A Doubly Functionalized Mesoporous Silica Nanoscavenger for the Analytical Extraction of Triphenyltin from Water

Awad Aqeel Al-rashdi

doi:doi:10.11648/j.sjac.20130101.11

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A Doubly Functionalized Mesoporous Silica Nanoscavenger for the Analytical Extraction of Triphenyltin from Water

Awad Aqeel Al-rashdi

Published in Science Journal of Analytical Chemistry (Volume 1, Issue 1)

Received: 20 July 2013 Published: 20 August 2013

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Abstract

A new analytical procedure has been developed for the determination of triphenyltin(TPT), diphenyltin (DPT), and monophenyltin (MPT) in water samples. The method is based on the use of the dual functionalization of mesoporous silica with diol and C18 alkane groups for the collection of TPT and its derivatives, DPT and MPT, from water samples, followed by hexylation of the target matrices using the Grignard reagent and quantification by gas chromatography with pulsed flame photometric detection. The nanoscavenger concept replaces conventional solid- and liquid-phase extractants with nanosized particles that can be readily dispersed in aqueous samples. Analyte partitioning between the solid and liquid phases occurs as the solid moves through the sample as a colloidal sol. By tailoring the size of the particles to approximately 250 nm in diameter, they can be readily recovered together with the analytes by simple filtration or centrifugation. Recoveries of TPT, DPT, and MPT chloride spiked matrices ranging from 89.3±2.1 to 97.1±1.3 in seawater samples (n= 9 samples). The limit of detection obtained was typically in the range of 0.5–5 ng Sn/L. The proposed method shows excellent linearity in the range of 0.5–2 ng Sn/L and good repeatability (RSD ≤ 5% at 0.02 ng TPT (as Sn)/L). The method performance is demonstrated with real seawater samples.

Published in	Science Journal of Analytical Chemistry (Volume 1, Issue 1)
DOI	10.11648/j.sjac.20130101.11
Page(s)	1-6
Creative Commons	This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.
Copyright	Copyright © The Author(s), 2013. Published by Science Publishing Group

Keywords

Triphenyltin, Mesoporous Silica, Nanoscavenger, Colloidal Sol, Seawater Sample

References

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Awad Aqeel Al-rashdi. (2013). A Doubly Functionalized Mesoporous Silica Nanoscavenger for the Analytical Extraction of Triphenyltin from Water. Science Journal of Analytical Chemistry, 1(1), 1-6. https://doi.org/10.11648/j.sjac.20130101.11

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ACS Style

Awad Aqeel Al-rashdi. A Doubly Functionalized Mesoporous Silica Nanoscavenger for the Analytical Extraction of Triphenyltin from Water. Sci. J. Anal. Chem. 2013, 1(1), 1-6. doi: 10.11648/j.sjac.20130101.11

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AMA Style

Awad Aqeel Al-rashdi. A Doubly Functionalized Mesoporous Silica Nanoscavenger for the Analytical Extraction of Triphenyltin from Water. Sci J Anal Chem. 2013;1(1):1-6. doi: 10.11648/j.sjac.20130101.11

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@article{10.11648/j.sjac.20130101.11,
  author = {Awad Aqeel Al-rashdi},
  title = {A Doubly Functionalized Mesoporous Silica Nanoscavenger for the Analytical Extraction of Triphenyltin from Water},
  journal = {Science Journal of Analytical Chemistry},
  volume = {1},
  number = {1},
  pages = {1-6},
  doi = {10.11648/j.sjac.20130101.11},
  url = {https://doi.org/10.11648/j.sjac.20130101.11},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.sjac.20130101.11},
  abstract = {A new analytical procedure has been developed for the determination of triphenyltin(TPT), diphenyltin (DPT), and monophenyltin (MPT) in water samples. The method is based on the use of the dual functionalization of mesoporous silica with diol and C18 alkane groups for the collection of TPT and its derivatives, DPT and MPT, from water samples, followed by hexylation of the target matrices using the Grignard reagent and quantification by gas chromatography with pulsed flame photometric detection. The nanoscavenger concept replaces conventional solid- and liquid-phase extractants with nanosized particles that can be readily dispersed in aqueous samples. Analyte partitioning between the solid and liquid phases occurs as the solid moves through the sample as a colloidal sol. By tailoring the size of the particles to approximately 250 nm in diameter, they can be readily recovered together with the analytes by simple filtration or centrifugation. Recoveries of TPT, DPT, and MPT chloride spiked matrices ranging from 89.3±2.1 to 97.1±1.3 in seawater samples (n= 9 samples). The limit of detection obtained was typically in the range of 0.5–5 ng Sn/L. The proposed method shows excellent linearity in the range of 0.5–2 ng Sn/L and good repeatability (RSD ≤ 5% at 0.02 ng TPT (as Sn)/L). The method performance is demonstrated with real seawater samples.},
 year = {2013}
}

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TY  - JOUR
T1  - A Doubly Functionalized Mesoporous Silica Nanoscavenger for the Analytical Extraction of Triphenyltin from Water
AU  - Awad Aqeel Al-rashdi
Y1  - 2013/08/20
PY  - 2013
N1  - https://doi.org/10.11648/j.sjac.20130101.11
DO  - 10.11648/j.sjac.20130101.11
T2  - Science Journal of Analytical Chemistry
JF  - Science Journal of Analytical Chemistry
JO  - Science Journal of Analytical Chemistry
SP  - 1
EP  - 6
PB  - Science Publishing Group
SN  - 2376-8053
UR  - https://doi.org/10.11648/j.sjac.20130101.11
AB  - A new analytical procedure has been developed for the determination of triphenyltin(TPT), diphenyltin (DPT), and monophenyltin (MPT) in water samples. The method is based on the use of the dual functionalization of mesoporous silica with diol and C18 alkane groups for the collection of TPT and its derivatives, DPT and MPT, from water samples, followed by hexylation of the target matrices using the Grignard reagent and quantification by gas chromatography with pulsed flame photometric detection. The nanoscavenger concept replaces conventional solid- and liquid-phase extractants with nanosized particles that can be readily dispersed in aqueous samples. Analyte partitioning between the solid and liquid phases occurs as the solid moves through the sample as a colloidal sol. By tailoring the size of the particles to approximately 250 nm in diameter, they can be readily recovered together with the analytes by simple filtration or centrifugation. Recoveries of TPT, DPT, and MPT chloride spiked matrices ranging from 89.3±2.1 to 97.1±1.3 in seawater samples (n= 9 samples). The limit of detection obtained was typically in the range of 0.5–5 ng Sn/L. The proposed method shows excellent linearity in the range of 0.5–2 ng Sn/L and good repeatability (RSD ≤ 5% at 0.02 ng TPT (as Sn)/L). The method performance is demonstrated with real seawater samples.
VL  - 1
IS  - 1
ER  -

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Awad Aqeel Al-rashdi

Department of Chemistry, Al-Qunfudah, Saudi Arabia

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Awad Aqeel Al-rashdi. (2013). A Doubly Functionalized Mesoporous Silica Nanoscavenger for the Analytical Extraction of Triphenyltin from Water. Science Journal of Analytical Chemistry, 1(1), 1-6. https://doi.org/10.11648/j.sjac.20130101.11

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ACS Style

Awad Aqeel Al-rashdi. A Doubly Functionalized Mesoporous Silica Nanoscavenger for the Analytical Extraction of Triphenyltin from Water. Sci. J. Anal. Chem. 2013, 1(1), 1-6. doi: 10.11648/j.sjac.20130101.11

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AMA Style

Awad Aqeel Al-rashdi. A Doubly Functionalized Mesoporous Silica Nanoscavenger for the Analytical Extraction of Triphenyltin from Water. Sci J Anal Chem. 2013;1(1):1-6. doi: 10.11648/j.sjac.20130101.11

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@article{10.11648/j.sjac.20130101.11,
  author = {Awad Aqeel Al-rashdi},
  title = {A Doubly Functionalized Mesoporous Silica Nanoscavenger for the Analytical Extraction of Triphenyltin from Water},
  journal = {Science Journal of Analytical Chemistry},
  volume = {1},
  number = {1},
  pages = {1-6},
  doi = {10.11648/j.sjac.20130101.11},
  url = {https://doi.org/10.11648/j.sjac.20130101.11},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.sjac.20130101.11},
  abstract = {A new analytical procedure has been developed for the determination of triphenyltin(TPT), diphenyltin (DPT), and monophenyltin (MPT) in water samples. The method is based on the use of the dual functionalization of mesoporous silica with diol and C18 alkane groups for the collection of TPT and its derivatives, DPT and MPT, from water samples, followed by hexylation of the target matrices using the Grignard reagent and quantification by gas chromatography with pulsed flame photometric detection. The nanoscavenger concept replaces conventional solid- and liquid-phase extractants with nanosized particles that can be readily dispersed in aqueous samples. Analyte partitioning between the solid and liquid phases occurs as the solid moves through the sample as a colloidal sol. By tailoring the size of the particles to approximately 250 nm in diameter, they can be readily recovered together with the analytes by simple filtration or centrifugation. Recoveries of TPT, DPT, and MPT chloride spiked matrices ranging from 89.3±2.1 to 97.1±1.3 in seawater samples (n= 9 samples). The limit of detection obtained was typically in the range of 0.5–5 ng Sn/L. The proposed method shows excellent linearity in the range of 0.5–2 ng Sn/L and good repeatability (RSD ≤ 5% at 0.02 ng TPT (as Sn)/L). The method performance is demonstrated with real seawater samples.},
 year = {2013}
}

Copy | Download

TY  - JOUR
T1  - A Doubly Functionalized Mesoporous Silica Nanoscavenger for the Analytical Extraction of Triphenyltin from Water
AU  - Awad Aqeel Al-rashdi
Y1  - 2013/08/20
PY  - 2013
N1  - https://doi.org/10.11648/j.sjac.20130101.11
DO  - 10.11648/j.sjac.20130101.11
T2  - Science Journal of Analytical Chemistry
JF  - Science Journal of Analytical Chemistry
JO  - Science Journal of Analytical Chemistry
SP  - 1
EP  - 6
PB  - Science Publishing Group
SN  - 2376-8053
UR  - https://doi.org/10.11648/j.sjac.20130101.11
AB  - A new analytical procedure has been developed for the determination of triphenyltin(TPT), diphenyltin (DPT), and monophenyltin (MPT) in water samples. The method is based on the use of the dual functionalization of mesoporous silica with diol and C18 alkane groups for the collection of TPT and its derivatives, DPT and MPT, from water samples, followed by hexylation of the target matrices using the Grignard reagent and quantification by gas chromatography with pulsed flame photometric detection. The nanoscavenger concept replaces conventional solid- and liquid-phase extractants with nanosized particles that can be readily dispersed in aqueous samples. Analyte partitioning between the solid and liquid phases occurs as the solid moves through the sample as a colloidal sol. By tailoring the size of the particles to approximately 250 nm in diameter, they can be readily recovered together with the analytes by simple filtration or centrifugation. Recoveries of TPT, DPT, and MPT chloride spiked matrices ranging from 89.3±2.1 to 97.1±1.3 in seawater samples (n= 9 samples). The limit of detection obtained was typically in the range of 0.5–5 ng Sn/L. The proposed method shows excellent linearity in the range of 0.5–2 ng Sn/L and good repeatability (RSD ≤ 5% at 0.02 ng TPT (as Sn)/L). The method performance is demonstrated with real seawater samples.
VL  - 1
IS  - 1
ER  -

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