Study of the PPCA-Materials’ Acid Sites and Basic Sites to Extract the MSB - 3-Methyl-3-Sulfanylbutan-1-Ol

Andry Tahina Rabeharitsara; Henri Rakotondrina; Nambinina Richard Randriana; Hanitraniaina Marie Ratsimba; Rakotomamonjy Pierre; Soloniaina Rakotoarijaona

doi:doi:10.11648/j.ajaic.20230702.12

Research Article |

Study of the PPCA-Materials’ Acid Sites and Basic Sites to Extract the MSB - 3-Methyl-3-Sulfanylbutan-1-Ol

Andry Tahina Rabeharitsara, Henri Rakotondrina, Nambinina Richard Randriana, Hanitraniaina Marie Ratsimba, Rakotomamonjy Pierre, Soloniaina Rakotoarijaona

Published in American Journal of Applied and Industrial Chemistry (Volume 7, Issue 2)

Received: 20 September 2023 Accepted: 12 October 2023 Published: 28 October 2023

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Abstract

The MSB - 3-Methyl-3-Sulfanylbutan-1-Ol is a thiol molecule which could be used as food additive flavor agent and encountered in the white wine, in the coffee perfume, in the passion fruit and in the cat urine where it’s the responsible of its strong odor characteristics. Its extraction from the cat-litter and the synthesis of a new material based on black citric acid polymers (pn), pozzolana and citric acid named PPCA (pn-pozzolana-citric-acid) was studied in the previous manuscript. This manuscript consisted to valorize the PPCA as material to extract and to retain the MSB - 3-Methyl-3-Sulfanylbutan-1-Ol molecule. Thus, reaction tests were done between a MSB - 3-Methyl-3-Sulfanylbutan-1-Ol solution and the PPCA. The first part of this manuscript treated the description of these reaction tests procedure and the various experimental conditions which was at ambient temperature, in the open air and at atmospheric pressure inside a container without a cover. It was also described on this first part the quantifications of the molecules and PPCA’s sites involved in this reaction such as citric acid residues, MSB, acid sites and basic sites which were especially considered as sites governing the reaction-extraction between the PPCA-material and the MSB - 3-Methyl-3-Sulfanylbutan-1-Ol molecules. The second part of this manuscript consisted on the analyzing of the previous reaction tests results which allowed to the evaluation of its kinetic parameters. In general, it was noted that the reacting basic sites increase as a primary product while the reacting acid sites evolved as a secondary product. Finally, a reaction mechanism governing the MSB extraction-reaction on the PPCA was proposed considering that the PPCA’s reactive sites acid were grouped into either acid sites either basic sites by Boëhm titration which could regenerated during the reaction. This proposed reaction mechanism was validated by the determination of the extraction-reaction kinetic constant k equals to 8E-4 superior to the kinetic constant determined by reaction results exploitation which is equals to 2.69E-08.

Published in	American Journal of Applied and Industrial Chemistry (Volume 7, Issue 2)
DOI	10.11648/j.ajaic.20230702.12
Page(s)	38-46
Creative Commons	This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.
Copyright	Copyright © The Author(s), 2024. Published by Science Publishing Group

Keywords

Pn-Black Citric Acid Polymer-PPCA, Acid Sites, Basic Sites, MSB (3-Methyl-3-Sulfanylbutan-1-Ol), Kinetics, Mechanism

References

[1]	Rabeharitsara Andry Tahina, Rakotondrina Henri, Randriana Nambinina Richard, Rakotoarijaona Soloniaina, Ratsimba Hanitraniaina Marie, Rakotomamonjy Pierre– Chemical Process Engineering Department (E. S. P. A), Antananarivo University – Madagascar – «MSB - 3-Methyl-3-Sulfanylbutan-1-Ol Extraction Its Esterification with Citric Acid and PPCA Materials Synthesis» - American Journal of Applied And Industrial Chemistry in Vol. 7, Issue Number 2, December 2023. doi: 10.11648/j.ajaic.20230702.11.
[2]	Rabeharitsara Andry Tahina, Raharilaza Paulin Merix, Randriana Richard Nambinina – Chemical Process Engineering Department (E. S. P. A), Antananarivo University – Madagascar – “Esterification Between Citric Acid and Pumpkin Pips’ Organic Molecules – Esters Hydrolysis and Esters Used as Hydrocarbons Additives” - American Journal of Applied Chemistry in Vol. 6, Issue Number 3, June 2018. doi: 10.11648/j.ajac.20180603.12.
[3]	Raharilaza Paulin Merix - "Estérification entre les molécules d’acide citrique et les molécules organiques des graines de courges - hydrolyse et valorisations des esters comme additifs des hydrocarbures" – [Esterification between citric acid molecules and organic molecules of pumpkin seeds - hydrolysis and valuation of esters as hydrocarbon additives] - Mémoire de fin d’étude en vue de l’obtention du diplôme de Licence en Génie Chimique. E. S. P. A. Université d’Antananarivo. Promotion 2017.
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[8]	S. S. Barton, M. J. B. Evans, E. Halliop, j. A. F. MacDonald – “Acidic and basic sites on the surface of porous carbon” – Department of chemistry and chemical engineering, royal military college of Canada, Kingston, Ont., Canada – Carbon Volume 35, Issue 9, 1997, pages 1361-1366.
[9]	Chao Li, Lijun Zhang, Mortaza Gholizadeh, Roel Westerhhof, Zhenhua Cui, Bingqiang Liu, Yonggui Tang Xinghui jin, Zhixiang Xu and Xun Hu – “Impact of acidic/basic of the catalyst on properties of the coke formed in Pyrolysis of Guaiacol: A model compound of the phenolics in bio-oil” – Energy fuels 2020, 34, 9, 11026-11040.
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APA Style

Andry Tahina Rabeharitsara, Henri Rakotondrina, Nambinina Richard Randriana, Hanitraniaina Marie Ratsimba, Rakotomamonjy Pierre, et al. (2023). Study of the PPCA-Materials’ Acid Sites and Basic Sites to Extract the MSB - 3-Methyl-3-Sulfanylbutan-1-Ol. American Journal of Applied and Industrial Chemistry, 7(2), 38-46. https://doi.org/10.11648/j.ajaic.20230702.12

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ACS Style

Andry Tahina Rabeharitsara; Henri Rakotondrina; Nambinina Richard Randriana; Hanitraniaina Marie Ratsimba; Rakotomamonjy Pierre, et al. Study of the PPCA-Materials’ Acid Sites and Basic Sites to Extract the MSB - 3-Methyl-3-Sulfanylbutan-1-Ol. Am. J. Appl. Ind. Chem. 2023, 7(2), 38-46. doi: 10.11648/j.ajaic.20230702.12

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AMA Style

Andry Tahina Rabeharitsara, Henri Rakotondrina, Nambinina Richard Randriana, Hanitraniaina Marie Ratsimba, Rakotomamonjy Pierre, et al. Study of the PPCA-Materials’ Acid Sites and Basic Sites to Extract the MSB - 3-Methyl-3-Sulfanylbutan-1-Ol. Am J Appl Ind Chem. 2023;7(2):38-46. doi: 10.11648/j.ajaic.20230702.12

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@article{10.11648/j.ajaic.20230702.12,
  author = {Andry Tahina Rabeharitsara and Henri Rakotondrina and Nambinina Richard Randriana and Hanitraniaina Marie Ratsimba and Rakotomamonjy Pierre and Soloniaina Rakotoarijaona},
  title = {Study of the PPCA-Materials’ Acid Sites and Basic Sites to Extract the MSB - 3-Methyl-3-Sulfanylbutan-1-Ol},
  journal = {American Journal of Applied and Industrial Chemistry},
  volume = {7},
  number = {2},
  pages = {38-46},
  doi = {10.11648/j.ajaic.20230702.12},
  url = {https://doi.org/10.11648/j.ajaic.20230702.12},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajaic.20230702.12},
  abstract = {The MSB - 3-Methyl-3-Sulfanylbutan-1-Ol is a thiol molecule which could be used as food additive flavor agent and encountered in the white wine, in the coffee perfume, in the passion fruit and in the cat urine where it’s the responsible of its strong odor characteristics. Its extraction from the cat-litter and the synthesis of a new material based on black citric acid polymers (pn), pozzolana and citric acid named PPCA (pn-pozzolana-citric-acid) was studied in the previous manuscript. This manuscript consisted to valorize the PPCA as material to extract and to retain the MSB - 3-Methyl-3-Sulfanylbutan-1-Ol molecule. Thus, reaction tests were done between a MSB - 3-Methyl-3-Sulfanylbutan-1-Ol solution and the PPCA. The first part of this manuscript treated the description of these reaction tests procedure and the various experimental conditions which was at ambient temperature, in the open air and at atmospheric pressure inside a container without a cover. It was also described on this first part the quantifications of the molecules and PPCA’s sites involved in this reaction such as citric acid residues, MSB, acid sites and basic sites which were especially considered as sites governing the reaction-extraction between the PPCA-material and the MSB - 3-Methyl-3-Sulfanylbutan-1-Ol molecules. The second part of this manuscript consisted on the analyzing of the previous reaction tests results which allowed to the evaluation of its kinetic parameters. In general, it was noted that the reacting basic sites increase as a primary product while the reacting acid sites evolved as a secondary product. Finally, a reaction mechanism governing the MSB extraction-reaction on the PPCA was proposed considering that the PPCA’s reactive sites acid were grouped into either acid sites either basic sites by Boëhm titration which could regenerated during the reaction. This proposed reaction mechanism was validated by the determination of the extraction-reaction kinetic constant k equals to 8E-4 superior to the kinetic constant determined by reaction results exploitation which is equals to 2.69E-08.
},
 year = {2023}
}

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TY  - JOUR
T1  - Study of the PPCA-Materials’ Acid Sites and Basic Sites to Extract the MSB - 3-Methyl-3-Sulfanylbutan-1-Ol
AU  - Andry Tahina Rabeharitsara
AU  - Henri Rakotondrina
AU  - Nambinina Richard Randriana
AU  - Hanitraniaina Marie Ratsimba
AU  - Rakotomamonjy Pierre
AU  - Soloniaina Rakotoarijaona
Y1  - 2023/10/28
PY  - 2023
N1  - https://doi.org/10.11648/j.ajaic.20230702.12
DO  - 10.11648/j.ajaic.20230702.12
T2  - American Journal of Applied and Industrial Chemistry
JF  - American Journal of Applied and Industrial Chemistry
JO  - American Journal of Applied and Industrial Chemistry
SP  - 38
EP  - 46
PB  - Science Publishing Group
SN  - 2994-7294
UR  - https://doi.org/10.11648/j.ajaic.20230702.12
AB  - The MSB - 3-Methyl-3-Sulfanylbutan-1-Ol is a thiol molecule which could be used as food additive flavor agent and encountered in the white wine, in the coffee perfume, in the passion fruit and in the cat urine where it’s the responsible of its strong odor characteristics. Its extraction from the cat-litter and the synthesis of a new material based on black citric acid polymers (pn), pozzolana and citric acid named PPCA (pn-pozzolana-citric-acid) was studied in the previous manuscript. This manuscript consisted to valorize the PPCA as material to extract and to retain the MSB - 3-Methyl-3-Sulfanylbutan-1-Ol molecule. Thus, reaction tests were done between a MSB - 3-Methyl-3-Sulfanylbutan-1-Ol solution and the PPCA. The first part of this manuscript treated the description of these reaction tests procedure and the various experimental conditions which was at ambient temperature, in the open air and at atmospheric pressure inside a container without a cover. It was also described on this first part the quantifications of the molecules and PPCA’s sites involved in this reaction such as citric acid residues, MSB, acid sites and basic sites which were especially considered as sites governing the reaction-extraction between the PPCA-material and the MSB - 3-Methyl-3-Sulfanylbutan-1-Ol molecules. The second part of this manuscript consisted on the analyzing of the previous reaction tests results which allowed to the evaluation of its kinetic parameters. In general, it was noted that the reacting basic sites increase as a primary product while the reacting acid sites evolved as a secondary product. Finally, a reaction mechanism governing the MSB extraction-reaction on the PPCA was proposed considering that the PPCA’s reactive sites acid were grouped into either acid sites either basic sites by Boëhm titration which could regenerated during the reaction. This proposed reaction mechanism was validated by the determination of the extraction-reaction kinetic constant k equals to 8E-4 superior to the kinetic constant determined by reaction results exploitation which is equals to 2.69E-08.

VL  - 7
IS  - 2
ER  -

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Author Information

Andry Tahina Rabeharitsara

Chemical Process Engineering Department (E. S. P. A), Antananarivo University, Antananarivo, Madagascar
Henri Rakotondrina

Chemical Process Engineering Department (E. S. P. A), Antananarivo University, Antananarivo, Madagascar
Nambinina Richard Randriana

Chemical Process Engineering Department (E. S. P. A), Antananarivo University, Antananarivo, Madagascar
Hanitraniaina Marie Ratsimba

Chemical Process Engineering Department (E. S. P. A), Antananarivo University, Antananarivo, Madagascar
Rakotomamonjy Pierre

Chemical Process Engineering Department (E. S. P. A), Antananarivo University, Antananarivo, Madagascar
Soloniaina Rakotoarijaona

Chemical Process Engineering Department (E. S. P. A), Antananarivo University, Antananarivo, Madagascar

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APA Style

Andry Tahina Rabeharitsara, Henri Rakotondrina, Nambinina Richard Randriana, Hanitraniaina Marie Ratsimba, Rakotomamonjy Pierre, et al. (2023). Study of the PPCA-Materials’ Acid Sites and Basic Sites to Extract the MSB - 3-Methyl-3-Sulfanylbutan-1-Ol. American Journal of Applied and Industrial Chemistry, 7(2), 38-46. https://doi.org/10.11648/j.ajaic.20230702.12

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ACS Style

Andry Tahina Rabeharitsara; Henri Rakotondrina; Nambinina Richard Randriana; Hanitraniaina Marie Ratsimba; Rakotomamonjy Pierre, et al. Study of the PPCA-Materials’ Acid Sites and Basic Sites to Extract the MSB - 3-Methyl-3-Sulfanylbutan-1-Ol. Am. J. Appl. Ind. Chem. 2023, 7(2), 38-46. doi: 10.11648/j.ajaic.20230702.12

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AMA Style

Andry Tahina Rabeharitsara, Henri Rakotondrina, Nambinina Richard Randriana, Hanitraniaina Marie Ratsimba, Rakotomamonjy Pierre, et al. Study of the PPCA-Materials’ Acid Sites and Basic Sites to Extract the MSB - 3-Methyl-3-Sulfanylbutan-1-Ol. Am J Appl Ind Chem. 2023;7(2):38-46. doi: 10.11648/j.ajaic.20230702.12

Copy | Download

@article{10.11648/j.ajaic.20230702.12,
  author = {Andry Tahina Rabeharitsara and Henri Rakotondrina and Nambinina Richard Randriana and Hanitraniaina Marie Ratsimba and Rakotomamonjy Pierre and Soloniaina Rakotoarijaona},
  title = {Study of the PPCA-Materials’ Acid Sites and Basic Sites to Extract the MSB - 3-Methyl-3-Sulfanylbutan-1-Ol},
  journal = {American Journal of Applied and Industrial Chemistry},
  volume = {7},
  number = {2},
  pages = {38-46},
  doi = {10.11648/j.ajaic.20230702.12},
  url = {https://doi.org/10.11648/j.ajaic.20230702.12},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajaic.20230702.12},
  abstract = {The MSB - 3-Methyl-3-Sulfanylbutan-1-Ol is a thiol molecule which could be used as food additive flavor agent and encountered in the white wine, in the coffee perfume, in the passion fruit and in the cat urine where it’s the responsible of its strong odor characteristics. Its extraction from the cat-litter and the synthesis of a new material based on black citric acid polymers (pn), pozzolana and citric acid named PPCA (pn-pozzolana-citric-acid) was studied in the previous manuscript. This manuscript consisted to valorize the PPCA as material to extract and to retain the MSB - 3-Methyl-3-Sulfanylbutan-1-Ol molecule. Thus, reaction tests were done between a MSB - 3-Methyl-3-Sulfanylbutan-1-Ol solution and the PPCA. The first part of this manuscript treated the description of these reaction tests procedure and the various experimental conditions which was at ambient temperature, in the open air and at atmospheric pressure inside a container without a cover. It was also described on this first part the quantifications of the molecules and PPCA’s sites involved in this reaction such as citric acid residues, MSB, acid sites and basic sites which were especially considered as sites governing the reaction-extraction between the PPCA-material and the MSB - 3-Methyl-3-Sulfanylbutan-1-Ol molecules. The second part of this manuscript consisted on the analyzing of the previous reaction tests results which allowed to the evaluation of its kinetic parameters. In general, it was noted that the reacting basic sites increase as a primary product while the reacting acid sites evolved as a secondary product. Finally, a reaction mechanism governing the MSB extraction-reaction on the PPCA was proposed considering that the PPCA’s reactive sites acid were grouped into either acid sites either basic sites by Boëhm titration which could regenerated during the reaction. This proposed reaction mechanism was validated by the determination of the extraction-reaction kinetic constant k equals to 8E-4 superior to the kinetic constant determined by reaction results exploitation which is equals to 2.69E-08.
},
 year = {2023}
}

Copy | Download

TY  - JOUR
T1  - Study of the PPCA-Materials’ Acid Sites and Basic Sites to Extract the MSB - 3-Methyl-3-Sulfanylbutan-1-Ol
AU  - Andry Tahina Rabeharitsara
AU  - Henri Rakotondrina
AU  - Nambinina Richard Randriana
AU  - Hanitraniaina Marie Ratsimba
AU  - Rakotomamonjy Pierre
AU  - Soloniaina Rakotoarijaona
Y1  - 2023/10/28
PY  - 2023
N1  - https://doi.org/10.11648/j.ajaic.20230702.12
DO  - 10.11648/j.ajaic.20230702.12
T2  - American Journal of Applied and Industrial Chemistry
JF  - American Journal of Applied and Industrial Chemistry
JO  - American Journal of Applied and Industrial Chemistry
SP  - 38
EP  - 46
PB  - Science Publishing Group
SN  - 2994-7294
UR  - https://doi.org/10.11648/j.ajaic.20230702.12
AB  - The MSB - 3-Methyl-3-Sulfanylbutan-1-Ol is a thiol molecule which could be used as food additive flavor agent and encountered in the white wine, in the coffee perfume, in the passion fruit and in the cat urine where it’s the responsible of its strong odor characteristics. Its extraction from the cat-litter and the synthesis of a new material based on black citric acid polymers (pn), pozzolana and citric acid named PPCA (pn-pozzolana-citric-acid) was studied in the previous manuscript. This manuscript consisted to valorize the PPCA as material to extract and to retain the MSB - 3-Methyl-3-Sulfanylbutan-1-Ol molecule. Thus, reaction tests were done between a MSB - 3-Methyl-3-Sulfanylbutan-1-Ol solution and the PPCA. The first part of this manuscript treated the description of these reaction tests procedure and the various experimental conditions which was at ambient temperature, in the open air and at atmospheric pressure inside a container without a cover. It was also described on this first part the quantifications of the molecules and PPCA’s sites involved in this reaction such as citric acid residues, MSB, acid sites and basic sites which were especially considered as sites governing the reaction-extraction between the PPCA-material and the MSB - 3-Methyl-3-Sulfanylbutan-1-Ol molecules. The second part of this manuscript consisted on the analyzing of the previous reaction tests results which allowed to the evaluation of its kinetic parameters. In general, it was noted that the reacting basic sites increase as a primary product while the reacting acid sites evolved as a secondary product. Finally, a reaction mechanism governing the MSB extraction-reaction on the PPCA was proposed considering that the PPCA’s reactive sites acid were grouped into either acid sites either basic sites by Boëhm titration which could regenerated during the reaction. This proposed reaction mechanism was validated by the determination of the extraction-reaction kinetic constant k equals to 8E-4 superior to the kinetic constant determined by reaction results exploitation which is equals to 2.69E-08.

VL  - 7
IS  - 2
ER  -

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