Kinetic Study of the Esterification Between Citric Acid Molecules and <i>Dombeya Mollis’</i> Leaf Cellulose Titrated by Spectrophotometer UV-Visible Procedure

Andry Tahina Rabeharitsara; Antsafanatitra Mandimbinirina Rabenarivo; Soloniaina Rakotoarijaona; Hanitraniaina Marie Ratsimba; Baholy Robijaona; Rakotomamonjy Pierre

doi:doi:10.11648/j.ajaic.20230702.13

Research/Technical Note |

Kinetic Study of the Esterification Between Citric Acid Molecules and Dombeya Mollis’ Leaf Cellulose Titrated by Spectrophotometer UV-Visible Procedure

Andry Tahina Rabeharitsara, Antsafanatitra Mandimbinirina Rabenarivo, Soloniaina Rakotoarijaona, Hanitraniaina Marie Ratsimba, Baholy Robijaona, Rakotomamonjy Pierre

Published in American Journal of Applied and Industrial Chemistry (Volume 7, Issue 2)

Received: 23 September 2023 Accepted: 12 October 2023 Published: 28 October 2023

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Abstract

Cellulose is the most abundant natural organic polymer on earth and could be valorized and used in different applications. It’s mainly used to produce paper but also to produce biodegradable cellophane and biofuels. Thus, the extraction of cellulose from green plants, where it’s the most important structural component, was interesting. This manuscript treated the extraction of cellulose from the Dombeya Mollis leaf by esterification-reaction with citric acid molecules. This method is usually used to extract, to identify, to characterize and to quantify the active molecules of alive organisms but in this case the advantage to use the esterification-reaction with citric acid molecules is that the synthesized solution contains straightaway reticulated cellulose. Indeed, the refractive index value of the Dombeya Molli leaf’s cellulose-citric acid esterified solution was 1.336 in the vicinity of the refractive index values of citric acid-solid, citric acid in solution and nanocellulose which were respectively 1.493, 1.345 and 1.470. In addition, A cellulose quantification procedure using spectrophotometer UV-visible was performed and established in this manuscript and permitted to quantify the quantities of cellulose extracted from the plants to the solution by esterification-reaction with citric acid molecules. In consequence, a kinetic study was done under this esterification-reaction between citric acid molecules and Dombeya Mollis leaf’s cellulose and permitted to evaluate the speed constant with the partial orders of citric acid, cellulose and proton-H+ which play the role of catalyst-inductive during this esterification-reaction. At the end, a reactional mechanism which could govern this esterification-reaction between the Dombeya Mollis leaf’s cellulose and the citric acid molecules was proposed.

Published in	American Journal of Applied and Industrial Chemistry (Volume 7, Issue 2)
DOI	10.11648/j.ajaic.20230702.13
Page(s)	47-53
Creative Commons	This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.
Copyright	Copyright © The Author(s), 2024. Published by Science Publishing Group

Keywords

Citric Acid, Cellulose, Esterification, Dombeya Mollis, Leaf, Spectrophotometer UV-Visible, Kinetic, Reactional Mechanism

References

[1]	Rabeharitsara Andry Tahina, Raharilaza Paulin Merix, Randriana Richard Nambinina – Chemical Process Engineering Department (E. S. P. A), Antananarivo University – Madagascar – “Esterification Between Citric Acid and Pumpkin Pips’ Organic Molecules – Esters Hydrolysis and Esters Used as Hydrocarbons Additives” - American Journal of Applied Chemistry in Vol. 6, Issue Number 3, June 2018. doi: 10.11648/j.ajac.20180603.12.
[2]	Raharilaza Paulin Merix - "Estérification entre les molécules d’acide citrique et les molécules organiques des graines de courges - hydrolyse et valorisations des esters comme additifs des hydrocarbures" – [Esterification between citric acid molecules and organic molecules of pumpkin seeds - hydrolysis and valuation of esters as hydrocarbon additives] - Mémoire de fin d’étude en vue de l’obtention du diplôme de Licence en Génie Chimique. E. S. P. A. Université d’Antananarivo. Promotion 2017.
[3]	Rabeharitsara Andry Tahina, Rakotonanahary Lovasoa Carolia Sabrinah, Ratsimba Marie Hanaitriniaina, Randriana Nambinina Richard, Robijaona Baholy, Rakotomamonjy Pierre – Chemical Process Engineering Department (E. S. P. A), Antananarivo University – Madagascar – “Determining Of The Constituent Molecules Of The Strychnos Spinosa Pips By Extraction With Citric Acid Esterification Procedure” – American Journal of Applied Chemistry – Pages 21-32, Feb. 24, 2023 doi: 10.11648/j.ajac.20231101.13.
[4]	RAKOTONANAHARY Lovasoa Carolia Sabrinah – “Etude Qualitative Et Quantitativedes Acides Gras, Des Steroides, Des Terpenoides, Des Flavonoides Et Des Alcaloides Dans Les Graines De Mokotro « Strychnos Spinosa » Par La Methode D’esterification Avec L’acide Citrique” [Qualitative and quantitative study of fatty acids, steroids, terpenoïds, flavonoids and alcaloïds in the mokotro-Strychnos spinosa pips”. Mémoire de fin d’étude en vue de l’obtention du diplôme de Licence en Génie Chimique. E. S. P. A. Université d’Antananarivo. Promotion 2021.
[5]	Rabeharitsara Andry Tahina, Ravomialisoa Ernestine, Randriana Nambinina Richard – “Synthesis of Capsicum chinense citric acid esters-Its methanol trans-esterification investigations with hplc analysis and Its valorization as gels-crystals Ca-salts” – American Journal of applied chemistry – volume 9, issue 6, December 2021, pages: 221-237 Received: Nov. 28, 2021; accepted: Dec. 16, 2021; published: Dec. 31, 2021.
[6]	Rabeharitsara Andry Tahina – “Trans-Esterification With Methanol Of Capsicum Chinense’s Citric Acid Ester Solution Its Calcium Gel And Crystal Salts Synthesis” 11th Edition Of International Conference On Catalysis, Chemical Engineering And Technology” Online conference held on may 16-17, 2022 – Magnus group conferences and organizing committee.
[7]	Pierre-Antoine FAUGERAS – “Valorisation des fibres lignocellulosiques de la pâte à papier” - L'UNIVERSITE DU QUEBEC A TROIS-RIVIERES des Substances Naturelles et L'UNIVERSITE DE LIMOGES Faculté des Sciences et Techniques Laboratoire de Chimie – Thèse de doctorat - 11 décembre 2012.
[8]	B. Pavlov, A. Terentiev – “Chimie organique” 3èmeEdition Editions MIR-Moscou.
[9]	Ran Zhao, Masatomo So, Hendrik Maat, Nicholas J. Ray, Fumio Arisaka, Yuji Goto, John A., Carver&Damien Hall – “Measurement of amyloid formation by turbidity assay – seeing through the cloud” – Biophysical Review (2016) 8 445-471.
[10]	Madalina M., Xiaodan Tian, Marilena M. Thomas E. Exner – “Interaction structure of the complex between neuroprotective factor humain and Alzheimer’s β-amyloid peptide revealed by affinity mas spectrometry and molecular modeling” – Journal of peptide science June 2012 18 (6) 373-82.
[11]	Handbook of chemistry and physics, 49th Edition 1961.
[12]	Refractive index reference – S. N. Kasarova et al, Optical Materials Journal.
[13]	Rabeharitsara Andry Tahina, Raherimandimby Jaochim, Randriana Nambinina Richard– Chemical Process Engineering Department (E. S. P. A), Antananarivo University, Antananarivo, Madagascar -“Trans-Esterification Between Citric Acid and Peanut Oil at Low pH and Ambient Temperature Catalyzed by Citric Acid and Sulfuric Acid Protonic Acid-H+” - American Journal of Applied Chemistry Volume 8, Issue 4, August 2020, Pages: 100-116 Received: Jul. 12, 2020; Accepted: Jul. 25, 2020; Published: Aug. 13, 2020.
[14]	Raherimandimby Jaochim - "Synthese De Biodiesel Par Transesterification De L’huile D’arachide Avec La Fonction Alcool De L’acide Citrique, Catalysée Par Ses Sites Acides Protoniques H+ Et Ceux Des H+/H2SO4 Eventuellement Supportés Sur Du Bois De Pin Seché BSH+" – [Synthesis of Biodiesel by Transesterification of Peanut Oil with the Alcohol Function of Citric Acid, Catalyzed by Its H+ Proton Acid Sites and Those of H+/H2SO4 Possibly Supported on BSH+ Seasoned Pinewood] - Mémoire de fin d’étude en vue de l’obtention du diplôme de Licence en Génie Chimique. E. S. P. A. Université d’Antananarivo. Promotion 2020.
[15]	Rabeharitsara Andry Tahina, Rovatahianjanahary Behevitra, Randriana Nambinina Richard – Chemical Process Engineering Department (E. S. P. A), Antananarivo University, Antananarivo, Madagascar - «Pine Wood Powder Treatment To BXH+ Homogeneous Catalyst (H+/H2SO4) Supported On Its Aromatics And PNA – Application In Black Citric Acid Polymer Synthesis» - American Journal of Polymer Science and Technology. Vol. 4, No. 1, 2018, pp. 1-27. doi: 10.11648/j.ajpst.20180401.11.
[16]	Behevitra Rovatahianjanahary - «Synthèse de catalyseurs homogènes BXH+ supportés sur les alcènes des aromatiques et des polynucléaires aromatiques oxygénés composant le bois du pin par traitement à l’acide sulfurique – Application dans la synthèse des polymères noires d’acide citrique» - [Synthesis of homogeneous BXH+ catalysts supported on the alkenes of the aromatics and oxygenated aromatic polynuclei composing pine wood by treatment with sulfuric acid - Application in the synthesis of black polymers of citric acid]. Mémoire de fin d’étude en vue de l’obtention du diplôme de Licence en génie des procédés chimiques et industriels. Ecole Supérieure Polytechnique Antananarivo (E. S. P. A) – Université d’Antananarivo. Promotion 2018 – Soutenue le 26 Juillet 2018.
[17]	Rabeharitsara Andry Tahina, Sedraniaina Domoina Marie Espérance, Randriamanantena Idealy Elite, Mampitefa Raïssa Faneva, Randriana Nambinina Richard - “Esterification Between Citric Acid and Callistemon citrinus, Rice-Husk and Garcinia dulcis In Glass-Flask Catalysed By Citric Acid’s Protonic Acid-H+ - Monomers and Polymers Formation Mechanism”, Chemical Process Engineering Department (E. S. P. A), Antananarivo University, Antananarivo, Madagascar, American Journal of Applied Chemistry, volume 8, Issue 2, April 10 2020 published 28, 2020.

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Andry Tahina Rabeharitsara, Antsafanatitra Mandimbinirina Rabenarivo, Soloniaina Rakotoarijaona, Hanitraniaina Marie Ratsimba, Baholy Robijaona, et al. (2023). Kinetic Study of the Esterification Between Citric Acid Molecules and Dombeya Mollis’ Leaf Cellulose Titrated by Spectrophotometer UV-Visible Procedure. American Journal of Applied and Industrial Chemistry, 7(2), 47-53. https://doi.org/10.11648/j.ajaic.20230702.13

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ACS Style

Andry Tahina Rabeharitsara; Antsafanatitra Mandimbinirina Rabenarivo; Soloniaina Rakotoarijaona; Hanitraniaina Marie Ratsimba; Baholy Robijaona, et al. Kinetic Study of the Esterification Between Citric Acid Molecules and Dombeya Mollis’ Leaf Cellulose Titrated by Spectrophotometer UV-Visible Procedure. Am. J. Appl. Ind. Chem. 2023, 7(2), 47-53. doi: 10.11648/j.ajaic.20230702.13

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AMA Style

Andry Tahina Rabeharitsara, Antsafanatitra Mandimbinirina Rabenarivo, Soloniaina Rakotoarijaona, Hanitraniaina Marie Ratsimba, Baholy Robijaona, et al. Kinetic Study of the Esterification Between Citric Acid Molecules and Dombeya Mollis’ Leaf Cellulose Titrated by Spectrophotometer UV-Visible Procedure. Am J Appl Ind Chem. 2023;7(2):47-53. doi: 10.11648/j.ajaic.20230702.13

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@article{10.11648/j.ajaic.20230702.13,
  author = {Andry Tahina Rabeharitsara and Antsafanatitra Mandimbinirina Rabenarivo and Soloniaina Rakotoarijaona and Hanitraniaina Marie Ratsimba and Baholy Robijaona and Rakotomamonjy Pierre},
  title = {Kinetic Study of the Esterification Between Citric Acid Molecules and Dombeya Mollis’ Leaf Cellulose Titrated by Spectrophotometer UV-Visible Procedure},
  journal = {American Journal of Applied and Industrial Chemistry},
  volume = {7},
  number = {2},
  pages = {47-53},
  doi = {10.11648/j.ajaic.20230702.13},
  url = {https://doi.org/10.11648/j.ajaic.20230702.13},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajaic.20230702.13},
  abstract = {Cellulose is the most abundant natural organic polymer on earth and could be valorized and used in different applications. It’s mainly used to produce paper but also to produce biodegradable cellophane and biofuels. Thus, the extraction of cellulose from green plants, where it’s the most important structural component, was interesting. This manuscript treated the extraction of cellulose from the Dombeya Mollis leaf by esterification-reaction with citric acid molecules. This method is usually used to extract, to identify, to characterize and to quantify the active molecules of alive organisms but in this case the advantage to use the esterification-reaction with citric acid molecules is that the synthesized solution contains straightaway reticulated cellulose. Indeed, the refractive index value of the Dombeya Molli leaf’s cellulose-citric acid esterified solution was 1.336 in the vicinity of the refractive index values of citric acid-solid, citric acid in solution and nanocellulose which were respectively 1.493, 1.345 and 1.470. In addition, A cellulose quantification procedure using spectrophotometer UV-visible was performed and established in this manuscript and permitted to quantify the quantities of cellulose extracted from the plants to the solution by esterification-reaction with citric acid molecules. In consequence, a kinetic study was done under this esterification-reaction between citric acid molecules and Dombeya Mollis leaf’s cellulose and permitted to evaluate the speed constant with the partial orders of citric acid, cellulose and proton-H+ which play the role of catalyst-inductive during this esterification-reaction. At the end, a reactional mechanism which could govern this esterification-reaction between the Dombeya Mollis leaf’s cellulose and the citric acid molecules was proposed.
},
 year = {2023}
}

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TY  - JOUR
T1  - Kinetic Study of the Esterification Between Citric Acid Molecules and Dombeya Mollis’ Leaf Cellulose Titrated by Spectrophotometer UV-Visible Procedure
AU  - Andry Tahina Rabeharitsara
AU  - Antsafanatitra Mandimbinirina Rabenarivo
AU  - Soloniaina Rakotoarijaona
AU  - Hanitraniaina Marie Ratsimba
AU  - Baholy Robijaona
AU  - Rakotomamonjy Pierre
Y1  - 2023/10/28
PY  - 2023
N1  - https://doi.org/10.11648/j.ajaic.20230702.13
DO  - 10.11648/j.ajaic.20230702.13
T2  - American Journal of Applied and Industrial Chemistry
JF  - American Journal of Applied and Industrial Chemistry
JO  - American Journal of Applied and Industrial Chemistry
SP  - 47
EP  - 53
PB  - Science Publishing Group
SN  - 2994-7294
UR  - https://doi.org/10.11648/j.ajaic.20230702.13
AB  - Cellulose is the most abundant natural organic polymer on earth and could be valorized and used in different applications. It’s mainly used to produce paper but also to produce biodegradable cellophane and biofuels. Thus, the extraction of cellulose from green plants, where it’s the most important structural component, was interesting. This manuscript treated the extraction of cellulose from the Dombeya Mollis leaf by esterification-reaction with citric acid molecules. This method is usually used to extract, to identify, to characterize and to quantify the active molecules of alive organisms but in this case the advantage to use the esterification-reaction with citric acid molecules is that the synthesized solution contains straightaway reticulated cellulose. Indeed, the refractive index value of the Dombeya Molli leaf’s cellulose-citric acid esterified solution was 1.336 in the vicinity of the refractive index values of citric acid-solid, citric acid in solution and nanocellulose which were respectively 1.493, 1.345 and 1.470. In addition, A cellulose quantification procedure using spectrophotometer UV-visible was performed and established in this manuscript and permitted to quantify the quantities of cellulose extracted from the plants to the solution by esterification-reaction with citric acid molecules. In consequence, a kinetic study was done under this esterification-reaction between citric acid molecules and Dombeya Mollis leaf’s cellulose and permitted to evaluate the speed constant with the partial orders of citric acid, cellulose and proton-H+ which play the role of catalyst-inductive during this esterification-reaction. At the end, a reactional mechanism which could govern this esterification-reaction between the Dombeya Mollis leaf’s cellulose and the citric acid molecules was proposed.

VL  - 7
IS  - 2
ER  -

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Author Information

Andry Tahina Rabeharitsara

Chemical Process Engineering Department (E. S. P. A), Antananarivo University, Antananarivo, Madagascar
Antsafanatitra Mandimbinirina Rabenarivo

Chemical Process Engineering Department (E. S. P. A), Antananarivo University, Antananarivo, Madagascar
Soloniaina Rakotoarijaona

Chemical Process Engineering Department (E. S. P. A), Antananarivo University, Antananarivo, Madagascar
Hanitraniaina Marie Ratsimba

Chemical Process Engineering Department (E. S. P. A), Antananarivo University, Antananarivo, Madagascar
Baholy Robijaona

Chemical Process Engineering Department (E. S. P. A), Antananarivo University, Antananarivo, Madagascar
Rakotomamonjy Pierre

Chemical Process Engineering Department (E. S. P. A), Antananarivo University, Antananarivo, Madagascar

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APA Style

Andry Tahina Rabeharitsara, Antsafanatitra Mandimbinirina Rabenarivo, Soloniaina Rakotoarijaona, Hanitraniaina Marie Ratsimba, Baholy Robijaona, et al. (2023). Kinetic Study of the Esterification Between Citric Acid Molecules and Dombeya Mollis’ Leaf Cellulose Titrated by Spectrophotometer UV-Visible Procedure. American Journal of Applied and Industrial Chemistry, 7(2), 47-53. https://doi.org/10.11648/j.ajaic.20230702.13

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ACS Style

Andry Tahina Rabeharitsara; Antsafanatitra Mandimbinirina Rabenarivo; Soloniaina Rakotoarijaona; Hanitraniaina Marie Ratsimba; Baholy Robijaona, et al. Kinetic Study of the Esterification Between Citric Acid Molecules and Dombeya Mollis’ Leaf Cellulose Titrated by Spectrophotometer UV-Visible Procedure. Am. J. Appl. Ind. Chem. 2023, 7(2), 47-53. doi: 10.11648/j.ajaic.20230702.13

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AMA Style

Andry Tahina Rabeharitsara, Antsafanatitra Mandimbinirina Rabenarivo, Soloniaina Rakotoarijaona, Hanitraniaina Marie Ratsimba, Baholy Robijaona, et al. Kinetic Study of the Esterification Between Citric Acid Molecules and Dombeya Mollis’ Leaf Cellulose Titrated by Spectrophotometer UV-Visible Procedure. Am J Appl Ind Chem. 2023;7(2):47-53. doi: 10.11648/j.ajaic.20230702.13

Copy | Download

@article{10.11648/j.ajaic.20230702.13,
  author = {Andry Tahina Rabeharitsara and Antsafanatitra Mandimbinirina Rabenarivo and Soloniaina Rakotoarijaona and Hanitraniaina Marie Ratsimba and Baholy Robijaona and Rakotomamonjy Pierre},
  title = {Kinetic Study of the Esterification Between Citric Acid Molecules and Dombeya Mollis’ Leaf Cellulose Titrated by Spectrophotometer UV-Visible Procedure},
  journal = {American Journal of Applied and Industrial Chemistry},
  volume = {7},
  number = {2},
  pages = {47-53},
  doi = {10.11648/j.ajaic.20230702.13},
  url = {https://doi.org/10.11648/j.ajaic.20230702.13},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajaic.20230702.13},
  abstract = {Cellulose is the most abundant natural organic polymer on earth and could be valorized and used in different applications. It’s mainly used to produce paper but also to produce biodegradable cellophane and biofuels. Thus, the extraction of cellulose from green plants, where it’s the most important structural component, was interesting. This manuscript treated the extraction of cellulose from the Dombeya Mollis leaf by esterification-reaction with citric acid molecules. This method is usually used to extract, to identify, to characterize and to quantify the active molecules of alive organisms but in this case the advantage to use the esterification-reaction with citric acid molecules is that the synthesized solution contains straightaway reticulated cellulose. Indeed, the refractive index value of the Dombeya Molli leaf’s cellulose-citric acid esterified solution was 1.336 in the vicinity of the refractive index values of citric acid-solid, citric acid in solution and nanocellulose which were respectively 1.493, 1.345 and 1.470. In addition, A cellulose quantification procedure using spectrophotometer UV-visible was performed and established in this manuscript and permitted to quantify the quantities of cellulose extracted from the plants to the solution by esterification-reaction with citric acid molecules. In consequence, a kinetic study was done under this esterification-reaction between citric acid molecules and Dombeya Mollis leaf’s cellulose and permitted to evaluate the speed constant with the partial orders of citric acid, cellulose and proton-H+ which play the role of catalyst-inductive during this esterification-reaction. At the end, a reactional mechanism which could govern this esterification-reaction between the Dombeya Mollis leaf’s cellulose and the citric acid molecules was proposed.
},
 year = {2023}
}

Copy | Download

TY  - JOUR
T1  - Kinetic Study of the Esterification Between Citric Acid Molecules and Dombeya Mollis’ Leaf Cellulose Titrated by Spectrophotometer UV-Visible Procedure
AU  - Andry Tahina Rabeharitsara
AU  - Antsafanatitra Mandimbinirina Rabenarivo
AU  - Soloniaina Rakotoarijaona
AU  - Hanitraniaina Marie Ratsimba
AU  - Baholy Robijaona
AU  - Rakotomamonjy Pierre
Y1  - 2023/10/28
PY  - 2023
N1  - https://doi.org/10.11648/j.ajaic.20230702.13
DO  - 10.11648/j.ajaic.20230702.13
T2  - American Journal of Applied and Industrial Chemistry
JF  - American Journal of Applied and Industrial Chemistry
JO  - American Journal of Applied and Industrial Chemistry
SP  - 47
EP  - 53
PB  - Science Publishing Group
SN  - 2994-7294
UR  - https://doi.org/10.11648/j.ajaic.20230702.13
AB  - Cellulose is the most abundant natural organic polymer on earth and could be valorized and used in different applications. It’s mainly used to produce paper but also to produce biodegradable cellophane and biofuels. Thus, the extraction of cellulose from green plants, where it’s the most important structural component, was interesting. This manuscript treated the extraction of cellulose from the Dombeya Mollis leaf by esterification-reaction with citric acid molecules. This method is usually used to extract, to identify, to characterize and to quantify the active molecules of alive organisms but in this case the advantage to use the esterification-reaction with citric acid molecules is that the synthesized solution contains straightaway reticulated cellulose. Indeed, the refractive index value of the Dombeya Molli leaf’s cellulose-citric acid esterified solution was 1.336 in the vicinity of the refractive index values of citric acid-solid, citric acid in solution and nanocellulose which were respectively 1.493, 1.345 and 1.470. In addition, A cellulose quantification procedure using spectrophotometer UV-visible was performed and established in this manuscript and permitted to quantify the quantities of cellulose extracted from the plants to the solution by esterification-reaction with citric acid molecules. In consequence, a kinetic study was done under this esterification-reaction between citric acid molecules and Dombeya Mollis leaf’s cellulose and permitted to evaluate the speed constant with the partial orders of citric acid, cellulose and proton-H+ which play the role of catalyst-inductive during this esterification-reaction. At the end, a reactional mechanism which could govern this esterification-reaction between the Dombeya Mollis leaf’s cellulose and the citric acid molecules was proposed.

VL  - 7
IS  - 2
ER  -

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