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Development and Characterization of Geopolymers Based on a Kaolinitic Clay

Received: 12 November 2021    Accepted: 9 December 2021    Published: 24 December 2021
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Abstract

Geopolymers today constitute an alternative to be considered with the aim, not of completely replacing cement, but of widening the possibilities available at the time of decision-making because this type of clay-based binder has a low impact environmental and thermal compared to Portland cement. The methods used to obtain eco-friendly building units from waste materials can be separated into three general categories: firing, cementing and geo-polymerization. The reaction of solid aluminosilicate materials with a highly concentrated aqueous alkali hydroxide or silicate solution produces a synthetic alkali aluminosilicate material called a ‘geopolymer. Geopolymers based on clay materials from Burkina Faso were developed and then characterized for use in construction. The results of the characterization of the clay mineral material referenced TAN as well as its calcined forms TAN-700 and TAN-800 have shown by several analysis techniques (DRX, IR, ICP-AES) that TAN contains kaolinite (71%), quartz (20%), illite (4%) and goethite (2%). TAN-700 and TAN-800 are essentially made of quartz. These clays are each mixed with the alkaline solution (sodium hydroxide solution 8 mol.L-1) in a mass ratio (alkaline solution/clay) ranging from 0.33 to 0.36. The results of the mechanical and mineralogical tests of the geopolymers produced showed that the grade GP-MK0 produced had the best performance favorable for its use in construction. Indeed, its linear shrinkage (3.44%) is low and the compressive strength (22.50 MPa) is greater than 4 MPa. This performance of GP-MK0 is due to the formation of a phase rich in silica and in alumina (Na2(AlSiO4)6(OH)2·2H2O).

Published in Science Journal of Chemistry (Volume 9, Issue 6)
DOI 10.11648/j.sjc.20210906.15
Page(s) 160-170
Creative Commons

This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.

Copyright

Copyright © The Author(s), 2024. Published by Science Publishing Group

Keywords

Clay, Development, Geopolymer, Characterization, Construction

References
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    Soungalo Ouattara, Brahima Sorgho, Moustapha Sawadogo, Youssouf Sawadogo, Mohamed Seynou, et al. (2021). Development and Characterization of Geopolymers Based on a Kaolinitic Clay. Science Journal of Chemistry, 9(6), 160-170. https://doi.org/10.11648/j.sjc.20210906.15

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    Soungalo Ouattara; Brahima Sorgho; Moustapha Sawadogo; Youssouf Sawadogo; Mohamed Seynou, et al. Development and Characterization of Geopolymers Based on a Kaolinitic Clay. Sci. J. Chem. 2021, 9(6), 160-170. doi: 10.11648/j.sjc.20210906.15

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    AMA Style

    Soungalo Ouattara, Brahima Sorgho, Moustapha Sawadogo, Youssouf Sawadogo, Mohamed Seynou, et al. Development and Characterization of Geopolymers Based on a Kaolinitic Clay. Sci J Chem. 2021;9(6):160-170. doi: 10.11648/j.sjc.20210906.15

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  • @article{10.11648/j.sjc.20210906.15,
      author = {Soungalo Ouattara and Brahima Sorgho and Moustapha Sawadogo and Youssouf Sawadogo and Mohamed Seynou and Philippe Blanchart and Moussa Gomina and Lamine Zerbo},
      title = {Development and Characterization of Geopolymers Based on a Kaolinitic Clay},
      journal = {Science Journal of Chemistry},
      volume = {9},
      number = {6},
      pages = {160-170},
      doi = {10.11648/j.sjc.20210906.15},
      url = {https://doi.org/10.11648/j.sjc.20210906.15},
      eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.sjc.20210906.15},
      abstract = {Geopolymers today constitute an alternative to be considered with the aim, not of completely replacing cement, but of widening the possibilities available at the time of decision-making because this type of clay-based binder has a low impact environmental and thermal compared to Portland cement. The methods used to obtain eco-friendly building units from waste materials can be separated into three general categories: firing, cementing and geo-polymerization. The reaction of solid aluminosilicate materials with a highly concentrated aqueous alkali hydroxide or silicate solution produces a synthetic alkali aluminosilicate material called a ‘geopolymer. Geopolymers based on clay materials from Burkina Faso were developed and then characterized for use in construction. The results of the characterization of the clay mineral material referenced TAN as well as its calcined forms TAN-700 and TAN-800 have shown by several analysis techniques (DRX, IR, ICP-AES) that TAN contains kaolinite (71%), quartz (20%), illite (4%) and goethite (2%). TAN-700 and TAN-800 are essentially made of quartz. These clays are each mixed with the alkaline solution (sodium hydroxide solution 8 mol.L-1) in a mass ratio (alkaline solution/clay) ranging from 0.33 to 0.36. The results of the mechanical and mineralogical tests of the geopolymers produced showed that the grade GP-MK0 produced had the best performance favorable for its use in construction. Indeed, its linear shrinkage (3.44%) is low and the compressive strength (22.50 MPa) is greater than 4 MPa. This performance of GP-MK0 is due to the formation of a phase rich in silica and in alumina (Na2(AlSiO4)6(OH)2·2H2O).},
     year = {2021}
    }
    

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  • TY  - JOUR
    T1  - Development and Characterization of Geopolymers Based on a Kaolinitic Clay
    AU  - Soungalo Ouattara
    AU  - Brahima Sorgho
    AU  - Moustapha Sawadogo
    AU  - Youssouf Sawadogo
    AU  - Mohamed Seynou
    AU  - Philippe Blanchart
    AU  - Moussa Gomina
    AU  - Lamine Zerbo
    Y1  - 2021/12/24
    PY  - 2021
    N1  - https://doi.org/10.11648/j.sjc.20210906.15
    DO  - 10.11648/j.sjc.20210906.15
    T2  - Science Journal of Chemistry
    JF  - Science Journal of Chemistry
    JO  - Science Journal of Chemistry
    SP  - 160
    EP  - 170
    PB  - Science Publishing Group
    SN  - 2330-099X
    UR  - https://doi.org/10.11648/j.sjc.20210906.15
    AB  - Geopolymers today constitute an alternative to be considered with the aim, not of completely replacing cement, but of widening the possibilities available at the time of decision-making because this type of clay-based binder has a low impact environmental and thermal compared to Portland cement. The methods used to obtain eco-friendly building units from waste materials can be separated into three general categories: firing, cementing and geo-polymerization. The reaction of solid aluminosilicate materials with a highly concentrated aqueous alkali hydroxide or silicate solution produces a synthetic alkali aluminosilicate material called a ‘geopolymer. Geopolymers based on clay materials from Burkina Faso were developed and then characterized for use in construction. The results of the characterization of the clay mineral material referenced TAN as well as its calcined forms TAN-700 and TAN-800 have shown by several analysis techniques (DRX, IR, ICP-AES) that TAN contains kaolinite (71%), quartz (20%), illite (4%) and goethite (2%). TAN-700 and TAN-800 are essentially made of quartz. These clays are each mixed with the alkaline solution (sodium hydroxide solution 8 mol.L-1) in a mass ratio (alkaline solution/clay) ranging from 0.33 to 0.36. The results of the mechanical and mineralogical tests of the geopolymers produced showed that the grade GP-MK0 produced had the best performance favorable for its use in construction. Indeed, its linear shrinkage (3.44%) is low and the compressive strength (22.50 MPa) is greater than 4 MPa. This performance of GP-MK0 is due to the formation of a phase rich in silica and in alumina (Na2(AlSiO4)6(OH)2·2H2O).
    VL  - 9
    IS  - 6
    ER  - 

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Author Information
  • Laboratory of Molecular Chemistry and Materials (LC2M), University Joseph KI-ZERBO, Ouagadougou, Burkina Faso

  • Laboratory of Molecular Chemistry and Materials (LC2M), University Joseph KI-ZERBO, Ouagadougou, Burkina Faso

  • Laboratory of Molecular Chemistry and Materials (LC2M), University Joseph KI-ZERBO, Ouagadougou, Burkina Faso

  • Laboratory of Molecular Chemistry and Materials (LC2M), University Joseph KI-ZERBO, Ouagadougou, Burkina Faso

  • Laboratory of Molecular Chemistry and Materials (LC2M), University Joseph KI-ZERBO, Ouagadougou, Burkina Faso

  • Institute of Research in Ceramic (IRCER), European Ceramic Center, Limoges, France

  • Laboratory of Cristallography and Material Sciences (CRISMAT), National Graduate School of Engineering of Caen (ENSICAEN), Caen, France

  • Laboratory of Molecular Chemistry and Materials (LC2M), University Joseph KI-ZERBO, Ouagadougou, Burkina Faso

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