Anodic Stripping Voltammetric Determination of Thallium at a Mercury Film/Glassy Carbon Electrode: Optimization of the Method and Application to Environmental Waters

Abdoulkadri Ayouba Mahamane; Boubie Guel; Paul Louis Fabre

doi:doi:10.11648/j.sjac.20221004.12

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Anodic Stripping Voltammetric Determination of Thallium at a Mercury Film/Glassy Carbon Electrode: Optimization of the Method and Application to Environmental Waters

Abdoulkadri Ayouba Mahamane, Boubie Guel, Paul Louis Fabre

Published in Science Journal of Analytical Chemistry (Volume 10, Issue 4)

Received: 11 October 2022 Accepted: 7 November 2022 Published: 14 November 2022

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Abstract

This paper describes a procedure for the determination of thallium by differential pulse anodic stripping voltammetry (DPASV) using a mercury film deposited on glassy carbon as the working electrode. The procedure has been optimized using experimental design methodology. The following results were obtained: deposition potential: -1000 mV, deposition time: 4 min, speed of the rotating disc electrode: 1000 rpm, pulse amplitude 80 mV. The response of the electrode towards thallium ions was then verified by establishing the calibration curve, which showed a good correlation coefficient of 0.9973 and the error between 5 successive determinations did not exceed 1.25%. The calculated limit of detection (LOD) is equal to 2.2 10^-8 mol.L^-1. A certified standard of thallium at 1 mg.L^-1 is determined by the standard addition method and the recovery rate obtained is 99.14%. The remarkable electroanalytical performances of the glassy carbon/mercury thin film electrode make it amenable to employ it successfully as an electrochemical sensor for the determination of traces of thallium in environmental samples. Measurements carried out on the waters from wells and boreholes in the village of Yamtenga reveal thallium levels above the standard for some sources of water. These waters are therefore not recommended for use as drinking as drinking water.

Published in	Science Journal of Analytical Chemistry (Volume 10, Issue 4)
DOI	10.11648/j.sjac.20221004.12
Page(s)	74-79
Creative Commons	This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.
Copyright	Copyright © The Author(s), 2022. Published by Science Publishing Group

Keywords

Thallium, Mercury Film, Differential Pulse Anodic Stripping Voltammetry, Optimization, Natural Waters

References

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Abdoulkadri Ayouba Mahamane, Boubie Guel, Paul Louis Fabre. (2022). Anodic Stripping Voltammetric Determination of Thallium at a Mercury Film/Glassy Carbon Electrode: Optimization of the Method and Application to Environmental Waters. Science Journal of Analytical Chemistry, 10(4), 74-79. https://doi.org/10.11648/j.sjac.20221004.12

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ACS Style

Abdoulkadri Ayouba Mahamane; Boubie Guel; Paul Louis Fabre. Anodic Stripping Voltammetric Determination of Thallium at a Mercury Film/Glassy Carbon Electrode: Optimization of the Method and Application to Environmental Waters. Sci. J. Anal. Chem. 2022, 10(4), 74-79. doi: 10.11648/j.sjac.20221004.12

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AMA Style

Abdoulkadri Ayouba Mahamane, Boubie Guel, Paul Louis Fabre. Anodic Stripping Voltammetric Determination of Thallium at a Mercury Film/Glassy Carbon Electrode: Optimization of the Method and Application to Environmental Waters. Sci J Anal Chem. 2022;10(4):74-79. doi: 10.11648/j.sjac.20221004.12

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@article{10.11648/j.sjac.20221004.12,
  author = {Abdoulkadri Ayouba Mahamane and Boubie Guel and Paul Louis Fabre},
  title = {Anodic Stripping Voltammetric Determination of Thallium at a Mercury Film/Glassy Carbon Electrode: Optimization of the Method and Application to Environmental Waters},
  journal = {Science Journal of Analytical Chemistry},
  volume = {10},
  number = {4},
  pages = {74-79},
  doi = {10.11648/j.sjac.20221004.12},
  url = {https://doi.org/10.11648/j.sjac.20221004.12},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.sjac.20221004.12},
  abstract = {This paper describes a procedure for the determination of thallium by differential pulse anodic stripping voltammetry (DPASV) using a mercury film deposited on glassy carbon as the working electrode. The procedure has been optimized using experimental design methodology. The following results were obtained: deposition potential: -1000 mV, deposition time: 4 min, speed of the rotating disc electrode: 1000 rpm, pulse amplitude 80 mV. The response of the electrode towards thallium ions was then verified by establishing the calibration curve, which showed a good correlation coefficient of 0.9973 and the error between 5 successive determinations did not exceed 1.25%. The calculated limit of detection (LOD) is equal to 2.2 10-8 mol.L-1. A certified standard of thallium at 1 mg.L-1 is determined by the standard addition method and the recovery rate obtained is 99.14%. The remarkable electroanalytical performances of the glassy carbon/mercury thin film electrode make it amenable to employ it successfully as an electrochemical sensor for the determination of traces of thallium in environmental samples. Measurements carried out on the waters from wells and boreholes in the village of Yamtenga reveal thallium levels above the standard for some sources of water. These waters are therefore not recommended for use as drinking as drinking water.},
 year = {2022}
}

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TY  - JOUR
T1  - Anodic Stripping Voltammetric Determination of Thallium at a Mercury Film/Glassy Carbon Electrode: Optimization of the Method and Application to Environmental Waters
AU  - Abdoulkadri Ayouba Mahamane
AU  - Boubie Guel
AU  - Paul Louis Fabre
Y1  - 2022/11/14
PY  - 2022
N1  - https://doi.org/10.11648/j.sjac.20221004.12
DO  - 10.11648/j.sjac.20221004.12
T2  - Science Journal of Analytical Chemistry
JF  - Science Journal of Analytical Chemistry
JO  - Science Journal of Analytical Chemistry
SP  - 74
EP  - 79
PB  - Science Publishing Group
SN  - 2376-8053
UR  - https://doi.org/10.11648/j.sjac.20221004.12
AB  - This paper describes a procedure for the determination of thallium by differential pulse anodic stripping voltammetry (DPASV) using a mercury film deposited on glassy carbon as the working electrode. The procedure has been optimized using experimental design methodology. The following results were obtained: deposition potential: -1000 mV, deposition time: 4 min, speed of the rotating disc electrode: 1000 rpm, pulse amplitude 80 mV. The response of the electrode towards thallium ions was then verified by establishing the calibration curve, which showed a good correlation coefficient of 0.9973 and the error between 5 successive determinations did not exceed 1.25%. The calculated limit of detection (LOD) is equal to 2.2 10-8 mol.L-1. A certified standard of thallium at 1 mg.L-1 is determined by the standard addition method and the recovery rate obtained is 99.14%. The remarkable electroanalytical performances of the glassy carbon/mercury thin film electrode make it amenable to employ it successfully as an electrochemical sensor for the determination of traces of thallium in environmental samples. Measurements carried out on the waters from wells and boreholes in the village of Yamtenga reveal thallium levels above the standard for some sources of water. These waters are therefore not recommended for use as drinking as drinking water.
VL  - 10
IS  - 4
ER  -

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Author Information

Abdoulkadri Ayouba Mahamane

Department of Chemistry, Faculty of Sciences, Abdou Moumouni University, Niamey, Niger
Boubie Guel

Department of Chemistry, Faculty of Sciences, Joseph KI ZERBO University, Ouagadougou, Burkina Faso
Paul Louis Fabre

Chemical Engineering Laboratory, University of Toulouse, Toulouse, France

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APA Style

Abdoulkadri Ayouba Mahamane, Boubie Guel, Paul Louis Fabre. (2022). Anodic Stripping Voltammetric Determination of Thallium at a Mercury Film/Glassy Carbon Electrode: Optimization of the Method and Application to Environmental Waters. Science Journal of Analytical Chemistry, 10(4), 74-79. https://doi.org/10.11648/j.sjac.20221004.12

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ACS Style

Abdoulkadri Ayouba Mahamane; Boubie Guel; Paul Louis Fabre. Anodic Stripping Voltammetric Determination of Thallium at a Mercury Film/Glassy Carbon Electrode: Optimization of the Method and Application to Environmental Waters. Sci. J. Anal. Chem. 2022, 10(4), 74-79. doi: 10.11648/j.sjac.20221004.12

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AMA Style

Abdoulkadri Ayouba Mahamane, Boubie Guel, Paul Louis Fabre. Anodic Stripping Voltammetric Determination of Thallium at a Mercury Film/Glassy Carbon Electrode: Optimization of the Method and Application to Environmental Waters. Sci J Anal Chem. 2022;10(4):74-79. doi: 10.11648/j.sjac.20221004.12

Copy | Download

@article{10.11648/j.sjac.20221004.12,
  author = {Abdoulkadri Ayouba Mahamane and Boubie Guel and Paul Louis Fabre},
  title = {Anodic Stripping Voltammetric Determination of Thallium at a Mercury Film/Glassy Carbon Electrode: Optimization of the Method and Application to Environmental Waters},
  journal = {Science Journal of Analytical Chemistry},
  volume = {10},
  number = {4},
  pages = {74-79},
  doi = {10.11648/j.sjac.20221004.12},
  url = {https://doi.org/10.11648/j.sjac.20221004.12},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.sjac.20221004.12},
  abstract = {This paper describes a procedure for the determination of thallium by differential pulse anodic stripping voltammetry (DPASV) using a mercury film deposited on glassy carbon as the working electrode. The procedure has been optimized using experimental design methodology. The following results were obtained: deposition potential: -1000 mV, deposition time: 4 min, speed of the rotating disc electrode: 1000 rpm, pulse amplitude 80 mV. The response of the electrode towards thallium ions was then verified by establishing the calibration curve, which showed a good correlation coefficient of 0.9973 and the error between 5 successive determinations did not exceed 1.25%. The calculated limit of detection (LOD) is equal to 2.2 10-8 mol.L-1. A certified standard of thallium at 1 mg.L-1 is determined by the standard addition method and the recovery rate obtained is 99.14%. The remarkable electroanalytical performances of the glassy carbon/mercury thin film electrode make it amenable to employ it successfully as an electrochemical sensor for the determination of traces of thallium in environmental samples. Measurements carried out on the waters from wells and boreholes in the village of Yamtenga reveal thallium levels above the standard for some sources of water. These waters are therefore not recommended for use as drinking as drinking water.},
 year = {2022}
}

Copy | Download

TY  - JOUR
T1  - Anodic Stripping Voltammetric Determination of Thallium at a Mercury Film/Glassy Carbon Electrode: Optimization of the Method and Application to Environmental Waters
AU  - Abdoulkadri Ayouba Mahamane
AU  - Boubie Guel
AU  - Paul Louis Fabre
Y1  - 2022/11/14
PY  - 2022
N1  - https://doi.org/10.11648/j.sjac.20221004.12
DO  - 10.11648/j.sjac.20221004.12
T2  - Science Journal of Analytical Chemistry
JF  - Science Journal of Analytical Chemistry
JO  - Science Journal of Analytical Chemistry
SP  - 74
EP  - 79
PB  - Science Publishing Group
SN  - 2376-8053
UR  - https://doi.org/10.11648/j.sjac.20221004.12
AB  - This paper describes a procedure for the determination of thallium by differential pulse anodic stripping voltammetry (DPASV) using a mercury film deposited on glassy carbon as the working electrode. The procedure has been optimized using experimental design methodology. The following results were obtained: deposition potential: -1000 mV, deposition time: 4 min, speed of the rotating disc electrode: 1000 rpm, pulse amplitude 80 mV. The response of the electrode towards thallium ions was then verified by establishing the calibration curve, which showed a good correlation coefficient of 0.9973 and the error between 5 successive determinations did not exceed 1.25%. The calculated limit of detection (LOD) is equal to 2.2 10-8 mol.L-1. A certified standard of thallium at 1 mg.L-1 is determined by the standard addition method and the recovery rate obtained is 99.14%. The remarkable electroanalytical performances of the glassy carbon/mercury thin film electrode make it amenable to employ it successfully as an electrochemical sensor for the determination of traces of thallium in environmental samples. Measurements carried out on the waters from wells and boreholes in the village of Yamtenga reveal thallium levels above the standard for some sources of water. These waters are therefore not recommended for use as drinking as drinking water.
VL  - 10
IS  - 4
ER  -

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