Study on Mechanism and Application of High Concentrations of Nitrite-Induced Specific Color Fading

Jiaxin Zuo; Jing Guo

doi:doi:10.11648/j.sjac.20221002.13

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Study on Mechanism and Application of High Concentrations of Nitrite-Induced Specific Color Fading

Jiaxin Zuo, Jing Guo

Published in Science Journal of Analytical Chemistry (Volume 10, Issue 2)

Received: 16 May 2022 Accepted: 6 June 2022 Published: 14 June 2022

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Abstract

Nitrite and edible salt are easy to confuse for their similar appearance and taste, thus possibly causing nitrite poisoning. Therefore, it is particularly crucial to figure out how to screen high concentrations of nitrite, how to discriminate NaNO₂ and NaCl, and how to accurately quantify high concentrations of nitrite. In this study, the phenomenon of high concentrations of nitrite fading to orange-yellow color in colorimetric solution of naphthalene ethylenediamine hydrochloride was studied and accurately quantified by dilution colorimetry. It is to prevent false negative detection while NaCl presented no such phenomenon. Through spectrophotometry, high-performance liquid chromatography, and liquid mass spectrometry, we discovered that the principle of high concentrations of nitrite fading to orange-yellow after colorimetry was that high concentrations of nitrite nitrosated azo compounds and naphthalene ethylenediamine hydrochloride in hydrochloric acid medium. This principle can make the solution appear orange-yellow while had almost no matrix interference and this demonstrates no difference in food and water. We thus argue that this principle can be used for the screening of high concentrations of nitrite, and discriminating NaNO₂ and NaCl to prevent poisoning events caused by misuses. In this sense, we believe the principle in question has a high applying value and is worth promoting. It can be made into a commercial hydrochloric acid acidified naphthylethylenediamine hydrochloride solution for further commercialized applications.

Published in	Science Journal of Analytical Chemistry (Volume 10, Issue 2)
DOI	10.11648/j.sjac.20221002.13
Page(s)	29-39
Creative Commons	This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.
Copyright	Copyright © The Author(s), 2022. Published by Science Publishing Group

Keywords

Nitrite, Discoloration, Study, Application

References

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Jiaxin Zuo, Jing Guo. (2022). Study on Mechanism and Application of High Concentrations of Nitrite-Induced Specific Color Fading. Science Journal of Analytical Chemistry, 10(2), 29-39. https://doi.org/10.11648/j.sjac.20221002.13

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ACS Style

Jiaxin Zuo; Jing Guo. Study on Mechanism and Application of High Concentrations of Nitrite-Induced Specific Color Fading. Sci. J. Anal. Chem. 2022, 10(2), 29-39. doi: 10.11648/j.sjac.20221002.13

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AMA Style

Jiaxin Zuo, Jing Guo. Study on Mechanism and Application of High Concentrations of Nitrite-Induced Specific Color Fading. Sci J Anal Chem. 2022;10(2):29-39. doi: 10.11648/j.sjac.20221002.13

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@article{10.11648/j.sjac.20221002.13,
  author = {Jiaxin Zuo and Jing Guo},
  title = {Study on Mechanism and Application of High Concentrations of Nitrite-Induced Specific Color Fading},
  journal = {Science Journal of Analytical Chemistry},
  volume = {10},
  number = {2},
  pages = {29-39},
  doi = {10.11648/j.sjac.20221002.13},
  url = {https://doi.org/10.11648/j.sjac.20221002.13},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.sjac.20221002.13},
  abstract = {Nitrite and edible salt are easy to confuse for their similar appearance and taste, thus possibly causing nitrite poisoning. Therefore, it is particularly crucial to figure out how to screen high concentrations of nitrite, how to discriminate NaNO2 and NaCl, and how to accurately quantify high concentrations of nitrite. In this study, the phenomenon of high concentrations of nitrite fading to orange-yellow color in colorimetric solution of naphthalene ethylenediamine hydrochloride was studied and accurately quantified by dilution colorimetry. It is to prevent false negative detection while NaCl presented no such phenomenon. Through spectrophotometry, high-performance liquid chromatography, and liquid mass spectrometry, we discovered that the principle of high concentrations of nitrite fading to orange-yellow after colorimetry was that high concentrations of nitrite nitrosated azo compounds and naphthalene ethylenediamine hydrochloride in hydrochloric acid medium. This principle can make the solution appear orange-yellow while had almost no matrix interference and this demonstrates no difference in food and water. We thus argue that this principle can be used for the screening of high concentrations of nitrite, and discriminating NaNO2 and NaCl to prevent poisoning events caused by misuses. In this sense, we believe the principle in question has a high applying value and is worth promoting. It can be made into a commercial hydrochloric acid acidified naphthylethylenediamine hydrochloride solution for further commercialized applications.},
 year = {2022}
}

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TY  - JOUR
T1  - Study on Mechanism and Application of High Concentrations of Nitrite-Induced Specific Color Fading
AU  - Jiaxin Zuo
AU  - Jing Guo
Y1  - 2022/06/14
PY  - 2022
N1  - https://doi.org/10.11648/j.sjac.20221002.13
DO  - 10.11648/j.sjac.20221002.13
T2  - Science Journal of Analytical Chemistry
JF  - Science Journal of Analytical Chemistry
JO  - Science Journal of Analytical Chemistry
SP  - 29
EP  - 39
PB  - Science Publishing Group
SN  - 2376-8053
UR  - https://doi.org/10.11648/j.sjac.20221002.13
AB  - Nitrite and edible salt are easy to confuse for their similar appearance and taste, thus possibly causing nitrite poisoning. Therefore, it is particularly crucial to figure out how to screen high concentrations of nitrite, how to discriminate NaNO2 and NaCl, and how to accurately quantify high concentrations of nitrite. In this study, the phenomenon of high concentrations of nitrite fading to orange-yellow color in colorimetric solution of naphthalene ethylenediamine hydrochloride was studied and accurately quantified by dilution colorimetry. It is to prevent false negative detection while NaCl presented no such phenomenon. Through spectrophotometry, high-performance liquid chromatography, and liquid mass spectrometry, we discovered that the principle of high concentrations of nitrite fading to orange-yellow after colorimetry was that high concentrations of nitrite nitrosated azo compounds and naphthalene ethylenediamine hydrochloride in hydrochloric acid medium. This principle can make the solution appear orange-yellow while had almost no matrix interference and this demonstrates no difference in food and water. We thus argue that this principle can be used for the screening of high concentrations of nitrite, and discriminating NaNO2 and NaCl to prevent poisoning events caused by misuses. In this sense, we believe the principle in question has a high applying value and is worth promoting. It can be made into a commercial hydrochloric acid acidified naphthylethylenediamine hydrochloride solution for further commercialized applications.
VL  - 10
IS  - 2
ER  -

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Author Information

Jiaxin Zuo

Hunan Center for Disease Control and Prevention, Changsha, China
Jing Guo

Hunan Provincial Finance and Trade Hospital, Changsha, China

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APA Style

Jiaxin Zuo, Jing Guo. (2022). Study on Mechanism and Application of High Concentrations of Nitrite-Induced Specific Color Fading. Science Journal of Analytical Chemistry, 10(2), 29-39. https://doi.org/10.11648/j.sjac.20221002.13

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ACS Style

Jiaxin Zuo; Jing Guo. Study on Mechanism and Application of High Concentrations of Nitrite-Induced Specific Color Fading. Sci. J. Anal. Chem. 2022, 10(2), 29-39. doi: 10.11648/j.sjac.20221002.13

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AMA Style

Jiaxin Zuo, Jing Guo. Study on Mechanism and Application of High Concentrations of Nitrite-Induced Specific Color Fading. Sci J Anal Chem. 2022;10(2):29-39. doi: 10.11648/j.sjac.20221002.13

Copy | Download

@article{10.11648/j.sjac.20221002.13,
  author = {Jiaxin Zuo and Jing Guo},
  title = {Study on Mechanism and Application of High Concentrations of Nitrite-Induced Specific Color Fading},
  journal = {Science Journal of Analytical Chemistry},
  volume = {10},
  number = {2},
  pages = {29-39},
  doi = {10.11648/j.sjac.20221002.13},
  url = {https://doi.org/10.11648/j.sjac.20221002.13},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.sjac.20221002.13},
  abstract = {Nitrite and edible salt are easy to confuse for their similar appearance and taste, thus possibly causing nitrite poisoning. Therefore, it is particularly crucial to figure out how to screen high concentrations of nitrite, how to discriminate NaNO2 and NaCl, and how to accurately quantify high concentrations of nitrite. In this study, the phenomenon of high concentrations of nitrite fading to orange-yellow color in colorimetric solution of naphthalene ethylenediamine hydrochloride was studied and accurately quantified by dilution colorimetry. It is to prevent false negative detection while NaCl presented no such phenomenon. Through spectrophotometry, high-performance liquid chromatography, and liquid mass spectrometry, we discovered that the principle of high concentrations of nitrite fading to orange-yellow after colorimetry was that high concentrations of nitrite nitrosated azo compounds and naphthalene ethylenediamine hydrochloride in hydrochloric acid medium. This principle can make the solution appear orange-yellow while had almost no matrix interference and this demonstrates no difference in food and water. We thus argue that this principle can be used for the screening of high concentrations of nitrite, and discriminating NaNO2 and NaCl to prevent poisoning events caused by misuses. In this sense, we believe the principle in question has a high applying value and is worth promoting. It can be made into a commercial hydrochloric acid acidified naphthylethylenediamine hydrochloride solution for further commercialized applications.},
 year = {2022}
}

Copy | Download

TY  - JOUR
T1  - Study on Mechanism and Application of High Concentrations of Nitrite-Induced Specific Color Fading
AU  - Jiaxin Zuo
AU  - Jing Guo
Y1  - 2022/06/14
PY  - 2022
N1  - https://doi.org/10.11648/j.sjac.20221002.13
DO  - 10.11648/j.sjac.20221002.13
T2  - Science Journal of Analytical Chemistry
JF  - Science Journal of Analytical Chemistry
JO  - Science Journal of Analytical Chemistry
SP  - 29
EP  - 39
PB  - Science Publishing Group
SN  - 2376-8053
UR  - https://doi.org/10.11648/j.sjac.20221002.13
AB  - Nitrite and edible salt are easy to confuse for their similar appearance and taste, thus possibly causing nitrite poisoning. Therefore, it is particularly crucial to figure out how to screen high concentrations of nitrite, how to discriminate NaNO2 and NaCl, and how to accurately quantify high concentrations of nitrite. In this study, the phenomenon of high concentrations of nitrite fading to orange-yellow color in colorimetric solution of naphthalene ethylenediamine hydrochloride was studied and accurately quantified by dilution colorimetry. It is to prevent false negative detection while NaCl presented no such phenomenon. Through spectrophotometry, high-performance liquid chromatography, and liquid mass spectrometry, we discovered that the principle of high concentrations of nitrite fading to orange-yellow after colorimetry was that high concentrations of nitrite nitrosated azo compounds and naphthalene ethylenediamine hydrochloride in hydrochloric acid medium. This principle can make the solution appear orange-yellow while had almost no matrix interference and this demonstrates no difference in food and water. We thus argue that this principle can be used for the screening of high concentrations of nitrite, and discriminating NaNO2 and NaCl to prevent poisoning events caused by misuses. In this sense, we believe the principle in question has a high applying value and is worth promoting. It can be made into a commercial hydrochloric acid acidified naphthylethylenediamine hydrochloride solution for further commercialized applications.
VL  - 10
IS  - 2
ER  -

Copy | Download