[14]	Shi J Y, Wen M Y, Li X Y, et al. Research progress of biomass-based formaldehyde-free adhesives [J]. Journal of Forestry Engineering, 2018, 3 (2): 1-10.
[15]	Y. Li, M. Zhang, Y. Zhang, Q. Gao, A. Mao, and J. Li, Effects of different denaturants on properties and performance of soy protein-based adhesive. Polymers, 11, 1262-1275, 2019.

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APA Style

Zhiyong Zheng, Yuanting Zhu, Kaisen Zheng, Qi Li, An Mao. (2022). Application of Graphene Oxide in Composite Geothermal Floor. International Journal of Materials Science and Applications, 11(1), 15-20. https://doi.org/10.11648/j.ijmsa.20221101.13

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ACS Style

Zhiyong Zheng; Yuanting Zhu; Kaisen Zheng; Qi Li; An Mao. Application of Graphene Oxide in Composite Geothermal Floor. Int. J. Mater. Sci. Appl. 2022, 11(1), 15-20. doi: 10.11648/j.ijmsa.20221101.13

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AMA Style

Zhiyong Zheng, Yuanting Zhu, Kaisen Zheng, Qi Li, An Mao. Application of Graphene Oxide in Composite Geothermal Floor. Int J Mater Sci Appl. 2022;11(1):15-20. doi: 10.11648/j.ijmsa.20221101.13

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@article{10.11648/j.ijmsa.20221101.13,
  author = {Zhiyong Zheng and Yuanting Zhu and Kaisen Zheng and Qi Li and An Mao},
  title = {Application of Graphene Oxide in Composite Geothermal Floor},
  journal = {International Journal of Materials Science and Applications},
  volume = {11},
  number = {1},
  pages = {15-20},
  doi = {10.11648/j.ijmsa.20221101.13},
  url = {https://doi.org/10.11648/j.ijmsa.20221101.13},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ijmsa.20221101.13},
  abstract = {With the rapid development of China's solid wood composite flooring industry, the market of solid wood composite geothermal flooring is gradually huge. The adhesives used in traditional solid wood composite geothermal flooring are mainly urea formaldehyde resin and phenolic resin. Its bonded wood-based panel has the problems of formaldehyde emission and poor waterproof. With the enhancement of people's awareness of safety and environmental protection, the problem of formaldehyde has attracted more and more attention. Looking for various formaldehyde free adhesives that can replace urea formaldehyde resin has become a research hotspot. Graphene oxide is a new carbon material with excellent properties, which has high specific surface area and rich functional groups on the surface. In this study, powdered oxygraphene material and isocyanate resin were mixed in different proportions to press the three-layer solid wood composite floor substrate, and the bonding strength and thermal conductivity were tested to investigate the effect of graphene oxide powder on the bonding and thermal conductivity of isocyanate resin. The experimental results show that the viscosity of the resin system increases with the increase of the amount of graphene oxide powder; Graphene oxide powder with mesh number of 250 can significantly enhance the bonding strength of isocyanate, But when the amount is too large (10%) on the contrary, the bonding strength decreases. Graphene oxide powder with mesh number of 50 does not significantly enhance the bonding strength; adding graphene oxide powder can improve the thermal conductivity of the floor. With the increase of the proportion of graphene oxide, the thermal conductivity, thermal conductivity and electrothermal conversion rate of the floor are significantly improved, but graphene oxide with mesh number of 50 is not as good as graphite oxide with mesh number of 250 Alkene increased significantly. The addition of an appropriate amount of graphene oxide fine powder reduces the infiltration of resin into wood, enhances the bonding performance and thermal conductivity, provides a new possible way for the application of graphene oxide material and isocyanate in the substrate of solid wood composite floor, and provides a certain practical basis for the manufacturing process and application technology development of thermal conductive floor and geothermal floor.},
 year = {2022}
}

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TY  - JOUR
T1  - Application of Graphene Oxide in Composite Geothermal Floor
AU  - Zhiyong Zheng
AU  - Yuanting Zhu
AU  - Kaisen Zheng
AU  - Qi Li
AU  - An Mao
Y1  - 2022/01/25
PY  - 2022
N1  - https://doi.org/10.11648/j.ijmsa.20221101.13
DO  - 10.11648/j.ijmsa.20221101.13
T2  - International Journal of Materials Science and Applications
JF  - International Journal of Materials Science and Applications
JO  - International Journal of Materials Science and Applications
SP  - 15
EP  - 20
PB  - Science Publishing Group
SN  - 2327-2643
UR  - https://doi.org/10.11648/j.ijmsa.20221101.13
AB  - With the rapid development of China's solid wood composite flooring industry, the market of solid wood composite geothermal flooring is gradually huge. The adhesives used in traditional solid wood composite geothermal flooring are mainly urea formaldehyde resin and phenolic resin. Its bonded wood-based panel has the problems of formaldehyde emission and poor waterproof. With the enhancement of people's awareness of safety and environmental protection, the problem of formaldehyde has attracted more and more attention. Looking for various formaldehyde free adhesives that can replace urea formaldehyde resin has become a research hotspot. Graphene oxide is a new carbon material with excellent properties, which has high specific surface area and rich functional groups on the surface. In this study, powdered oxygraphene material and isocyanate resin were mixed in different proportions to press the three-layer solid wood composite floor substrate, and the bonding strength and thermal conductivity were tested to investigate the effect of graphene oxide powder on the bonding and thermal conductivity of isocyanate resin. The experimental results show that the viscosity of the resin system increases with the increase of the amount of graphene oxide powder; Graphene oxide powder with mesh number of 250 can significantly enhance the bonding strength of isocyanate, But when the amount is too large (10%) on the contrary, the bonding strength decreases. Graphene oxide powder with mesh number of 50 does not significantly enhance the bonding strength; adding graphene oxide powder can improve the thermal conductivity of the floor. With the increase of the proportion of graphene oxide, the thermal conductivity, thermal conductivity and electrothermal conversion rate of the floor are significantly improved, but graphene oxide with mesh number of 50 is not as good as graphite oxide with mesh number of 250 Alkene increased significantly. The addition of an appropriate amount of graphene oxide fine powder reduces the infiltration of resin into wood, enhances the bonding performance and thermal conductivity, provides a new possible way for the application of graphene oxide material and isocyanate in the substrate of solid wood composite floor, and provides a certain practical basis for the manufacturing process and application technology development of thermal conductive floor and geothermal floor.
VL  - 11
IS  - 1
ER  -

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Author Information

Zhiyong Zheng

Shandong Yisen Meiju New Material Technology Co., Ltd, Linyi, China
Yuanting Zhu

College of Forestry, Shandong Agricultural University, Taian, China
Kaisen Zheng

Shandong Yisen Meiju New Material Technology Co., Ltd, Linyi, China
Qi Li

College of Forestry, Shandong Agricultural University, Taian, China
An Mao

College of Forestry, Shandong Agricultural University, Taian, China

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Plain Text BibTeX RIS

APA Style

Zhiyong Zheng, Yuanting Zhu, Kaisen Zheng, Qi Li, An Mao. (2022). Application of Graphene Oxide in Composite Geothermal Floor. International Journal of Materials Science and Applications, 11(1), 15-20. https://doi.org/10.11648/j.ijmsa.20221101.13

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ACS Style

Zhiyong Zheng; Yuanting Zhu; Kaisen Zheng; Qi Li; An Mao. Application of Graphene Oxide in Composite Geothermal Floor. Int. J. Mater. Sci. Appl. 2022, 11(1), 15-20. doi: 10.11648/j.ijmsa.20221101.13

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AMA Style

Zhiyong Zheng, Yuanting Zhu, Kaisen Zheng, Qi Li, An Mao. Application of Graphene Oxide in Composite Geothermal Floor. Int J Mater Sci Appl. 2022;11(1):15-20. doi: 10.11648/j.ijmsa.20221101.13

Copy | Download

@article{10.11648/j.ijmsa.20221101.13,
  author = {Zhiyong Zheng and Yuanting Zhu and Kaisen Zheng and Qi Li and An Mao},
  title = {Application of Graphene Oxide in Composite Geothermal Floor},
  journal = {International Journal of Materials Science and Applications},
  volume = {11},
  number = {1},
  pages = {15-20},
  doi = {10.11648/j.ijmsa.20221101.13},
  url = {https://doi.org/10.11648/j.ijmsa.20221101.13},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ijmsa.20221101.13},
  abstract = {With the rapid development of China's solid wood composite flooring industry, the market of solid wood composite geothermal flooring is gradually huge. The adhesives used in traditional solid wood composite geothermal flooring are mainly urea formaldehyde resin and phenolic resin. Its bonded wood-based panel has the problems of formaldehyde emission and poor waterproof. With the enhancement of people's awareness of safety and environmental protection, the problem of formaldehyde has attracted more and more attention. Looking for various formaldehyde free adhesives that can replace urea formaldehyde resin has become a research hotspot. Graphene oxide is a new carbon material with excellent properties, which has high specific surface area and rich functional groups on the surface. In this study, powdered oxygraphene material and isocyanate resin were mixed in different proportions to press the three-layer solid wood composite floor substrate, and the bonding strength and thermal conductivity were tested to investigate the effect of graphene oxide powder on the bonding and thermal conductivity of isocyanate resin. The experimental results show that the viscosity of the resin system increases with the increase of the amount of graphene oxide powder; Graphene oxide powder with mesh number of 250 can significantly enhance the bonding strength of isocyanate, But when the amount is too large (10%) on the contrary, the bonding strength decreases. Graphene oxide powder with mesh number of 50 does not significantly enhance the bonding strength; adding graphene oxide powder can improve the thermal conductivity of the floor. With the increase of the proportion of graphene oxide, the thermal conductivity, thermal conductivity and electrothermal conversion rate of the floor are significantly improved, but graphene oxide with mesh number of 50 is not as good as graphite oxide with mesh number of 250 Alkene increased significantly. The addition of an appropriate amount of graphene oxide fine powder reduces the infiltration of resin into wood, enhances the bonding performance and thermal conductivity, provides a new possible way for the application of graphene oxide material and isocyanate in the substrate of solid wood composite floor, and provides a certain practical basis for the manufacturing process and application technology development of thermal conductive floor and geothermal floor.},
 year = {2022}
}

Copy | Download

TY  - JOUR
T1  - Application of Graphene Oxide in Composite Geothermal Floor
AU  - Zhiyong Zheng
AU  - Yuanting Zhu
AU  - Kaisen Zheng
AU  - Qi Li
AU  - An Mao
Y1  - 2022/01/25
PY  - 2022
N1  - https://doi.org/10.11648/j.ijmsa.20221101.13
DO  - 10.11648/j.ijmsa.20221101.13
T2  - International Journal of Materials Science and Applications
JF  - International Journal of Materials Science and Applications
JO  - International Journal of Materials Science and Applications
SP  - 15
EP  - 20
PB  - Science Publishing Group
SN  - 2327-2643
UR  - https://doi.org/10.11648/j.ijmsa.20221101.13
AB  - With the rapid development of China's solid wood composite flooring industry, the market of solid wood composite geothermal flooring is gradually huge. The adhesives used in traditional solid wood composite geothermal flooring are mainly urea formaldehyde resin and phenolic resin. Its bonded wood-based panel has the problems of formaldehyde emission and poor waterproof. With the enhancement of people's awareness of safety and environmental protection, the problem of formaldehyde has attracted more and more attention. Looking for various formaldehyde free adhesives that can replace urea formaldehyde resin has become a research hotspot. Graphene oxide is a new carbon material with excellent properties, which has high specific surface area and rich functional groups on the surface. In this study, powdered oxygraphene material and isocyanate resin were mixed in different proportions to press the three-layer solid wood composite floor substrate, and the bonding strength and thermal conductivity were tested to investigate the effect of graphene oxide powder on the bonding and thermal conductivity of isocyanate resin. The experimental results show that the viscosity of the resin system increases with the increase of the amount of graphene oxide powder; Graphene oxide powder with mesh number of 250 can significantly enhance the bonding strength of isocyanate, But when the amount is too large (10%) on the contrary, the bonding strength decreases. Graphene oxide powder with mesh number of 50 does not significantly enhance the bonding strength; adding graphene oxide powder can improve the thermal conductivity of the floor. With the increase of the proportion of graphene oxide, the thermal conductivity, thermal conductivity and electrothermal conversion rate of the floor are significantly improved, but graphene oxide with mesh number of 50 is not as good as graphite oxide with mesh number of 250 Alkene increased significantly. The addition of an appropriate amount of graphene oxide fine powder reduces the infiltration of resin into wood, enhances the bonding performance and thermal conductivity, provides a new possible way for the application of graphene oxide material and isocyanate in the substrate of solid wood composite floor, and provides a certain practical basis for the manufacturing process and application technology development of thermal conductive floor and geothermal floor.
VL  - 11
IS  - 1
ER  -

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