Synthesis and Determination of Active Acidic/Basic Sites on Zn Loaded Zeolite (ZSM-5) Catalyst & Its Role in Catalytic Reforming of Naphtha Using HPMR Reactor

Mohd Kamran Khan; Mohd Faizan Alam Siddiqui; Navira Qayyum

doi:doi:10.11648/j.sjac.20231103.11

Research Article |

| Peer-Reviewed

Synthesis and Determination of Active Acidic/Basic Sites on Zn Loaded Zeolite (ZSM-5) Catalyst & Its Role in Catalytic Reforming of Naphtha Using HPMR Reactor

Mohd Kamran Khan^*, Mohd Faizan Alam Siddiqui, Navira Qayyum

Published in Science Journal of Analytical Chemistry (Volume 11, Issue 3)

Received: 23 June 2023 Accepted: 30 October 2023 Published: 8 December 2023

Views: Downloads:

Download PDF

Share This Article

Twitter
Linked In
Facebook

Abstract

The crystalline aluminosilicate ZSM-5 (Zeolite Socony Mobil) has a high Si to Al ratio. It is utilized as a catalytic support material. Zeolite has huge industrial applications. They are commonly employed as heterogeneous catalyst for hydrocarbon isomerization reactions in the petroleum sector. In general, zeolite is synthesized as a powder with low mechanical strength. Powdered ZSM-5 and binder (alumina) were combined, and glacial acetic acid (peptide agent) was added. Mix them thoroughly before loading them into the extruder to form the shape. After drying for one day to let the acetic acid drain, they were heated for eight hours and calcined to remove the liquid from the pores, which aids in the formation of pores/active sites. By mixing the ZnNO₃ solution with the sample, the wet impregnation process is utilized to load Zn metal on extruded ZSM-5. Zn is chosen for loading because it favours cyclization and forming aromatic compounds. After many hours of such wet contact, the suspension evaporates, and the chemical is deposited randomly inside and outside the zeolite pores. Further heating and calcination are carried out. TPD (temperature-programmed desorption) of H/ZSM-5 is performed under catalyst characteristics. TPD of H/ZSM-5 reveals that it comprises primarily highly acidic sites with temperatures above 500°C. The prepared catalyst is employed in the naphtha reforming process in the HPMR (High-Pressure Micro Reactor) to produce BTX as the product.

Published in	Science Journal of Analytical Chemistry (Volume 11, Issue 3)
DOI	10.11648/j.sjac.20231103.11
Page(s)	23-33
Creative Commons	This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.
Copyright	Copyright © The Author(s), 2023. Published by Science Publishing Group

Keywords

Alumino-Silicate, Heterogeneous, Peptide Agent, Isomerization, Naphtha Reforming

References

[1]	Hydrocarbon Processing, September (2012) 47-52.
[2]	N. H. A. Razek and N. M. Michieka, Research in International Business and Finance, 50 (2019) 201-225.
[3]	W. Kang, F. P. Gracia and R. A. Ratti, Energy Economics, 77 (2019) 66-79.
[4]	M. Edgar, In Applied Industrial Catalysis; Leach, B. Eds.; Academic Press: New York, 1 (1983) 123.
[5]	H. Lovink, In Catalytic Naphtha Reforming, Eds.; Marcel Dekker: New York, 1995; 257.
[6]	D. Little, Catalytic Reforming; PennWell, (1985) 25.
[7]	J. Parera and N. Figoli Reactions in the commercial reformer. In Catalytic Naphtha Reforming, Eds.; Marcel Dekker: New York, (1995) 79.
[8]	M. O. Coppens and G. F. Froment, Chemical Engineering Science, 51 (1996) 2283-2292.
[9]	U. D. Turaga, R. Ramanathan, journal of scientific and industrial research 62 (2003) 963-978.
[10]	H. Weifeng, S. Hongye, M. Shengjing, C. Jian, Chinese Journal of Chemical Engineering, 15 (2007) 75-80.
[11]	G. Zahedi, S. Mohammadzadeh and G. Moradi, Energy Fuels, 22 (2008) 2671-2677.
[12]	A. Z. Yusuf, B. O. Aderemi, R. Patel and I. M. Mujtaba, Processes 7 (2019) 192.
[13]	T. Unmesh and B. R. James, American Institute of Chemical Engineer Journal, 43 (1997) 740–753.
[14]	C. L. Pieck, C. R. Vera, J. M. Parea, G. N. Gimenez, L. R. Sera and L. S. Carvalho, Catalysis Today, 107 (2005) 637–642.
[15]	R. G. Axens, Series Catalyst Handbook Catalytic Reforming Catalyst; A. I. G. Technologies, Inc: Paris, France, 2004.
[16]	J. A. Anabtawi, D. S. Redwan, A. M. Al-Jarallah and A. M. Aitani, Fuel Science and Technology International, 9 (1991) 1-23.
[17]	J. R. Anderson and N. R. Avery, Journal of Catalysis, 7 (1967) 315-323.
[18]	Y. Barron, Journal of Catalysis, 2 (1963) 152-155.
[19]	M. R. Rahimpour, M. Jafari and D. Iranshahi, Applied Energy 109 (2013) 79–93.
[20]	M. A. Rodriguez and J. Ancheyta, Fuel, 90 (2011) 3492-3508.
[21]	M. Mahdavian, S. Fatemi, and A. Fazeli, International Journal of Chemical Reactor Engineering, (2010) Article 8.
[22]	I. Mall, Petrochemical process technology, First edition. New Delhi: Macmillan India, 2006.
[23]	M. S. Gyngazova, A. V. Kravtsov, E. D. Ivanchina, M. V. Korolenko and N. V. Chekantsev, Chemical Engineering Journal, 176 (2011) 134-143.
[24]	I. Elizalde and J. Ancheyta, Applied Mathematical Modelling, 39 (2015) 764-775.
[25]	J. W. Lee, Y. C. Ko, Y. K. Jung, K. S. Lee and E. S. Yoon, Computers & Chemical Engineering, 21 (1997) 05–10.
[26]	P. R. Pujado and M. Moser, Catalytic reforming, in: Handbook of Petroleum Processing, ed., Springer, Dordrecht, the Netherlands (2006) 217–237.
[27]	R. A. Meyers, Handbook of petroleum refining processes. New York: McGraw-Hill, (1986) 3.
[28]	R. Pins and G. Schuit, Chemistry and chemical engineering of catalytic processes. The Netherlands: (1980) 389.
[29]	S. Majid, M. Navid and R. Sotudeh-¬Gharebagh, International Journal of Applied Engineering Research, 2 (2011) 1.
[30]	B. S. Babaqi, M. S. Takriff, S. K. Kamarudin and N. T Ali-Othman, International Journal of Applied Engineering Research, 11 (2016) 9984-9989.
[31]	41^st CHT Activity committee meeting on Catalytic reforming and isomerization 9^th to 10^th April 2019 at paradip refinery.
[32]	S. Raseev, Thermal and catalytic Processes in Petroleum Refining, Marcel, Dekker, Inc New York (2003).
[33]	L. Mohan, Catalytic Reforming Process, Catalysts and Reactors 6th Summer School on Petroleum Refining & Petrochemicals Indian Institute of Petroleum Management Gurgaon, June 6-10 (2011).
[34]	A. U. Akram, I. Ahmad and A. Chughtai, International Journal of Energy, 26 (2018) 247-266.

Cite This Article

Plain Text BibTeX RIS

APA Style

Khan, M. K., Siddiqui, M. F. A., Qayyum, N. (2023). Synthesis and Determination of Active Acidic/Basic Sites on Zn Loaded Zeolite (ZSM-5) Catalyst & Its Role in Catalytic Reforming of Naphtha Using HPMR Reactor. Science Journal of Analytical Chemistry, 11(3), 23-33. https://doi.org/10.11648/j.sjac.20231103.11

Copy | Download

ACS Style

Khan, M. K.; Siddiqui, M. F. A.; Qayyum, N. Synthesis and Determination of Active Acidic/Basic Sites on Zn Loaded Zeolite (ZSM-5) Catalyst & Its Role in Catalytic Reforming of Naphtha Using HPMR Reactor. Sci. J. Anal. Chem. 2023, 11(3), 23-33. doi: 10.11648/j.sjac.20231103.11

Copy | Download

AMA Style

Khan MK, Siddiqui MFA, Qayyum N. Synthesis and Determination of Active Acidic/Basic Sites on Zn Loaded Zeolite (ZSM-5) Catalyst & Its Role in Catalytic Reforming of Naphtha Using HPMR Reactor. Sci J Anal Chem. 2023;11(3):23-33. doi: 10.11648/j.sjac.20231103.11

Copy | Download

@article{10.11648/j.sjac.20231103.11,
  author = {Mohd Kamran Khan and Mohd Faizan Alam Siddiqui and Navira Qayyum},
  title = {Synthesis and Determination of Active Acidic/Basic Sites on Zn Loaded Zeolite (ZSM-5) Catalyst & Its Role in Catalytic Reforming of Naphtha Using HPMR Reactor},
  journal = {Science Journal of Analytical Chemistry},
  volume = {11},
  number = {3},
  pages = {23-33},
  doi = {10.11648/j.sjac.20231103.11},
  url = {https://doi.org/10.11648/j.sjac.20231103.11},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.sjac.20231103.11},
  abstract = {The crystalline aluminosilicate ZSM-5 (Zeolite Socony Mobil) has a high Si to Al ratio. It is utilized as a catalytic support material. Zeolite has huge industrial applications. They are commonly employed as heterogeneous catalyst for hydrocarbon isomerization reactions in the petroleum sector. In general, zeolite is synthesized as a powder with low mechanical strength. Powdered ZSM-5 and binder (alumina) were combined, and glacial acetic acid (peptide agent) was added. Mix them thoroughly before loading them into the extruder to form the shape. After drying for one day to let the acetic acid drain, they were heated for eight hours and calcined to remove the liquid from the pores, which aids in the formation of pores/active sites. By mixing the ZnNO3 solution with the sample, the wet impregnation process is utilized to load Zn metal on extruded ZSM-5. Zn is chosen for loading because it favours cyclization and forming aromatic compounds. After many hours of such wet contact, the suspension evaporates, and the chemical is deposited randomly inside and outside the zeolite pores. Further heating and calcination are carried out. TPD (temperature-programmed desorption) of H/ZSM-5 is performed under catalyst characteristics. TPD of H/ZSM-5 reveals that it comprises primarily highly acidic sites with temperatures above 500°C. The prepared catalyst is employed in the naphtha reforming process in the HPMR (High-Pressure Micro Reactor) to produce BTX as the product.
},
 year = {2023}
}

Copy | Download

TY - JOUR
T1 - Synthesis and Determination of Active Acidic/Basic Sites on Zn Loaded Zeolite (ZSM-5) Catalyst & Its Role in Catalytic Reforming of Naphtha Using HPMR Reactor
AU - Mohd Kamran Khan
AU - Mohd Faizan Alam Siddiqui
AU - Navira Qayyum
Y1 - 2023/12/08
PY - 2023
N1 - https://doi.org/10.11648/j.sjac.20231103.11
DO - 10.11648/j.sjac.20231103.11
T2 - Science Journal of Analytical Chemistry
JF - Science Journal of Analytical Chemistry
JO - Science Journal of Analytical Chemistry
SP - 23
EP - 33
PB - Science Publishing Group
SN - 2376-8053
UR - https://doi.org/10.11648/j.sjac.20231103.11
AB - The crystalline aluminosilicate ZSM-5 (Zeolite Socony Mobil) has a high Si to Al ratio. It is utilized as a catalytic support material. Zeolite has huge industrial applications. They are commonly employed as heterogeneous catalyst for hydrocarbon isomerization reactions in the petroleum sector. In general, zeolite is synthesized as a powder with low mechanical strength. Powdered ZSM-5 and binder (alumina) were combined, and glacial acetic acid (peptide agent) was added. Mix them thoroughly before loading them into the extruder to form the shape. After drying for one day to let the acetic acid drain, they were heated for eight hours and calcined to remove the liquid from the pores, which aids in the formation of pores/active sites. By mixing the ZnNO3 solution with the sample, the wet impregnation process is utilized to load Zn metal on extruded ZSM-5. Zn is chosen for loading because it favours cyclization and forming aromatic compounds. After many hours of such wet contact, the suspension evaporates, and the chemical is deposited randomly inside and outside the zeolite pores. Further heating and calcination are carried out. TPD (temperature-programmed desorption) of H/ZSM-5 is performed under catalyst characteristics. TPD of H/ZSM-5 reveals that it comprises primarily highly acidic sites with temperatures above 500°C. The prepared catalyst is employed in the naphtha reforming process in the HPMR (High-Pressure Micro Reactor) to produce BTX as the product.

VL - 11
IS - 3
ER -

Copy | Download

Author Information

Mohd Kamran Khan

Department of Industrial Chemistry, Faculty of Science, Aligarh Muslim University, Aligarh, India

Contact Email
Mohd Faizan Alam Siddiqui

Department of Chemistry, Faculty of Science, Aligarh Muslim University, Aligarh, India

Contact Email
Navira Qayyum

Department of Industrial Chemistry, Faculty of Science, Aligarh Muslim University, Aligarh, India

Download PDF

Sections

Plain Text BibTeX RIS

APA Style

Khan, M. K., Siddiqui, M. F. A., Qayyum, N. (2023). Synthesis and Determination of Active Acidic/Basic Sites on Zn Loaded Zeolite (ZSM-5) Catalyst & Its Role in Catalytic Reforming of Naphtha Using HPMR Reactor. Science Journal of Analytical Chemistry, 11(3), 23-33. https://doi.org/10.11648/j.sjac.20231103.11

Copy | Download

ACS Style

Khan, M. K.; Siddiqui, M. F. A.; Qayyum, N. Synthesis and Determination of Active Acidic/Basic Sites on Zn Loaded Zeolite (ZSM-5) Catalyst & Its Role in Catalytic Reforming of Naphtha Using HPMR Reactor. Sci. J. Anal. Chem. 2023, 11(3), 23-33. doi: 10.11648/j.sjac.20231103.11

Copy | Download

AMA Style

Khan MK, Siddiqui MFA, Qayyum N. Synthesis and Determination of Active Acidic/Basic Sites on Zn Loaded Zeolite (ZSM-5) Catalyst & Its Role in Catalytic Reforming of Naphtha Using HPMR Reactor. Sci J Anal Chem. 2023;11(3):23-33. doi: 10.11648/j.sjac.20231103.11

Copy | Download

@article{10.11648/j.sjac.20231103.11,
  author = {Mohd Kamran Khan and Mohd Faizan Alam Siddiqui and Navira Qayyum},
  title = {Synthesis and Determination of Active Acidic/Basic Sites on Zn Loaded Zeolite (ZSM-5) Catalyst & Its Role in Catalytic Reforming of Naphtha Using HPMR Reactor},
  journal = {Science Journal of Analytical Chemistry},
  volume = {11},
  number = {3},
  pages = {23-33},
  doi = {10.11648/j.sjac.20231103.11},
  url = {https://doi.org/10.11648/j.sjac.20231103.11},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.sjac.20231103.11},
  abstract = {The crystalline aluminosilicate ZSM-5 (Zeolite Socony Mobil) has a high Si to Al ratio. It is utilized as a catalytic support material. Zeolite has huge industrial applications. They are commonly employed as heterogeneous catalyst for hydrocarbon isomerization reactions in the petroleum sector. In general, zeolite is synthesized as a powder with low mechanical strength. Powdered ZSM-5 and binder (alumina) were combined, and glacial acetic acid (peptide agent) was added. Mix them thoroughly before loading them into the extruder to form the shape. After drying for one day to let the acetic acid drain, they were heated for eight hours and calcined to remove the liquid from the pores, which aids in the formation of pores/active sites. By mixing the ZnNO3 solution with the sample, the wet impregnation process is utilized to load Zn metal on extruded ZSM-5. Zn is chosen for loading because it favours cyclization and forming aromatic compounds. After many hours of such wet contact, the suspension evaporates, and the chemical is deposited randomly inside and outside the zeolite pores. Further heating and calcination are carried out. TPD (temperature-programmed desorption) of H/ZSM-5 is performed under catalyst characteristics. TPD of H/ZSM-5 reveals that it comprises primarily highly acidic sites with temperatures above 500°C. The prepared catalyst is employed in the naphtha reforming process in the HPMR (High-Pressure Micro Reactor) to produce BTX as the product.
},
 year = {2023}
}

Copy | Download

VL - 11
IS - 3
ER -

Copy | Download