Organic substances as pesticides, especially aromatic compounds are a major environmental concern. In the present work, solutions of Promecarb or 3-isopropyl-5-methylphenyl-N-methylcarbamate of pH = 3 have been degraded by electro Fenton process, using a volumic electrochemical reactor filled with carbon graphite. Effects of nature of material of cathode, initial concentration of insecticide and applied current on the kinetics of oxidative degradation and mineralization efficiency have been investigated. Kinetic analysis showed that the oxidation of Promecarb by hydroxyl radicals follows a reaction kinetic of pseudo first order. The absolute rate constant for Promecarb oxidation by hydroxyl radicals was determined as 10.88 × 109 L mol-1 s-1 by competitive kinetics method and benzoic acid was used as reference compound. Mineralization of this pesticide by hydroxyl radicals consists in its transformation to mineral products. The evolution of the mineralization during Promecarb treatment by electro Fenton process was followed by analysis of Total Organic Carbon TOC. Thus, after 3 hours of electrolysis and at I = 800 mA, more than 50% of the organic carbon present in the solution is mineralized. Several degradation products were formed during its electro Fenton treatment. These intermediates were identified using High Performance Liquid Chromatography HPLC, Ionic Chromatography IC and Liquid Chromatography - Mass Spectrometry LC-MS. Based on identification of aromatic intermediates and carboxylic acids, a plausible Promecarb mineralization pathway is proposed. Also, we realized the measurement of the Biochemical Oxygen Demand BOD5 of insecticide solution after treatment by electro Fenton process, to evaluate its biodegradability.
| Published in | Science Journal of Analytical Chemistry (Volume 10, Issue 2) |
| DOI | 10.11648/j.sjac.20221002.11 |
| Page(s) | 15-22 |
| Creative Commons |
This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited. |
| Copyright |
Copyright © The Author(s), 2022. Published by Science Publishing Group |
Promecarb, Electro Fenton, Hydroxyl Radicals, Oxidation, Mineralization
| [1] | S. Chiron, A. Fernandez Alba, A. Rodriguez, E. Garcia Calvo, "Pesticide chemical oxidation: state of the art," Elsevier Science, vol. 34, pp. 366-377, 2000. |
| [2] | S. Sole, A. Merkoci, S. Alegret, "Determination of Toxic Substances Based on Enzyme Inhibition. Part I. Electrochemical Biosensors for the Determination of Pesticides Using Batch Procedures," Crit Rev Anal Chem, vol. 33, pp. 89-126, 2003. |
| [3] | S. Omura, "book: The Search for Bioactive Compounds from Microorganisms, Chapter 13, Insecticides, Acaricides, and Anticoccidial Agents," pp. 241, 1992. |
| [4] | N. L. Pacioni, A. V. Veglia, "Determination of poorly fluorescent carbamate pesticides in water, bendiocarb and promecarb, using cyclodextrin nanocavities and related media," J. Analytica Chimica Acta, vol. 583, pp. 63-71, 2007. |
| [5] | F. Garcia Sanchez, C. Cruces Blanco, Analyst, vol. 116, pp. 851-6, 1991. |
| [6] | W. Andrew, "Pesticide Synthesis" Handbook, pp. 93, 1996. |
| [7] | M. Bourgin, F. Violleau, L. Debrwer, J. Albet, Journal of Hazardous Materials, vol. 190, pp. 60-68, 2011. |
| [8] | F. Moscoso, I. Teijiz, F. J. Deive, M. A. Sanromán, Bioprocess and Biosystems Engineering, pp. 1-7, 2012. |
| [9] | S. Devipriya, S. Yesodharan, Solar Energy Mater. Solar Cells, vol. 86, pp. 309-348, 2005. |
| [10] | M. Pera Titus, V. Garcı´a-Molina, M. A. Ban˜os, J. Gime´nez, S. Esplugas, Appl Catal B: Environ, vol. 47, pp. 219-256, 2004. |
| [11] | S. Malato, P. Fernández-Ibáñez, M. I. Maldonado, J. Blanco, W. Gernjak, "Decontamination and disinfection of water by solar photocatalysis: recent overview and trends," Catalysis Today, vol. 147, pp. 1-59, 2009. |
| [12] | I. Carra, J. Antonio Sánchez Pérez, S. Malato, O. Autin, B. Jeffersond, P. Jarvisd, "Performance of different advanced oxidation processes for tertiary wastewater treatment to remove the pesticide acetamiprid," J Chem Technol Biotechnol, 2014. |
| [13] | O. Iglesias, M. A. F. De Dios, E. Rosales, M. Pazos, M. A. Sanromán, "Optimisation of decolourisation and degradation of Reactive Black 5 dye under electro-Fenton process using Fe alginate gel beads," Environmental Science and Pollution Research, vol. 144, pp. 2172-2183, 2013. |
| [14] | M. Yahya, N. Oturan, K. El Kacemi, M. El Karbane, C. T. Aravindakumar, M. A. Oturan, "Oxidative degradation study on antimicrobial agent ciprofloxacin by electro-fenton process: Kinetics and oxidation products, " Chemosphere, vol. 117, pp. 447-454, 2014. |
| [15] | T. M. Do, J. Y. Byun, S. H. Kim, "An electro Fenton system using magnetite coated metallic foams as cathode for dye degradation," Catalysis Today, vol. 295, pp. 48-55, 2017. |
| [16] | A. Baiju, R. Gandhimathi, S. T. Ramesh, P. V. Nidheesh, "Combined heterogeneous Electro Fenton and biological process for the treatment of stabilized landfill leachate," Journal of Environmental Management, vol. 210, pp. 328-337, 2018. |
| [17] | G. Buftia, E. Rosales, M. Pazos, G. Lazar, M. A. Sanromán, "Electro-Fenton process for implementation of acid black liquor waste treatment," Science of The Total Environment, vol. 635, pp. 397-404, 2018. |
| [18] | A. Özcan, Y. Sahin, A. S. Koparal, M. A. Oturan, "A comparative study on the efficiency of electro-Fenton process in the removal of propham from water," Appl Catal B Environ, vol. 89, pp. 620-626, 2009. |
| [19] | L. Zhou, M. Zhou, Z. Hu, Z. Bi, K. G. Serrano, "Chemically modified graphite felt as an efficient cathode in electro-Fenton for p-nitrophenol degradation," Electrochim Acta, vol. 140, pp. 376-383, 2014. |
| [20] | A. K. Abdessalem, N. Bellakhal, N. Oturan, M. Dachraoui, M. A. Oturan, "Treatment of a mixture of three pesticides by photo- and electro Fenton processes," Desalination, vol. 250, pp. 450-455, 2010. |
| [21] | A. Zcan, Y. Sahin, M. A. Oturan, "Complete removal of the insecticide azinphosmethyl from water by the electro-Fenton method-A kinetic and mechanistic study," Water research, vol. 47, pp. 1470-1479, 2013. |
| [22] | A. Özcan, Y. Sahin, M. A. Oturan, " Removal of propham from water by using electro-Fenton technology: Kinetics and mechanism," Chemosphere, vol. 73, pp. 737-744, 2008. |
| [23] | M. A. Oturan, N. Oturan, M. C. Edelahi, F. I. Podvorica, K. El Kacemi, "Oxidative degradation of herbicide diuron in aqueous medium by Fenton’s reaction based advanced oxidation processes," Chemical Engineering Journal, vol. 171, pp. 127-135, 2011. |
| [24] | A. K. Abdessalem, N. Oturan, N. Bellakhal, M. Dachraoui, M. A. Oturan, "Experimental design methodology applied to electro-Fenton treatment for degradation of herbicide chlortoluron," Applied Catalysis B: Environmental, vol. 78, pp. 334-341, 2008. |
| [25] | O. Iglesias, J. Gómez, M. Pazos, M. Á. Sanromán, "Electro-Fenton oxidation of imidacloprid by Fe alginate gel beads," Applied Catalysis B: Environmental, vol. 144, pp. 416-424, 2014. |
| [26] | A. Dirany, I. Sires, N. Oturan, A. Özcan, M. A. Oturan, "Electrochemical treatment of the antibiotic sulfachloropyridazine: kinetics, reaction pathways and toxicity evolution," Environ Sci Technol, vol. 46, pp. 4074-4082, 2012. |
| [27] | E. Brillas, I. Sirés, M. A. Oturan, "Electro Fenton process and related electrochemical technologies based on Fenton’s reaction chemistry," Chem Rev, vol. 109, pp. 6570- 6631, 2009. |
| [28] | S. Hammami, N. Oturan, N. Bellakhal, M. Dachraoui, M. A. Oturan, "Oxidative degradation of direct orange 61 by electro-Fenton process using a carbon felt electrode: Application of the experimental design methodology," J Electroanal Chem, vol. 610, pp. 75-84, 2007. |
| [29] | M. C. Edelahi, N. Oturan, M. A. Oturan, Y. Padellec, A. Bermond, K. El Kacemi, "Degradation of diuron by the electro-Fenton process," Environ Chem Lett, vol. 1, pp. 233-236, 2004. |
| [30] | A. Alverez-gallegos, D. Pletcher, Eelectrochimica Acta, vol. 44, pp. 2483-2492, 1999. |
| [31] | S. Chou, Y. H. Huang, S. N. Lee, Water Research, vol. 33, pp. 751- 759, 1999. |
| [32] | W. R. Haag, C. C. Davld, Environ Sci Technol, vol. 26, pp. 1005-1013, 1992. |
| [33] | M. Stylidi, D. I. Kondarides, X. E. Verykios, Applied Catalysis B: Environmental, vol. 40, pp. 271-286, 2003. |
| [34] | M. Stylidi, D. I. Kondarides, X. E. Verykios, Applied Catalysis B: Environmental, vol. 47, pp. 189-201, 2004. |
| [35] | A. Özcan, Y. Saahin, M. A. Oturan, Chemosphere, vol. 73, pp. 737-744, 2008. |
| [36] | E. Alfaya, O. Iglesias, M. Pazos, M. A. Sanromán, "Environmental application of an industrial waste as catalyst for the electro Fenton like treatment of organic pollutants," RSC Advances, vol. 5, pp. 14416-14424, 2015. |
| [37] | J. C. Block, L. Mathieu, P. Servais, D. Fontvieille, P. Wermer, "Indigenous bacterial inocula for measuring the biodegradable dissolved organic carbon (BDOC) in waters," Wat Res, vol. 26, pp. 48-486, 1992. |
| [38] | G. Jin, T. Kelley, M. Freeman, M. Callahan, IJP, vol. 4, pp. 127-141, 2006. |
APA Style
Hayet Bakhti, Najib Ben Hamida, Didier Hauchard. (2022). Degradation and Mineralization Study of Promecarb by Electro Fenton Process. Science Journal of Analytical Chemistry, 10(2), 15-22. https://doi.org/10.11648/j.sjac.20221002.11
ACS Style
Hayet Bakhti; Najib Ben Hamida; Didier Hauchard. Degradation and Mineralization Study of Promecarb by Electro Fenton Process. Sci. J. Anal. Chem. 2022, 10(2), 15-22. doi: 10.11648/j.sjac.20221002.11
AMA Style
Hayet Bakhti, Najib Ben Hamida, Didier Hauchard. Degradation and Mineralization Study of Promecarb by Electro Fenton Process. Sci J Anal Chem. 2022;10(2):15-22. doi: 10.11648/j.sjac.20221002.11
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Download@article{10.11648/j.sjac.20221002.11,
author = {Hayet Bakhti and Najib Ben Hamida and Didier Hauchard},
title = {Degradation and Mineralization Study of Promecarb by Electro Fenton Process},
journal = {Science Journal of Analytical Chemistry},
volume = {10},
number = {2},
pages = {15-22},
doi = {10.11648/j.sjac.20221002.11},
url = {https://doi.org/10.11648/j.sjac.20221002.11},
eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.sjac.20221002.11},
abstract = {Organic substances as pesticides, especially aromatic compounds are a major environmental concern. In the present work, solutions of Promecarb or 3-isopropyl-5-methylphenyl-N-methylcarbamate of pH = 3 have been degraded by electro Fenton process, using a volumic electrochemical reactor filled with carbon graphite. Effects of nature of material of cathode, initial concentration of insecticide and applied current on the kinetics of oxidative degradation and mineralization efficiency have been investigated. Kinetic analysis showed that the oxidation of Promecarb by hydroxyl radicals follows a reaction kinetic of pseudo first order. The absolute rate constant for Promecarb oxidation by hydroxyl radicals was determined as 10.88 × 109 L mol-1 s-1 by competitive kinetics method and benzoic acid was used as reference compound. Mineralization of this pesticide by hydroxyl radicals consists in its transformation to mineral products. The evolution of the mineralization during Promecarb treatment by electro Fenton process was followed by analysis of Total Organic Carbon TOC. Thus, after 3 hours of electrolysis and at I = 800 mA, more than 50% of the organic carbon present in the solution is mineralized. Several degradation products were formed during its electro Fenton treatment. These intermediates were identified using High Performance Liquid Chromatography HPLC, Ionic Chromatography IC and Liquid Chromatography - Mass Spectrometry LC-MS. Based on identification of aromatic intermediates and carboxylic acids, a plausible Promecarb mineralization pathway is proposed. Also, we realized the measurement of the Biochemical Oxygen Demand BOD5 of insecticide solution after treatment by electro Fenton process, to evaluate its biodegradability.},
year = {2022}
}
TY - JOUR T1 - Degradation and Mineralization Study of Promecarb by Electro Fenton Process AU - Hayet Bakhti AU - Najib Ben Hamida AU - Didier Hauchard Y1 - 2022/05/12 PY - 2022 N1 - https://doi.org/10.11648/j.sjac.20221002.11 DO - 10.11648/j.sjac.20221002.11 T2 - Science Journal of Analytical Chemistry JF - Science Journal of Analytical Chemistry JO - Science Journal of Analytical Chemistry SP - 15 EP - 22 PB - Science Publishing Group SN - 2376-8053 UR - https://doi.org/10.11648/j.sjac.20221002.11 AB - Organic substances as pesticides, especially aromatic compounds are a major environmental concern. In the present work, solutions of Promecarb or 3-isopropyl-5-methylphenyl-N-methylcarbamate of pH = 3 have been degraded by electro Fenton process, using a volumic electrochemical reactor filled with carbon graphite. Effects of nature of material of cathode, initial concentration of insecticide and applied current on the kinetics of oxidative degradation and mineralization efficiency have been investigated. Kinetic analysis showed that the oxidation of Promecarb by hydroxyl radicals follows a reaction kinetic of pseudo first order. The absolute rate constant for Promecarb oxidation by hydroxyl radicals was determined as 10.88 × 109 L mol-1 s-1 by competitive kinetics method and benzoic acid was used as reference compound. Mineralization of this pesticide by hydroxyl radicals consists in its transformation to mineral products. The evolution of the mineralization during Promecarb treatment by electro Fenton process was followed by analysis of Total Organic Carbon TOC. Thus, after 3 hours of electrolysis and at I = 800 mA, more than 50% of the organic carbon present in the solution is mineralized. Several degradation products were formed during its electro Fenton treatment. These intermediates were identified using High Performance Liquid Chromatography HPLC, Ionic Chromatography IC and Liquid Chromatography - Mass Spectrometry LC-MS. Based on identification of aromatic intermediates and carboxylic acids, a plausible Promecarb mineralization pathway is proposed. Also, we realized the measurement of the Biochemical Oxygen Demand BOD5 of insecticide solution after treatment by electro Fenton process, to evaluate its biodegradability. VL - 10 IS - 2 ER -
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