Comparative Spectrophotometric Determination of Neodymium (III), Praseodymium (III), Samarium (III) and Terbium (III) in Aqueous and Micelle Media

Uwanta Emaime Jimmy; Nicholas Eno-obong Sunday; Ikpe Edidiong Emmanuel; Ocheni Adejoh; Ukoha Pius Onyeoziri

doi:doi:10.11648/j.sjc.20231102.14

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Comparative Spectrophotometric Determination of Neodymium (III), Praseodymium (III), Samarium (III) and Terbium (III) in Aqueous and Micelle Media

Uwanta Emaime Jimmy, Nicholas Eno-obong Sunday, Ikpe Edidiong Emmanuel, Ocheni Adejoh, Ukoha Pius Onyeoziri

Published in Science Journal of Chemistry (Volume 11, Issue 2)

Received: 4 April 2023 Accepted: 20 April 2023 Published: 27 April 2023

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Abstract

This research work titled comparative spectrophotometric determination of neodymium (III), praseodymium (III), samarium (III) and terbium (III)in aqueous and micelle media using schiff base was carried out with the aim to use a simple, rapid and sensitive spectrophotometric method for the determination of Nd (III), Pr (III), Sm(III) and Tb(III) using the Schiff base 2,2′-((1E,1′E)-(1,2-phenylenebis(azanlylidene)bis (methanylylidene))diphenol (BSOPD) as a ligand. Spectral and absorbance measurements were carried out using UV/Visible Spectrophotometer (Jenway model no.: 6305) with 1-cm matched quartz cells. This method of experiment was based on the formation of green coloured complexes, upon the reaction of Nd(III) and Pr(III) and a brown coloured complexes for Sm(III) and Tb(III) having a maximum absorbance of 376, 386, 384 and 380 nm respectively. The comparative analysis of the complexes formed in aqueous and in micellar media were investigated in this study. In the obtained results, it was discovered that, Beer’s law was obeyed in the concentration ranges of 0.001 - 0.02 ppm. The molar absorptivity was found to be in the range of 7,776- 23,197 and 27,087 dm³mol^-1cm^-1 and the Sandell’s sensitivity for the compounds analyzed were in the ranges of 6.13-19.34 g cm^-2. The increase in absorbance in the presence of the surfactants is due to micelle formation. The reactants were bound in a small volume of stern layer of the micelle leading to a greater increase in concentration effect. This effect in concentration reaches a maximum before decreasing due to dilution effect occasioned by increase in metal ion concentration.

Published in	Science Journal of Chemistry (Volume 11, Issue 2)
DOI	10.11648/j.sjc.20231102.14
Page(s)	64-70
Creative Commons	This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.
Copyright	Copyright © The Author(s), 2024. Published by Science Publishing Group

Keywords

Schiff Base, Metal Complexes, Lanthanides, Stoichiometry, Spectrophotometer

References

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[2]	McGill, I. (2005,). “Rare Earth Elements” Ullmann’s Encyclopedia of Industrial Chemistry, (31) Weinheim. Wiley-VCH. 191.
[3]	Livergood, R. (2005). Rare Earth Elements: A Wrench in the Supply Chain (PDF) Center for Strategic and International Studies.
[4]	Haxel, G.; Hedrick, J. and Orris, J. (2006). Rare earth element critical resources for high technology. Reston (VA) United States Geological Survey USGS fact sheet, 087-02 (PDF).
[5]	Spinu, C.; Pleniceanu, M. and Tigae, C. (2008). Biologically Active Transition metal Chelates with a 2-Thiophenecarboxaldehyde-Derived Schiff Base: Synthesis, Characterization, and Antibacterial Properties. Turk. J. Chem., 32, 487.
[6]	Drozd, A. V and Baskir, I. M. (2002). Simultaneous Determination of Zinc and Cadmium with 1-(2-naphthol in aqueous micellar solution using Two Dimensional Absorption Spectra. J. Anal Chem., 57, 1, 12-14.
[7]	Mathew, A. V.; Kumar, K.; Rao, I. M.; Satyanarayana, A. and Shyamala, P. (2012). Spectrophotometric determination of neodymium (III), samarium (III), dysprosium(III), holmium(III) in micellar media. Ind. J. chem. Techno., 19, 331-336.
[8]	Dhepe, A. S. and Zade, A. B. (2011). Spectrophotometric study of ternary complex forming systems of some lanthanide metal ions with Eriochrome Cyanide R in presence of Cetylpyridinium Bromide for micro-determination. E-journal of Chemistry, 8 (3), 1264-1274. DOI: 10.1155/2011/871685.
[9]	Belsare, G. W.; Zade, A. B.; Kalbende, P. P. and Belsare, P. U. (2012). Spectrophotometric study of ternary complex forming systems of some rare earths with bromopyrogallol red in presence of cetyldimethylammonium bromide for micro-determination. Der Pharma Chemica., 4 (3), 1226 -1238.
[10]	Athira, C. J.; Sindhu, Y.; Sujamol, M. S and Mohanan, K. (2011). Synthesis and spectroscopic characterization of some Lanthanide (111) nitrate complexes of ethyl 2-[2-(1-acetyl-2-oxopropyl)azo]-4,5-dimethyl-3-thiophenecarboxylate. Jour. serb. chem. soc., 76 (2), 249-261.
[11]	Dik, T. A.; Kostyuk, N. N and Trebikov, A. O. (2003). Spectrophotometric determination of Sm (III) content in hydrochloric acid solution. Jour. Appl. Spectro., 70, 729-732.
[12]	Gadzhieva, S. R; Chyragov, F. M and Guscinov, F. E. (2005). Spectrophotometric study of the complexation of Samarium (III) with disodium 2-(2-hydroxy -3-sulfo-5-nitrophenylazo) naphthalene-1,8-dihydroxy-3,6-disulfonate in the presence of cetyltrimethylammonium bromide. Jour. Anal. Chem., 60, 819-821.
[13]	Mohanan, K.; Athira, C. J; Sindhu, Y and Sujamol, M. S. (2009). Synthesis, spectroscopic characterization and thermal studies of some Lanthanide (III) nitrate complexes with a hydrazo derivative of 4-aminoantipyrine. Journal of rare-earths., 27 (5), 705.
[14]	Ratre, P. and Kumar, D. (2013). Spectrophotometric Determination of Trace Amounts of Samarium in Environmental Samples. American International Journal of Research in Formal, Applied & Natural Sciences. USA. AURFAN 13-254, 110-118.
[15]	Uwanta, E. J.; Ukoha, P. O. and Ekwere, I. O. (2020). Synthesis and Characterization of Neodymium (III), Samarium (III) and Terbium (III) Complexes Containing Bis(Salicylaldehyde)Orthophenylenediamine as Ligand. Scientific Research Journal (SCIRJ), 8 (6), 5-10. http://dx.doi.org/10.31364/SCIRJ/v8.i6.2020.P0620XX
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Uwanta Emaime Jimmy, Nicholas Eno-obong Sunday, Ikpe Edidiong Emmanuel, Ocheni Adejoh, Ukoha Pius Onyeoziri. (2023). Comparative Spectrophotometric Determination of Neodymium (III), Praseodymium (III), Samarium (III) and Terbium (III) in Aqueous and Micelle Media. Science Journal of Chemistry, 11(2), 64-70. https://doi.org/10.11648/j.sjc.20231102.14

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Uwanta Emaime Jimmy; Nicholas Eno-obong Sunday; Ikpe Edidiong Emmanuel; Ocheni Adejoh; Ukoha Pius Onyeoziri. Comparative Spectrophotometric Determination of Neodymium (III), Praseodymium (III), Samarium (III) and Terbium (III) in Aqueous and Micelle Media. Sci. J. Chem. 2023, 11(2), 64-70. doi: 10.11648/j.sjc.20231102.14

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Uwanta Emaime Jimmy, Nicholas Eno-obong Sunday, Ikpe Edidiong Emmanuel, Ocheni Adejoh, Ukoha Pius Onyeoziri. Comparative Spectrophotometric Determination of Neodymium (III), Praseodymium (III), Samarium (III) and Terbium (III) in Aqueous and Micelle Media. Sci J Chem. 2023;11(2):64-70. doi: 10.11648/j.sjc.20231102.14

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@article{10.11648/j.sjc.20231102.14,
  author = {Uwanta Emaime Jimmy and Nicholas Eno-obong Sunday and Ikpe Edidiong Emmanuel and Ocheni Adejoh and Ukoha Pius Onyeoziri},
  title = {Comparative Spectrophotometric Determination of Neodymium (III), Praseodymium (III), Samarium (III) and Terbium (III) in Aqueous and Micelle Media},
  journal = {Science Journal of Chemistry},
  volume = {11},
  number = {2},
  pages = {64-70},
  doi = {10.11648/j.sjc.20231102.14},
  url = {https://doi.org/10.11648/j.sjc.20231102.14},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.sjc.20231102.14},
  abstract = {This research work titled comparative spectrophotometric determination of neodymium (III), praseodymium (III), samarium (III) and terbium (III)in aqueous and micelle media using schiff base was carried out with the aim to use a simple, rapid and sensitive spectrophotometric method for the determination of Nd (III), Pr (III), Sm(III) and Tb(III) using the Schiff base 2,2′-((1E,1′E)-(1,2-phenylenebis(azanlylidene)bis (methanylylidene))diphenol (BSOPD) as a ligand. Spectral and absorbance measurements were carried out using UV/Visible Spectrophotometer (Jenway model no.: 6305) with 1-cm matched quartz cells. This method of experiment was based on the formation of green coloured complexes, upon the reaction of Nd(III) and Pr(III) and a brown coloured complexes for Sm(III) and Tb(III) having a maximum absorbance of 376, 386, 384 and 380 nm respectively. The comparative analysis of the complexes formed in aqueous and in micellar media were investigated in this study. In the obtained results, it was discovered that, Beer’s law was obeyed in the concentration ranges of 0.001 - 0.02 ppm. The molar absorptivity was found to be in the range of 7,776- 23,197 and 27,087 dm3mol-1cm-1 and the Sandell’s sensitivity for the compounds analyzed were in the ranges of 6.13-19.34 g cm-2. The increase in absorbance in the presence of the surfactants is due to micelle formation. The reactants were bound in a small volume of stern layer of the micelle leading to a greater increase in concentration effect. This effect in concentration reaches a maximum before decreasing due to dilution effect occasioned by increase in metal ion concentration.},
 year = {2023}
}

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TY  - JOUR
T1  - Comparative Spectrophotometric Determination of Neodymium (III), Praseodymium (III), Samarium (III) and Terbium (III) in Aqueous and Micelle Media
AU  - Uwanta Emaime Jimmy
AU  - Nicholas Eno-obong Sunday
AU  - Ikpe Edidiong Emmanuel
AU  - Ocheni Adejoh
AU  - Ukoha Pius Onyeoziri
Y1  - 2023/04/27
PY  - 2023
N1  - https://doi.org/10.11648/j.sjc.20231102.14
DO  - 10.11648/j.sjc.20231102.14
T2  - Science Journal of Chemistry
JF  - Science Journal of Chemistry
JO  - Science Journal of Chemistry
SP  - 64
EP  - 70
PB  - Science Publishing Group
SN  - 2330-099X
UR  - https://doi.org/10.11648/j.sjc.20231102.14
AB  - This research work titled comparative spectrophotometric determination of neodymium (III), praseodymium (III), samarium (III) and terbium (III)in aqueous and micelle media using schiff base was carried out with the aim to use a simple, rapid and sensitive spectrophotometric method for the determination of Nd (III), Pr (III), Sm(III) and Tb(III) using the Schiff base 2,2′-((1E,1′E)-(1,2-phenylenebis(azanlylidene)bis (methanylylidene))diphenol (BSOPD) as a ligand. Spectral and absorbance measurements were carried out using UV/Visible Spectrophotometer (Jenway model no.: 6305) with 1-cm matched quartz cells. This method of experiment was based on the formation of green coloured complexes, upon the reaction of Nd(III) and Pr(III) and a brown coloured complexes for Sm(III) and Tb(III) having a maximum absorbance of 376, 386, 384 and 380 nm respectively. The comparative analysis of the complexes formed in aqueous and in micellar media were investigated in this study. In the obtained results, it was discovered that, Beer’s law was obeyed in the concentration ranges of 0.001 - 0.02 ppm. The molar absorptivity was found to be in the range of 7,776- 23,197 and 27,087 dm3mol-1cm-1 and the Sandell’s sensitivity for the compounds analyzed were in the ranges of 6.13-19.34 g cm-2. The increase in absorbance in the presence of the surfactants is due to micelle formation. The reactants were bound in a small volume of stern layer of the micelle leading to a greater increase in concentration effect. This effect in concentration reaches a maximum before decreasing due to dilution effect occasioned by increase in metal ion concentration.
VL  - 11
IS  - 2
ER  -

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Author Information

Uwanta Emaime Jimmy

Department of Chemistry, Faculty of Physical Sciences, Akwa Ibom State University, Ikot Akpaden, Nigeria
Nicholas Eno-obong Sunday

Department of Pure and Industrial Chemistry, Faculty of Physical Sciences, University of Nigeria, Nsukka, Nigeria
Ikpe Edidiong Emmanuel

Department of Chemistry, Faculty of Physical Sciences, Akwa Ibom State University, Ikot Akpaden, Nigeria
Ocheni Adejoh

Department of Chemistry, Faculty of Natural Sciences, Kogi State University, Anyigba, Nigeria
Ukoha Pius Onyeoziri

Department of Pure and Industrial Chemistry, Faculty of Physical Sciences, University of Nigeria, Nsukka, Nigeria

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APA Style

Uwanta Emaime Jimmy, Nicholas Eno-obong Sunday, Ikpe Edidiong Emmanuel, Ocheni Adejoh, Ukoha Pius Onyeoziri. (2023). Comparative Spectrophotometric Determination of Neodymium (III), Praseodymium (III), Samarium (III) and Terbium (III) in Aqueous and Micelle Media. Science Journal of Chemistry, 11(2), 64-70. https://doi.org/10.11648/j.sjc.20231102.14

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ACS Style

Uwanta Emaime Jimmy; Nicholas Eno-obong Sunday; Ikpe Edidiong Emmanuel; Ocheni Adejoh; Ukoha Pius Onyeoziri. Comparative Spectrophotometric Determination of Neodymium (III), Praseodymium (III), Samarium (III) and Terbium (III) in Aqueous and Micelle Media. Sci. J. Chem. 2023, 11(2), 64-70. doi: 10.11648/j.sjc.20231102.14

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AMA Style

Uwanta Emaime Jimmy, Nicholas Eno-obong Sunday, Ikpe Edidiong Emmanuel, Ocheni Adejoh, Ukoha Pius Onyeoziri. Comparative Spectrophotometric Determination of Neodymium (III), Praseodymium (III), Samarium (III) and Terbium (III) in Aqueous and Micelle Media. Sci J Chem. 2023;11(2):64-70. doi: 10.11648/j.sjc.20231102.14

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@article{10.11648/j.sjc.20231102.14,
  author = {Uwanta Emaime Jimmy and Nicholas Eno-obong Sunday and Ikpe Edidiong Emmanuel and Ocheni Adejoh and Ukoha Pius Onyeoziri},
  title = {Comparative Spectrophotometric Determination of Neodymium (III), Praseodymium (III), Samarium (III) and Terbium (III) in Aqueous and Micelle Media},
  journal = {Science Journal of Chemistry},
  volume = {11},
  number = {2},
  pages = {64-70},
  doi = {10.11648/j.sjc.20231102.14},
  url = {https://doi.org/10.11648/j.sjc.20231102.14},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.sjc.20231102.14},
  abstract = {This research work titled comparative spectrophotometric determination of neodymium (III), praseodymium (III), samarium (III) and terbium (III)in aqueous and micelle media using schiff base was carried out with the aim to use a simple, rapid and sensitive spectrophotometric method for the determination of Nd (III), Pr (III), Sm(III) and Tb(III) using the Schiff base 2,2′-((1E,1′E)-(1,2-phenylenebis(azanlylidene)bis (methanylylidene))diphenol (BSOPD) as a ligand. Spectral and absorbance measurements were carried out using UV/Visible Spectrophotometer (Jenway model no.: 6305) with 1-cm matched quartz cells. This method of experiment was based on the formation of green coloured complexes, upon the reaction of Nd(III) and Pr(III) and a brown coloured complexes for Sm(III) and Tb(III) having a maximum absorbance of 376, 386, 384 and 380 nm respectively. The comparative analysis of the complexes formed in aqueous and in micellar media were investigated in this study. In the obtained results, it was discovered that, Beer’s law was obeyed in the concentration ranges of 0.001 - 0.02 ppm. The molar absorptivity was found to be in the range of 7,776- 23,197 and 27,087 dm3mol-1cm-1 and the Sandell’s sensitivity for the compounds analyzed were in the ranges of 6.13-19.34 g cm-2. The increase in absorbance in the presence of the surfactants is due to micelle formation. The reactants were bound in a small volume of stern layer of the micelle leading to a greater increase in concentration effect. This effect in concentration reaches a maximum before decreasing due to dilution effect occasioned by increase in metal ion concentration.},
 year = {2023}
}

Copy | Download

TY  - JOUR
T1  - Comparative Spectrophotometric Determination of Neodymium (III), Praseodymium (III), Samarium (III) and Terbium (III) in Aqueous and Micelle Media
AU  - Uwanta Emaime Jimmy
AU  - Nicholas Eno-obong Sunday
AU  - Ikpe Edidiong Emmanuel
AU  - Ocheni Adejoh
AU  - Ukoha Pius Onyeoziri
Y1  - 2023/04/27
PY  - 2023
N1  - https://doi.org/10.11648/j.sjc.20231102.14
DO  - 10.11648/j.sjc.20231102.14
T2  - Science Journal of Chemistry
JF  - Science Journal of Chemistry
JO  - Science Journal of Chemistry
SP  - 64
EP  - 70
PB  - Science Publishing Group
SN  - 2330-099X
UR  - https://doi.org/10.11648/j.sjc.20231102.14
AB  - This research work titled comparative spectrophotometric determination of neodymium (III), praseodymium (III), samarium (III) and terbium (III)in aqueous and micelle media using schiff base was carried out with the aim to use a simple, rapid and sensitive spectrophotometric method for the determination of Nd (III), Pr (III), Sm(III) and Tb(III) using the Schiff base 2,2′-((1E,1′E)-(1,2-phenylenebis(azanlylidene)bis (methanylylidene))diphenol (BSOPD) as a ligand. Spectral and absorbance measurements were carried out using UV/Visible Spectrophotometer (Jenway model no.: 6305) with 1-cm matched quartz cells. This method of experiment was based on the formation of green coloured complexes, upon the reaction of Nd(III) and Pr(III) and a brown coloured complexes for Sm(III) and Tb(III) having a maximum absorbance of 376, 386, 384 and 380 nm respectively. The comparative analysis of the complexes formed in aqueous and in micellar media were investigated in this study. In the obtained results, it was discovered that, Beer’s law was obeyed in the concentration ranges of 0.001 - 0.02 ppm. The molar absorptivity was found to be in the range of 7,776- 23,197 and 27,087 dm3mol-1cm-1 and the Sandell’s sensitivity for the compounds analyzed were in the ranges of 6.13-19.34 g cm-2. The increase in absorbance in the presence of the surfactants is due to micelle formation. The reactants were bound in a small volume of stern layer of the micelle leading to a greater increase in concentration effect. This effect in concentration reaches a maximum before decreasing due to dilution effect occasioned by increase in metal ion concentration.
VL  - 11
IS  - 2
ER  -

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