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Application of Response Surface Design to Optimize the Production of Bioethanol from Lignocellulosic Biomass (Maize cob)

Received: 24 July 2022    Accepted: 8 August 2022    Published: 29 November 2022
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Abstract

Another sustainable energy source with many uses is bioethanol. The investigation of diluted H2SO4 hydrolysis (0.25 M to 2 M) was initially conducted in this context of producing bioethanol from maize cob using a magnetic stirrer at varied temperatures (40 to 100°C) and reaction times (60 to 105 min) with the purpose of optimizing the processes. According to the findings, a low glucose output was seen at low acid concentrations of 0.25 M and 0.5 M, increasing gradually at 1 M and 2 M. At a high temperature of 90°C, a significant glucose yield was seen, with the glucose yield decreasing as the reaction time increased past 90 minutes. The outcome additionally demonstrated that yeast affected the glucose yield during fermentation. After fermentation, bioethanol was later recovered by distillation at 78.9°C. Bioethanol characterization showed that kinematic octane rating was 117, cloud point was -11, pour point was -13, flash point was 16.5, and specific gravity was 0.781. The empirical model obtained showed that reaction time, catalyst concentration and reaction temperature are the most important variables that influence the process.

Published in Journal of Biomaterials (Volume 6, Issue 2)
DOI 10.11648/j.jb.20220602.11
Page(s) 20-24
Creative Commons

This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.

Copyright

Copyright © The Author(s), 2024. Published by Science Publishing Group

Keywords

Bioethanol, Maize cob, Fermentation, Optimizing

References
[1] Saeed, A. F. Ni, Y. (2011). Chitosan as a Flocculant for Pre-Hydrolysis Liquor of Kraft-Based Dissolving Pulp Production Process. Carbohydrate Polymer, 86, 1630-1636.
[2] Naik, S. N. Goud, V. V. Rout, P. K. (2010). Production of First and Second Generation Biofuel a Comprehensive Review. Renewable and Sustainable Energy. 14 (2), 578-597.
[3] Farrell, A. E. Plevin, R. J. Jones, A. D. O’hare, M. and Kammen, D. (2006) Ethanol can Contribute to Energy and Developmental Goals. Science 311 (5769), 506-508.
[4] Sivakumar, G. V. D. Xu, J. Burner, J. O. Ge, X. and Weathers, P. J. (2010). Bioethanol and Biodiesel: Alternative Liquid Fuels for Future Generation. Engineering and Life Science, 8-18.
[5] Dufey, A. (2006). Biofuel Production Trade and Sustainable Development Emerging Issues. Environmental Economic Program Sustainable Markets Discussion Paper No. 2. International Institution for Environment and Development (IEED), London.
[6] Balata M. Balata, H. and Cahide, O. Z. (2007). Global Bio-Fuel Processing and Production Trends. Energy Explore Exploit, 195-218.
[7] Demirbas, A. (2005). Bioethanol from Cellulosic Materials: a Renewable Motor Fuel from Biomass. Energy sources, 27 (4), 327-337.
[8] Alvira, P. Tomas-pejo, E. Ballestores, M. and Negro, M. (2010) Pretreatment Technologies for an Efficient Bioethanol Process Based on Enzymatic Hydrolysis a Review. Bioresource Technology. 101 (13), 4851-4861.
[9] Banerjee, S. M. Sen. L. Giri, D. Satpute, T. Chakrabarti, R. A. Pandey (2010). Commercializing Lignocellulosic Bioethanol Technology Bottleneck, Biofuels, Bio Products and Bio Refining Biotechnology, 77-93.
[10] Gurgel (2012). Dilute Acid Hydrolysis of Sugarcane Bagasse at High Temperature: a Kinetic Study of Cellulose Saccharification and Glucose Decomposition. Part 1: Sulfuric Acid as the Catalyst. Industrial and Engineering Chemistry Research, 51 (3), 1173-1185.
[11] Adeeyo, O. A. Ayeni, A. O. Oladimeji, T. E. Oresegun, O. M. (2015) Acid Hydrolysis of Lignocellulosic Content of Sawdust to Fermentable Sugars for Ethanol Production. International Journal of Scientific and Engineering Research, 3-6.
[12] Ajani, A. O. Agarry, S. E. and Agbede, O. O. (2012). A comparative Kinetic Study of Acidic Hydrolysis of Waste Cellulose from Agricultural Derived Biomass. Journal of Nigerian Society of Chemical Engineers, 27 (1), 166-134.
[13] Shen, J. F. P. Soleimani, P. Ni, Y. (2012). Lime Treatment of Pre-hydrolysis Liquor from Kraft-Based Dissolving Pulp Production Process Industries. Engineering and Chemistry Research, 51, 662-667.
[14] Silvia, M. R. Jose, M. Campos, M. and Jose, L. G. (2013) Sustainable Energy and Chemistry Group (EQS), Institute of Catalysis Petroleoquimica, CSIC, Marie Curie, Canto Blanco, 28049 Madrid, Spain, http://www.icp.csic.es/eqsgroup/
[15] Alternative fuel Data center (AFDC) (1997). Replacement Fuel and Alternative Fuel Vehicle Technical and Policy Analysis, an Overview and Summary. The United State Department of Energy.
[16] Galazka, J. M. Tian, C. Beeson, W. T. Martinez, B. Glass, N. l. and Cate, J. H. (2010). Cellodextrin Transport in Yeast for Improved Biofuel Production. Science, 330 (6000), 84-86.
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  • APA Style

    Ogala Harrison, Ige Ayodeji Raphael, Adipere Ebiye, Iboyi Nathaniel, Chidozie Ekene. (2022). Application of Response Surface Design to Optimize the Production of Bioethanol from Lignocellulosic Biomass (Maize cob). Journal of Biomaterials, 6(2), 20-24. https://doi.org/10.11648/j.jb.20220602.11

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    ACS Style

    Ogala Harrison; Ige Ayodeji Raphael; Adipere Ebiye; Iboyi Nathaniel; Chidozie Ekene. Application of Response Surface Design to Optimize the Production of Bioethanol from Lignocellulosic Biomass (Maize cob). J. Biomater. 2022, 6(2), 20-24. doi: 10.11648/j.jb.20220602.11

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    AMA Style

    Ogala Harrison, Ige Ayodeji Raphael, Adipere Ebiye, Iboyi Nathaniel, Chidozie Ekene. Application of Response Surface Design to Optimize the Production of Bioethanol from Lignocellulosic Biomass (Maize cob). J Biomater. 2022;6(2):20-24. doi: 10.11648/j.jb.20220602.11

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  • @article{10.11648/j.jb.20220602.11,
      author = {Ogala Harrison and Ige Ayodeji Raphael and Adipere Ebiye and Iboyi Nathaniel and Chidozie Ekene},
      title = {Application of Response Surface Design to Optimize the Production of Bioethanol from Lignocellulosic Biomass (Maize cob)},
      journal = {Journal of Biomaterials},
      volume = {6},
      number = {2},
      pages = {20-24},
      doi = {10.11648/j.jb.20220602.11},
      url = {https://doi.org/10.11648/j.jb.20220602.11},
      eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.jb.20220602.11},
      abstract = {Another sustainable energy source with many uses is bioethanol. The investigation of diluted H2SO4 hydrolysis (0.25 M to 2 M) was initially conducted in this context of producing bioethanol from maize cob using a magnetic stirrer at varied temperatures (40 to 100°C) and reaction times (60 to 105 min) with the purpose of optimizing the processes. According to the findings, a low glucose output was seen at low acid concentrations of 0.25 M and 0.5 M, increasing gradually at 1 M and 2 M. At a high temperature of 90°C, a significant glucose yield was seen, with the glucose yield decreasing as the reaction time increased past 90 minutes. The outcome additionally demonstrated that yeast affected the glucose yield during fermentation. After fermentation, bioethanol was later recovered by distillation at 78.9°C. Bioethanol characterization showed that kinematic octane rating was 117, cloud point was -11, pour point was -13, flash point was 16.5, and specific gravity was 0.781. The empirical model obtained showed that reaction time, catalyst concentration and reaction temperature are the most important variables that influence the process.},
     year = {2022}
    }
    

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  • TY  - JOUR
    T1  - Application of Response Surface Design to Optimize the Production of Bioethanol from Lignocellulosic Biomass (Maize cob)
    AU  - Ogala Harrison
    AU  - Ige Ayodeji Raphael
    AU  - Adipere Ebiye
    AU  - Iboyi Nathaniel
    AU  - Chidozie Ekene
    Y1  - 2022/11/29
    PY  - 2022
    N1  - https://doi.org/10.11648/j.jb.20220602.11
    DO  - 10.11648/j.jb.20220602.11
    T2  - Journal of Biomaterials
    JF  - Journal of Biomaterials
    JO  - Journal of Biomaterials
    SP  - 20
    EP  - 24
    PB  - Science Publishing Group
    SN  - 2640-2629
    UR  - https://doi.org/10.11648/j.jb.20220602.11
    AB  - Another sustainable energy source with many uses is bioethanol. The investigation of diluted H2SO4 hydrolysis (0.25 M to 2 M) was initially conducted in this context of producing bioethanol from maize cob using a magnetic stirrer at varied temperatures (40 to 100°C) and reaction times (60 to 105 min) with the purpose of optimizing the processes. According to the findings, a low glucose output was seen at low acid concentrations of 0.25 M and 0.5 M, increasing gradually at 1 M and 2 M. At a high temperature of 90°C, a significant glucose yield was seen, with the glucose yield decreasing as the reaction time increased past 90 minutes. The outcome additionally demonstrated that yeast affected the glucose yield during fermentation. After fermentation, bioethanol was later recovered by distillation at 78.9°C. Bioethanol characterization showed that kinematic octane rating was 117, cloud point was -11, pour point was -13, flash point was 16.5, and specific gravity was 0.781. The empirical model obtained showed that reaction time, catalyst concentration and reaction temperature are the most important variables that influence the process.
    VL  - 6
    IS  - 2
    ER  - 

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Author Information
  • Department of Biology and Forensic Sciences, Admiralty University of Nigeria, Ibusa, Nigeria

  • Department of Pure and Applied Chemistry, Kebbi State University of Science and Technology, Aliero, Nigeria

  • Department of Biology and Forensic Sciences, Admiralty University of Nigeria, Ibusa, Nigeria

  • Department of Biology and Forensic Sciences, Admiralty University of Nigeria, Ibusa, Nigeria

  • Department of Biology and Forensic Sciences, Admiralty University of Nigeria, Ibusa, Nigeria

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