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Adsorption Studies for the Removal Heavy Metal by Chitosan-G-Poly (Acrylicacid-Co-Acrylamide) Composite

Received: 24 September 2014     Accepted: 25 October 2014     Published: 19 December 2014
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Abstract

In present research work natural bio polymer “Chitosan” was grafted onto Acrylic acid and Acrylamide and adsorption of some heavy metal studied by batch method. Synthesis of grafted chitosan supersorbent was synthesized by radical polymerization method. The adsorption of heavy metal cations, Cu(II), Cd(II), Ni(II), and Pb(II) from aqueous solution by newly-synthesized superabsorbent composite of chitosan-g-poly (acrylicacid-co-acrylamide) was investigated. The superabsorbent gel was characterized on the basis of FTIR, X-ray differation, Scanning electron Microscopy and thermal properties. The percentage adsorptions of metal ions on adsorbent were determined by batch methods using atomic absorption spectrophotometry (AAS). The effect of experimental parameters, such as pH, treatment time, temperature, adsorbent dose, initial metal ion concentra¬tion on the removal of metal ions was also studied. Chitosan-g-poly (acrylicacid-co-acrylamide) proved to be an effective adsorbent for the removal of different heavy metal ions from aqueous solution.

Published in Science Journal of Analytical Chemistry (Volume 2, Issue 6)
DOI 10.11648/j.sjac.20140206.12
Page(s) 67-70
Creative Commons

This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.

Copyright

Copyright © The Author(s), 2014. Published by Science Publishing Group

Keywords

Chitosan, Superabsorbent, Acrylamide, Acrylic Acid, Heavymetal, Bio-Adsorption

References
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[3] Dengshan Bao, Preparation and characterization of double crosslinked composites films from carboxymethylchitosan and carboxymethylcellulose Carbohydrate Polymers (September 2014), Volume 110, 22, Pages 113-120.
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[5] Lin H, Zhou J, Yingde C, Gunasekaran S, Synthesis and characterization of pH- and salt-responsive composites based on etherificated sodium alginate, J. Appl. Polym. Sci. (2010),115: 3161-3167.
[6] Jia Liu, Qian Li, Yuan Su, Qinyan Yue, Bao yu Characterization and swelling–deswelling properties of wheat straw cellulose based semi-IPNs composite, Carbohydrate Polymers(17 July 2014)Volume 107, Pages 232-240.
[7] Pourjavadi A, Farhadpour B, Seidi F, Synthesis and investigation of swelling behavior of new agar based superabsorbent composite as a candidate for agrochemical delivery,J. Polym. Res (2009), 16: 655-665.
[8] Mohammad Sadeghi and Mojgan Yarahmadi, Synthesis and characterization of superabsorbent composite based on chitosan-g-poly (acrylic acid-co-acrylonitrile), African Journal of Biotechnology Vol. 10(57), pp. 12265-12275, 28.
[9] Chin-San Wu, A comparison of the structure, thermal properties, and biodegradability of polycaprolactone/chitosan and acrylic acid grafted polycaprolactone/chitosan ,Polymer (6 January 2005)Volume 46, Issue 1,, Pages 147–155.
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    Shyam R. Khairkar, Arun R. Raut. (2014). Adsorption Studies for the Removal Heavy Metal by Chitosan-G-Poly (Acrylicacid-Co-Acrylamide) Composite. Science Journal of Analytical Chemistry, 2(6), 67-70. https://doi.org/10.11648/j.sjac.20140206.12

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    ACS Style

    Shyam R. Khairkar; Arun R. Raut. Adsorption Studies for the Removal Heavy Metal by Chitosan-G-Poly (Acrylicacid-Co-Acrylamide) Composite. Sci. J. Anal. Chem. 2014, 2(6), 67-70. doi: 10.11648/j.sjac.20140206.12

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    AMA Style

    Shyam R. Khairkar, Arun R. Raut. Adsorption Studies for the Removal Heavy Metal by Chitosan-G-Poly (Acrylicacid-Co-Acrylamide) Composite. Sci J Anal Chem. 2014;2(6):67-70. doi: 10.11648/j.sjac.20140206.12

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  • @article{10.11648/j.sjac.20140206.12,
      author = {Shyam R. Khairkar and Arun R. Raut},
      title = {Adsorption Studies for the Removal Heavy Metal by Chitosan-G-Poly (Acrylicacid-Co-Acrylamide) Composite},
      journal = {Science Journal of Analytical Chemistry},
      volume = {2},
      number = {6},
      pages = {67-70},
      doi = {10.11648/j.sjac.20140206.12},
      url = {https://doi.org/10.11648/j.sjac.20140206.12},
      eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.sjac.20140206.12},
      abstract = {In present research work natural bio polymer “Chitosan” was grafted onto Acrylic acid and Acrylamide and adsorption of some heavy metal studied by batch method. Synthesis of grafted chitosan supersorbent was synthesized by radical polymerization method. The adsorption of heavy metal cations, Cu(II), Cd(II), Ni(II), and Pb(II) from aqueous solution by newly-synthesized superabsorbent composite of chitosan-g-poly (acrylicacid-co-acrylamide) was investigated. The superabsorbent gel was characterized on the basis of FTIR, X-ray differation, Scanning electron Microscopy and thermal properties. The percentage adsorptions of metal ions on adsorbent were determined by batch methods using atomic absorption spectrophotometry (AAS). The effect of experimental parameters, such as pH, treatment time, temperature, adsorbent dose, initial metal ion concentra¬tion on the removal of metal ions was also studied. Chitosan-g-poly (acrylicacid-co-acrylamide) proved to be an effective adsorbent for the removal of different heavy metal ions from aqueous solution.},
     year = {2014}
    }
    

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  • TY  - JOUR
    T1  - Adsorption Studies for the Removal Heavy Metal by Chitosan-G-Poly (Acrylicacid-Co-Acrylamide) Composite
    AU  - Shyam R. Khairkar
    AU  - Arun R. Raut
    Y1  - 2014/12/19
    PY  - 2014
    N1  - https://doi.org/10.11648/j.sjac.20140206.12
    DO  - 10.11648/j.sjac.20140206.12
    T2  - Science Journal of Analytical Chemistry
    JF  - Science Journal of Analytical Chemistry
    JO  - Science Journal of Analytical Chemistry
    SP  - 67
    EP  - 70
    PB  - Science Publishing Group
    SN  - 2376-8053
    UR  - https://doi.org/10.11648/j.sjac.20140206.12
    AB  - In present research work natural bio polymer “Chitosan” was grafted onto Acrylic acid and Acrylamide and adsorption of some heavy metal studied by batch method. Synthesis of grafted chitosan supersorbent was synthesized by radical polymerization method. The adsorption of heavy metal cations, Cu(II), Cd(II), Ni(II), and Pb(II) from aqueous solution by newly-synthesized superabsorbent composite of chitosan-g-poly (acrylicacid-co-acrylamide) was investigated. The superabsorbent gel was characterized on the basis of FTIR, X-ray differation, Scanning electron Microscopy and thermal properties. The percentage adsorptions of metal ions on adsorbent were determined by batch methods using atomic absorption spectrophotometry (AAS). The effect of experimental parameters, such as pH, treatment time, temperature, adsorbent dose, initial metal ion concentra¬tion on the removal of metal ions was also studied. Chitosan-g-poly (acrylicacid-co-acrylamide) proved to be an effective adsorbent for the removal of different heavy metal ions from aqueous solution.
    VL  - 2
    IS  - 6
    ER  - 

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Author Information
  • Dept. of Chemistry, Govt. Institute of Science & Humanities Amravati, Amravati, India 444606

  • Dept. of Chemistry, Govt. Institute of Science & Humanities Amravati, Amravati, India 444606

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